A study of bernalite,Fe(OH)3, using Mössbauer spectroscopy,optical spectroscopy and transmission electron microscopy

To study the crystal chemistry of bernalite, Fe(OH)₃, and the nature of the octahedral Fe³⁺ environment, Mössbauer spectra were recorded from 80 to 350 K, optical spectra were recorded at room temperature and a sample was studied using transmission electron microscopy. The Mössbauer spectrum of bernalite consists of a single six-line magnetic spectrum at 80 K. A broadened six-line magnetic spectrum with significantly less intensity is observed at higher temperatures, and is attributed to a small fraction of bernalite occurring as small particles. The variation of hyperfine magnetic field data for bulk bernalite with temperature is well described by the Weiss molecular field model with parameters of H ₀ = 55.7±0.3 T and T _N = 427±5K. The centre shift data were fitted to the Debye model with parameters ₀=0.482±0.005 mm/s (relative to -Fe) and _M=492±30 K. The quadrupole shift is near zero at 300 K, and does not vary significantly with temperature. Absorption spectra in the visible and near infrared range show three crystal field bands of Fe³⁺ at 11 300, 16000 and 23 200 cm^-1, giving a crystal field splitting of 14 570 cm^-1 and Racah parameters of B=629 cm^-1 and C=3381 cm^-1. Infrared reflection spectra show two distinct OH-stretching frequencies, which could correspond to two structurally different types of OH groups. A band was also observed at 2250 cm^-1, suggesting the presence of molecular CO₂ in the large cation site. Analytical transmission electron microscopy indicates that Si occurs within the bernalite structure as well as along domain boundaries. Electron diffraction and imaging show that bernalite is polysynthetically twinned along {100} planes with twin domains ranging from 3 to 20 nm in thickness. Results are discussed with respect to the nature of the octahedral Fe³⁺ site, and compared with values for other iron oxides and hydroxides.     

Comparing Solar Minimum 23/24 with Historical Solar Wind Records at 1 AU

Based on the variations of sunspot numbers, we choose a 1-year interval at each solar minimum from the beginning of the acquisition of solar wind measurements in the ecliptic plane and at 1 AU. We take the period of July 2008??C?June 2009 to represent the solar minimum between Solar Cycles 23 and 24. In comparison with the previous three minima, this solar minimum has the slowest, least dense, and coolest solar wind, and the weakest magnetic field. As a result, the solar wind dynamic pressure, dawn?Cdusk electric field, and geomagnetic activity during this minimum are the weakest among the four minima. The weakening trend had already appeared during solar minimum 22/23, and it may continue into the next solar minimum. During this minimum, the galactic cosmic ray intensity reached the highest level in the space age, while the number of solar energetic proton events and the ground level enhancement events were the least. Using solar wind measurements near the Earth over 1995??C?2009, we have surveyed and characterized the large-scale solar wind structures, including fast-slow stream interaction regions (SIRs), interplanetary coronal mass ejections (ICMEs), and interplanetary shocks. Their solar cycle variations over the 15 years are studied comprehensively. In contrast with the previous minimum, we find that there are more SIRs and they recur more often during this minimum, probably because more low- and mid-latitude coronal holes and active regions emerged due to the weaker solar polar field than during the previous minimum. There are more shocks during this solar minimum, probably caused by the slower fast magnetosonic speed of the solar wind. The SIRs, ICMEs, and shocks during this minimum are generally weaker than during the previous minimum, but did not change as much as did the properties of the undisturbed solar wind.     

Lithologic mapping of HED terrains on Vesta using Dawn Framing Camera color data

The surface composition of Vesta, the most massive intact basaltic object in the asteroid belt, is interesting because it provides us with an insight into magmatic differentiation of planetesimals that eventually coalesced to form the terrestrial planets. The distribution of lithologic and compositional units on the surface of Vesta provides important constraints on its petrologic evolution, impact history, and its relationship with vestoids and howardite‐eucrite‐diogenite (HED) meteorites. Using color parameters (band tilt and band curvature) originally developed for analyzing lunar data, we have identified and mapped HED terrains on Vesta in Dawn Framing Camera (FC) color data. The average color spectrum of Vesta is identical to that of howardite regions, suggesting an extensive mixing of surface regolith due to impact gardening over the course of solar system history. Our results confirm the hemispherical dichotomy (east‐west and north‐south) in albedo/color/composition that has been observed by earlier studies. The presence of diogenite‐rich material in the southern hemisphere suggests that it was excavated during the formation of the Rheasilvia and Veneneia basins. Our lithologic mapping of HED regions provides direct evidence for magmatic evolution of Vesta with diogenite units in Rheasilvia forming the lower crust of a differentiated object.     

Carbon-Oxidizing and Sulfate-Reducing Bacteria in Mozhaisk Reservoir Soils

The population and distribution of carbon-oxidizing and sulfate-reducing bacteria in the soils of the Mozhaisk Reservoir are studied.     

Phosphides in Volcanic Seamount Basalts in the Sea of Japan

Electron microprobe data on phosphide grains detected for the first time in basalts from volcanic edifices in the Sea of Japan are presented. The find of phosphides can testify to the endogenic source of phosphorus and, consequently, volcanogenic hydrothermal origin of phosphorites in the Sea of Japan.     

Nitrogen and phosphorus in New Zealand streams and rivers: Control and impact of eutrophication and the influence of land management

Abstract

Given sufficient light and heat, the growth of aquatic macrophytes and algae associated with eutrophication is generally controlled by the concentration, form and ratio between nitrogen (N) and phosphorus (P). Data from 1100 freshwater sites monitored for the last 10 years by New Zealand's regional councils and unitary authorities were assessed for streams and rivers with mean nitrate/ nitrite‐N (NNN), dissolved reactive P (DRP), total N (TN) and total P (TP) concentrations in excess of New Zealand guidelines, and to generate a data set of N:P ratios to predict potential periphyton response according to the concentration of the limiting nutrient. The frequency of sites exceeding the guidelines varied from 0 to 100% depending on the parameter and region, but South Island regions were generally more compliant. The dissolved inorganic N (DIN) to dissolved reactive P (DRP) ratio was used to group data into three nutrient limitation classes: <7:1 (N‐limited), between 7:1 and 15:1 (co‐limited), and>15:l (P‐limited), by mass. P‐limitation was the most frequent scenario in New Zealand streams (overall, 76% of sites were P‐limited, 12% N‐limited, and 12% co‐limited). The mean concentration of the limiting nutrient for each site was combined with empirical relationships to predict periphyton densities (the average of N‐and P‐limited growth was used for sites with co‐limitation). This assessment predicted that 22 sites were likely to exceed the periphyton guideline for protecting benthic biodiversity (50 mg chlorophyll a m^?2), but this assessment is likely to be highly changeable in response to climatic conditions and present and future land use. As an example, we modelled N and P losses from an average sheep and a dairy farm in Southland (South Island, New Zealand) in 1958, 1988, 2008 and 2028. We predicted that with time, as farm systems have and continue to intensify, N losses increase at a greater rate than P losses. Since the pathway for N to reach fresh waters may be more tortuous and take longer than P to reach a stream or river, focusing mitigation on P losses may have a quicker effect on potential algal growth. In addition, with time, it is expected that P‐limitation in New Zealand's rivers and streams will be more widespread as N‐losses are unabated. Hence, although strategies to decrease N losses should be practised, mitigating P losses is also central to preventing eutrophication.     

A Search for a Globular Cluster whose Passage Through the Galactic Disk Could Induce the Formation of the Gould Belt

The distribution of sites where globular clusters have crossed the Galactic disk during the last 100 million years has been analyzed using the most recent kinematic data for 133 globular clusters (GCs). ThreeGCs (NGC 6341, NGC 7078, and ω Cen) whose distances between the positions where they crossed the Galactic disk and trajectories of the Gould Belt are less than 20% of their heliocentric distances at the crossing time (82, 98, and 96 million years ago, respectively) have been identified. For each of the clusters, this was their next to last, rather than their last, crossing of the Galactic disk. The passage of any one of these three GCs through the disk could potentially have initiated the formation of the Gould Belt.     

Bioactive substances of various seaweeds and their applications and utilization

Over the past century or more,traditional uses of seaweeds began and initially comprised the simple collection,sorting and drying of seaweeds harvested from the wild,or cast upon the beach,for use as soil“manure/fertilizer/improver”.Some macroalgae were used for unprocessed food purposes and subsequently harvested and cultivated biomasses of selected brown and red seaweeds becameindustrially processed to yield alginates,mannitol,iodine,agar,agarose,carrageenan,and more recently biostimulants,etc.Products from various seaweeds are very diverse and are commonly applied in a range that includes textiles and dying,food/feed and supplements and specialized medical applications.     

The Singapore River thematic zone: sustainable tourism in an urban context

This paper explores the concept of sustainable tourism and how it applies to urban destinations such as Singapore. As tourism is an important industry in Singapore, in terms of employment, business activity and an income generator, the Singapore Tourism Board is continuously looking at potential avenues to make Singapore a competitive destination. We examine the use of thematic zones in Singapore as a strategy to achieve its ambition of becoming a tourism capital of the world. By focusing on a case study of the Singapore River thematic zone (one of the 11 thematic zones identified by the Singapore Tourism Board), we assess the viability of thematic zones in ensuring sustainable urban tourism. The paper closes with some theoretical reflections and policy implications arising from our key findings.     

The “slip law” of the free surface

A “slip law” connects the excess velocity or “slip” of a wind-blown water surface, relative to the motion in the middle of the mixed layer, to the wind stress, the wind-wave field, and buoyancy flux. An inner layer-outer layer model of the turbulent shear flow in the mixed layer is appropriate, as for a turbulent boundary layer or Ekman layer over a solid surface, allowing, however, for turbulent kinetic energy transfer from the air-side via breaking waves, and for Stokes drift. Asymptotic matching of the velocity distributions in inner and outer portions of the mixed layer yields a slip law of logarithmic form, akin to the drag law of a turbulent boundary layer. The dominant independent variable is the ratio of water-side roughness length to mixed layer depth or turbulent Ekman depth. Convection due to surface cooling is also an important influence, reducing surface slip. Water-side roughness length is a wind-wave property, varying with wind speed similarly to air-side roughness. Slip velocity is typically 20 times water-side friction velocity or 3% of wind speed, varying within a range of about 2 to 4.5%. A linearized model of turbulent kinetic energy distribution shows much higher values near the surface than in a wall layer. Nondimensional dissipation peaks at a value of about eight, a short distance below the surface.