Late Ordovician high-Mg adakitic andesite in the western South China block: evidence of oceanic subduction

The Early Palaeozoic was an important period in the geologic evolution of the South China block (SCB), marking the intracontinental orogen in the Wuyi-Yunkai region. One salient feature of the western SCB is the absence of Early Palaeozoic oceanic subduction-related magmatism. Here, we report the first known occurrence of Late Ordovician andesites from the Shimian area, western SCB. Zircon SHRIMP U–Pb dating reveals that the andesites formed at ca. 451 Ma. They have geochemical features of high-Mg adakitic andesite (HMAA) and are characterized by low K₂O (1.09–2.24 wt.%) and Th (2.50–5.65 ppm) and high MgO (4.02–6.91 wt.%) and Mg# (56–71). Furthermore, their zircon grains display positive ε_Hf(t) (+11.4 to +19.6) and low δ¹⁸O (4.72–6.20‰) values. The andesites are interpreted to have been derived from partial melting of a peridotitic mantle wedge in an oceanic subduction setting and subsequent fractional crystallization. Integrating previous studies of the Qinling-Dabie orogenic belt with the data presented in this contribution, we suggest that the SCB was probably involved in the Early Palaeozoic Andean-type orogeny along the Gondwanan proto-Tethyan margin.     

Comparison of Fenton,ultraviolet–Fenton and ultrasonic–Fenton processes on organics and colour removal from pre-treated natural gas produced water

Produced water (PW) from natural gas field, characterized with high organic contents, has brought high environmental concerns world widely. Fenton and enhanced Fenton technologies were considered as the potential methods to degrade the organic contaminates in the PW, but with very limited data or reference. Here, we examined the optimum conditions of Fenton on organics and colour removal from natural gas PW after coagulation pre-treatment. Simultaneously, the optimal Fenton process integrated with ultraviolet (UV) and ultrasonic (US) irradiation were applied to enhance pollutants removal efficiencies. The optimal Fenton conditions were found at 60 min with molar ratios of 6:1 and 25:1 for H₂O₂/COD and H₂O₂/Fe²⁺, respectively and the initial pH of 3. Among these the three treatment processes, chemical oxygen demand (COD), total organic carbon, 5-day biological oxygen demand (BOD₅), and colour removal efficiencies were highest during UV–Fenton (82, 73, 68, and 95%,) followed by US–Fenton (79, 70, 66, and 95%) and Fenton treatment (70, 58, 51, and 92%), respectively. High biodegradability (BOD₅/COD) was also observed after UV–Fenton process (0.76) than the others (both 0.73). The current study showed a satisfactory carbon and colour removal efficiencies from PW using different Fenton processes; however, there still is a need for final polishing such as biological treatment or low cost constructed wetland before discharge. This study can be a good reference for engineering application PW treatment.     

First observation of domoic acid and its isomers in shellfish samples from Shandong Province,China

Journal of Oceanology and Limnology - A total of 133 shellfish samples were collected in seven cities of Shandong Province, China, from May to October, 2019. The domoic acid (DA) concentrations...     

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北半球近地层典型区CO_2体积分数时空分布及成因

利用GEOS-Chem全球三维大气化学传输模式,分析了北半球近地层CO2体积分数的时空变化特征及其成因。2006—2010年的5 a的模拟结果表明:北半球中纬度近地层CO2体积分数存在着两个高值中心,即亚洲东部和北美东北部。在季节尺度上,亚洲东部CO2体积分数最大值出现在春季,而北美东北区域CO2体积分数最大值出现在冬季;而两个地区的CO2体积分数最低值都出现在夏季。在年际尺度上,两个区域CO2体积分数的年际变率增幅明显高于北半球其它区域,且CO2体积分数高值出现时间的年际差异较大。另外,模拟分析发现北半球森林、农田、草原典型区域,所对应的CO2体积分数具有不同的季节变化特点,它们的CO2季节内变幅依次减小。进一步分析发现3种不同典型区域的CO2体积分数与叶面积指数(LAI)季节变化,具有很好的负相关性。可见陆地生态系统作为碳汇,对近地层CO2体积分数的季节变化具有重要的作用。而温度和降水是影响LAI的最重要的两个气象因子,它们与CO2体积分数季节变化存在内在联系,模拟结果表明北半球大部分陆地近地层CO2体积分数与温度、降水呈现显著的负相关。     

地下储层构型表征:现状与展望

地下储层构型表征是近十几年发展起来的油气藏开发地质研究方向。与露头构型分析不同的是,地下储层构型表征主要依据地震信息和多井信息,相应地发展了两类方法,其一为地震沉积学(地貌学)方法,即通过三维地震资料地层切片等方式,利用地震成像特征研究沉积单元的分布;其二为多井模式预测方法,即通过将不同级次的定量构型模式与地下井资料(包括动态监测资料)进行拟合,分级约束并预测不同级次的构型单元的井间分布。论述了这两类方法的起源、基本原理、应用范畴及存在问题,并根据油田生产要求与技术发展提出了进一步深入研究的方向,包括三维定量构型模式的深化研究、储层构型地震响应及解释方法研究、多井模拟拟合方法的改进与创新等。     

大兴安岭南段多金属成矿带硫、铅同位素组成及其地质意义

大兴安岭南段是我国北方重要的多金属矿床成矿带,对其成矿物质来源的分析研究有利于区域成矿规律的总结。在前人的工作基础上,对典型矿床的矿石矿物进行了硫、铅同位素研究。结果表明:闪锌矿、方铅矿、毒砂、黄铜矿、辉钼矿等硫化物的δ34S值主要变化范围为-6‰～4‰,平均值为0‰,峰值出现在0‰～2‰,呈塔式分布;无明显的重硫、轻硫富集,说明硫源较单一;矿石矿物及岩石的206 Pb/204 Pb、207Pb/204Pb、208Pb/204Pb值的变化范围主要集中在18.13～18.74、15.38～15.68和37.1～38.93,其平均值分别为18.38、15.54和38.09。同时,数据结果显示:成矿带的东部与西部存在较为明显的铅同位素差异,西部矿床中铅的分布主要集中在造山带演化线附近,而东部矿床中铅主要集中分布在上地幔和造山带演化曲线附近。     

Spatial Statistical Properties of Pressure Solution Seams in Clastic Rocks in Southwest Ireland

Length, height, thickness and spacing measurements of pressure solution seams at outcrop, hand sample and thin section scale were taken from clastic rocks located in the southwest of Ireland. The lengths and spacings of pressure solution seams have similarly shaped (approximately log-hyperbolic) distributions at the observed scales suggesting that length and spacing distributions are scale-independent over the scales studied with a fractal dimension in the range of 1.4 to 1.6. Pressure solution seam lengths and thicknesses are related by a power-law and their spacings have a linear relationship to bed thickness. Although pressure solution seams are often considered as anticracks (forming under the same remote stresses as joints, but with opposite sign) we describe how the mechanism of pressure solution differs substantially from that of jointing. We use an existing mechanical model to show that stresses around pressure solution seam tips are much lower than those for joints under equal but opposite loading conditions. Pressure solution seams also have a decreasing tendency to lengthen as they grow, which is reflected in their length distributions. We propose that pressure solution seams, unlike joints, do not reach fracture saturation spacing because of transverse coalescence.     

Interannual variations of North Equatorial Current transport in the Pacific Ocean during two types of El Niño

Interannual variations of Pacific North Equatorial Current (NEC) transport during eastern-Pacific El Niños (EP-El Niños) and central-Pacific El Niños (CP-El Niños) are investigated by composite analysis with European Centre for Medium-Range Weather Forecast Ocean Analysis/Reanalysis System 3. During EP-El Niño, NEC transport shows significant positive anomalies from the developing to decay phases, with the largest anomalies around the mature phase. During CP-El Niño, however, the NEC transport only shows positive anomalies before the mature phase, with much weaker anomalies than those during EP-El Niño. The NEC transport variations are strongly associated with variations of the tropical gyre and wind forcing in the tropical North Pacific. During EP-El Niño, strong westerly wind anomalies and positive wind stress curl anomalies in the tropical North Pacific induce local upward Ekman pumping and westward-propagating upwelling Rossby waves in the ocean, lowering the sea surface height and generating a cyclonic gyre anomaly in the western tropical Pacific. During CP-El Niño, however, strength of the wind and associated Ekman pumping velocity are very weak. Negative sea surface height and cyclonic flow anomalies are slightly north of those during EP El Niño.     

桃山大布铀矿床绿泥石特征及其形成环境

花岗岩型铀矿中,绿泥石化作为热液蚀变的重要类型之一,其种类多样,据此可以推断其形成环境。笔者在岩石薄片观察的基础上,通过对绿泥石进行电子探针成分分析,认为桃山大布铀矿床的绿泥石主要为铁绿泥石、蠕绿泥石,其形成于中低温酸性热液作用环境。