宁阳县蒋集镇水库土坝非稳定性探析

宁阳县蒋集镇地处汶河南岸,黄淮分水岭北侧,最大海拔高程361m.全镇区域面积12．7万km^2,其中山区、丘陵占2／3,岩石类型以花岗片麻岩为主。20世纪50-60年代兴建了117座水库塘坝,其中小（一）型水库2座,小（二）型水库15座,塘坝100座,总库容1700余万m^2,坝体以土坝为主。由于当时施工机械落后,技术有限,经费不足,造成工程质量较低,因而不少土坝产生渗流、流土、管涌、滑坡等现象。     

西藏自治区昂仁县朱诺铜矿地质特征及找矿潜力远景评价

通过典型斑岩型铜矿模式对比,朱诺铜矿含矿斑岩体剥蚀程度为钾化带和黄铁绢英岩化上部,向深部及西部,具有较大的找矿潜力。     

Iron isotopic analyses of geological reference materials on MC-ICP-MS with instrumental mass bias corrected by three independent methods

Here we report iron (Fe) isotopic data of three pure Fe solution standards (IRMM-014, GSB Fe, and NIST 3126a) and five widely used geological reference materials (RMs) from the United States Geological Survey and Geological Survey of Japan obtained on a Neptune Plus multi-collector–inductively coupled plasma–mass spectrometer (MC-ICP-MS) in our laboratory over the past 3 years. The instrumental mass bias was corrected by three independent methods: sample-standard bracketing (SSB), Ni doping?+?SSB, and ⁵⁷Fe–⁵⁸Fe double spike?+?SSB. Measurements reveal that both the Ni doping and double spike methods helped calibrate short-term fluctuations in mass bias. Collectively, almost all measurements of RMs yielded δ⁵⁶Fe within?±?0.05 of recommended values, provided that each sample was measured four times on MC-ICP-MS. For the first time, new recommended values for NIST SRM3126a are reported (δ⁵⁶Fe?=?0.363?±?0.006, 2SE, 95% CI; and δ⁵⁷Fe?=?0.534?±?0.010, 2SE).     

Pretreatment of high strength waste emulsions by combined vibratory shear enhanced process with Fenton oxidation

Pretreatment of waste emulsions with high organic content by a combined process of vibratory shear enhanced process and Fenton’s oxidation prior to biological treatment was investigated. Vibrating membrane had shown good performance in chemical oxygen demand and oil removals and the mitigation of concentration polarization. However, the permeate after filtration processing still contained high content of organics. Thus, additional Fenton oxidation was applied to reduce the organic loading, and improve the biodegradability of the wastewater. The optimal molar ratio of ferrous iron to hydrogen peroxide was 0.05 obtained from the jar-test experiments. Removal of organics was enhanced by increasing hydrogen peroxide dosage, while efficiency of hydrogen peroxide reached maximum of 1.11(w/w) at the hydrogen peroxide dosage of 6.8 g/L. Furthermore, the biological experiments indicated that the high concentration of organics could inhibit microbial activity, which decreased the chemical oxygen demand degradation rates. The adaptive period of the microbe was greatly shortened using Fenton’s reagent at the low dosages. The improvement of the biodegradability could be explained by partial mineralization and chemical transformation of parent organic compounds after Fenton oxidation.     

桂西下三叠统牙形石序列的新认识

桂西下三叠统为海相沉积,根据其岩性、厚度、化石类型等诸方面的明显差异可以分为两种类型,即作登型和太平型。本文详细研究了桂西两种类型下三叠统的牙形石,认为不同类型的下三叠统具有不同的牙形石序列。在前人工作基础上,对桂西下三叠统牙形石序列予以重新厘定。补充了作登型下三叠统的Neogondolella carinta带;指出作登型下三叠统不宜建立Platyvillosus costatus带;在太平型下三叠统Dienerian阶—Spathian阶中新建了Pachvcladina erromera带,Platyvillosus costatus带,Pachycladina obliqua-Parachirognathus delicatulus带和Neospathodus triangularis带;指出了每一个牙形石带的性质并与作登型下三叠统牙形石序列进行了对比。本文还从事件地层学和生物地层学两个角度,对桂西二叠一三叠系界线提出了新的认识。     

青海省都兰县果洛龙洼金矿成矿流体

果洛龙洼金矿是青海东昆仑地区最典型、最具规模的金矿床之一。在前人资料基础上,将果洛龙洼金矿热液成矿期划分为4个成矿阶段：贫矿化石英阶段、石英-多金属硫化物阶段（主要成矿阶段）、石英-贫硫化物阶段（次要成矿阶段）和石英-碳酸盐阶段。随后对主要和次要成矿阶段石英脉开展流体包裹体显微测温和H-O同位素研究。结果表明：原生流体包裹体主要包括气液两相、富CO₂三相、纯CO₂两相共3类;成矿流体总体以CO₂-NaCl-H₂O体系为主,均一温度为130.0~357.3 ℃,盐度（w(NaCl)）为1.83%~20.11%。石英-多金属硫化物阶段石英δ¹⁸O_V-SMOW值为14.8‰~17.2‰,据此计算流体的δ¹⁸O_H2O值为5.5‰~8.5‰,流体的δD_V-SMOW值为-61‰~-96‰;而石英-贫硫化物阶段石英δ¹⁸O_V-SMOW值为15.7‰~16.9‰,据此计算流体的δ¹⁸O_H2O值为4.1‰~5.3‰,流体的δD_V-SMOW值为-84‰~-101‰。由此认为：主要成矿阶段成矿流体可能为高温低盐度富CO₂变质热液和低温中高盐度岩浆热液两个端元组成的混合流体;次要成矿阶段成矿流体主要为混合后更均匀的中低温中低盐度热液,但后期明显有大气降水混入。总之,成矿流体的来源、性质及其演化等方面的研究结果进一步证明果洛龙洼金矿为造山型金矿。     

Calcified roasting-acid leaching process of vanadium from low-grade vanadium-containing stone coal

The low-grade vanadium-containing stone coal used in this experiment was collected from Wuxi Coun- try, Chongqing City, China. The experiment focused on the vanadium recovery from roasted residue through opti- mizing the process conditions of an effective and environmentally-friendly technology, named calcified roast- ing-sulfuric acid leaching technology. By single-factor experiments and orthogonal experiments, the effects of roast- ing temperature, roasting time, sulfuric acid concentration and leaching time on the leaching ratio of vanadium were analyzed. The results showed that the leaching ratio of vanadium reached 85.5% under the proper technological con- ditions of roasting temperature=950℃, roasting time=4 h, 40% concentration of sulfuric acid and leaching time=6 h.     

锶矿X

研究了找锶矿的     

闽西北铅锌矿成矿特征及控矿条件浅析

闽北地区属华南褶皱系的一部分,其中铅、锌为区内优势矿种,广泛分布于前震旦纪变质岩系中,尤其以前震旦纪龙北溪组的黑云斜长变粒岩、云母片岩、石英片岩中最为多见。其成矿特征可分为热液型铅锌矿床、充填交代型铅锌矿床及沉积变质热液叠加型铅锌矿床。其形成受地层、岩浆、构造（以断裂构造为主）控制较为明显,前震旦系变质岩系中的绿片岩、压扭性断裂及前震旦系变质岩系与岩体的接触带及其附近应是本区铅锌矿床找矿的主要方向。