DFT study of the carbonation on mineral aerosol surface models of olivine: effect of water

Mineral aerosols play a significant role in gas–solid interfacial and atmospheric chemistry. Carbonation of olivine aerosol, which takes place in a multiphase reaction processes, can be an effective means to reduce the concentration of atmospheric carbon dioxide. Due to the presence of a huge reserve of silicate minerals in nature, olivine aerosol could be an ideal potential raw material for mineral carbonation for its higher reactivity with H₂O and CO₂. However, quantitative information about the carbonation process on the surface of natural olivine aerosol is not available. In this paper, calculations on the carbonation reaction processes with and without a H₂O molecule using a periodic olivine model has been carried out via the density functional theory. The pathways and their corresponding energies and structures in the carbonation reactions have been established, and the effect of water as means to reduce the energy barriers and stabilize the carbonated structures by forming hydrogen bonds has been confirmed.     

Structural and stratigraphical constraints on the kinematics history of the Southern Tan–Lu Fault Zone during the Mesozoic Anhui Province, China

The Tan–Lu Fault Zone (TLFZ) extends in a NNE–SSW direction for more than 2000 km in Eastern China. It has been considered either as a major sinistral strike-slip fault, as a suture zone or as a normal fault. We have conducted a structural analysis of the southern segment of this fault zone (STLFZ) in the Anhui Province. The ages (Triassic to Palaeocene) of the formations affected by the faults have been re-appraised taking into account recent stratigraphical studies to better constraint the ages of the successive stages of the kinematics of the STLFZ. Subsequently, the kinematics of the faults is presented in terms of strain/stress fields by inversion of the striated fault set data. Finally, the data are discussed in the light of the results obtained by previous workers.We propose the following history of the STLFZ kinematics during the Mesozoic. At the time of collision, a  NNE orientated Tan–Lu margin probably connected two margins located north of the Dabie and Sulu collision belts. During the Middle–Late Triassic, the SCB has been obliquely subducted below the NCB along this margin which has acted as a compressional transfer zone between the Dabie and Sulu continental subduction zones. The STLFZ has been initiated during the Early Jurassic and has acted as a sinistral transform fault during the Jurassic, following which the NCB/SCB collision stopped. A  NW-trending extension related to metamorphic domes was active during the basal Early Cretaceous ( 135–130 Ma); it has been followed by a NW–SE compression and a NE–SW tension during the middle–late Early Cretaceous ( 127 to  105 Ma, possibly  95 Ma); at that time the TLFZ was a sinistral transcurrent fault within the eastern part of the Asian continent. During the Late Cretaceous–Palaeocene, the STLFZ was a normal fault zone under a WNW–ESE tension.     

Lamproitic Rocks from a Continental Collision Zone: Evidence for Recycling of Subducted Tethyan Oceanic Sediments in the Mantle Beneath Southern Tibet

Major and trace element, Sr–Nd–Pb isotope and mineralchemical data are presented for newly discovered ultrapotassiclavas in the Tangra Yumco–Xuruco graben in southern Tibet.The ultrapotassic lavas are characterized by high MgO, K₂O andTiO₂, low Al₂O₃ and Na₂O contents, and also have high molarK₂O/Al₂O₃, molar (K₂O + Na₂O)/Al₂O₃ and K₂O/Na₂O ratios. Theirhigh abundances of incompatible trace elements such as largeion lithophile elements (LILE) and light rare earth elements(LREE) reach the extreme levels typical of lamproites. The lamproitesshow highly radiogenic ⁸⁷Sr/⁸⁶Sr (0· 7166–0·7363) and unradiogenic ¹⁴³Nd/¹⁴⁴Nd (0· 511796–0·511962), low ²⁰⁶Pb/²⁰⁴Pb (18· 459–18· 931),and elevated radiogenic ²⁰⁷Pb/²⁰⁴Pb (15· 6732–15·841) and ²⁰⁸Pb/²⁰⁴Pb (39· 557–40· 058) ratios.On the basis of their geochemical and isotopic systematics,the lamproites in south Tibet have a distinct magma source thatcan be differentiated from the sources of potassic lavas inthe east Lhasa and Qiangtang blocks. Their high Nb/Ta ratios(17· 10–19· 84), extremely high Th/U ratios(5· 70–13· 74) and distinctive isotope compositionsare compatible with a veined mantle source consisting of partialmelts of subducted Tethyan oceanic sediments and sub-continentallithospheric depleted mantle. Identification of the lamproitesand the delineation of their mantle source provide new evidencerelevant for models of the uplift and extension of the Tibetanplateau following the Indo-Asia collision. Metasomatism by partialmelts from isotopically evolved, old sediment subducted on theyoung Tethyan slab is an alternative explanation for PrecambrianNd and Pb model ages. In this model, differences in isotopiccomposition along-strike are attributed to differences in thetype of sediment being subducted, thus obviating the need formultiple metasomatic events over hundreds of million years.The distribution of lamproites, restricted within a north–south-trendinggraben, indicates that the initiation of east–west extensionin south Tibet started at 25 Ma. KEY WORDS: lamproites; subducted oceanic sediment; Tibetan active continental collision belt     

2007年中国大陆地震灾害损失述评

在列出2007年中国5级以上地震目录的基础上,结合有关省(自治区、直辖市)地震局的地震灾害评估资料,总结出2007年中国大陆地震灾害的主要数据和特性。最后列出1990—2007年中国大陆地震灾害的相应数据,并进行了简要的比较。     

超高强混凝土短柱抗震性能的试验研究

通过对12根剪跨比λ=2．0的超高强混凝土短柱在低周反复荷载下抗震性能的试验研究,分析了其破坏形态,并研究了轴压比和配箍率对试件滞回特性和抗震延性的影响,提出了满足一定延性要求（μ△≥3．0）超高强混凝土短柱的轴压比限值和箍筋加密区的最小配箍特征值的建议值。该值可为现行规范的修订提供参考。     

防震减灾行业下一代IPv6信息网络发展研究

下一代网络(next generation network,缩写为NGN)是以高性能、可扩展、可运营、可管理、更安全的下一代电信网络为基础,实现高质晕流媒体应用、无线和移动应用、多样化终端没备、按需的传输质量控制和更高安全保障的新型网络,IPv6是下一代网络的关键支撑技术.IPv6网是F一代IP网,不等同于下一代网络,IPv6网只有在满足下一代网络的必要特征后才可成为下一代网络.     

大连地磁台天文方位角测量

论述大连地磁台天文方位角的测量原理、方法及观测结果,在地磁观测室未封顶的条件下,能在观测墩直接观测北极星,避免比测墩转角换算等因素增加的观测误差,观测精度提高.     

Palynological constraints on the age of the Mississippi Valley-type Changdong Pb-Zn deposit,Sanjiang belt,West China

Mississippi Valley-type(MVT)Pb-Zn deposits serve as the world’s major supply of Pb-Zn resources.However,the age constraint of MVT Pb-Zn deposits has long been a big challenge,due to the lack of minerals that are unequivocally related to ore deposition and that can be used for radioisotopic dating.Here we show sporopollens can provide useful chronological information on the Changdong MVT Pb-Zn deposit in the Simao basin,Sanjiang belt,West China.The Pb-Zn ores in the Changdong deposit are hosted by internal sediments in paleo-karst caves of meteoric origin.Sphalerite and galena occur as replacements of carbonate minerals and void infillings in the internal sediments.The relations suggest that the Pb-Zn mineralization occurred after the deposition of the internal sediments.A palynological assemblage mainly composed of angiosperm pollen dominated by Castanea,Quercus,and Carya and fern spores dominated by Polypodiaceae,Pteris,and Athyriaceae was identified.These pollen and spores place the ore-hosting internal sediments and the Changdong paleo-karst at early to middle Oligocene.Consequently,the Changdong Pb-Zn deposit must have formed after the early Oligocene(~34 Ma).These age constraints,together with the geological characteristics,indicate that the Changdong Pb-Zn deposit is a paleo-karst-controlled MVT deposit related to fold-thrust systems in the Sanjiang belt.The Changdong deposit is similar to other MVT Pb-Zn deposits in the northern part of the Sanjiang belt,making it possible to extend this Pb-Zn belt 500 km further to the South.Results presented here highlights the potential of sporopollens in dating the age of MVT deposits related to paleo-karst formation in young orogenic belts.     

中国地震网格试验系统中资源管理与作业调度研究-资源管理和作业动态分配模型ProRMJS的建立me

通过分析与研究建立资源管理和作业动态分配ProRMJS模型,解决了中国地震灾害仿真网格试验系统（CEDAGrid）中网格科学计算平台在初期建设中存在的一些资源管理方面的问题. 针对网格科学计算平台默认各个计算节点均能提供计算服务的问题,ProRMJS通过ldquo;计算池rdquo;这一虚拟组织为调度器分发作业提供支撑;而调度器则根据计算池中各个节点的计算能力和状态,动态分配任务,这样就保证了计算平台的稳定性. 针对默认各个计算节点均能完成任务的问题, ProRMJS通过监控各个节点所负担作业的运行进度和设定作业时间阈值来管理作业运行. 对于各个节点计算能力大小的区别, ProRMJS通过对各个节点计算性能的权值量化,实行按ldquo;需rdquo;分配作业. 对各个节点计算性能的权值量化, ProRMJS是通过综合考虑各个因素对机器计算能力大小的影响后通过加权计算的方式完成的,从而提高了整个计算平台的工作效率. 最后通过实现地震应力触发科学计算实例验证了方案的有效性,为网格技术在地震领域内的进一步应用作了有意义的探索.      

川东南盆缘常压区页岩裂缝脉体特征及古压力演化

为了查明川东南盆缘常压页岩气区五峰组页岩裂缝脉体记录的古温度及古压力特征,揭示常压页岩气区储层压力降低的主要影响因素和页岩气散失机理.以松坎地区五峰组黑色碳质页岩裂缝脉体内的流体包裹体为主要研究对象,通过显微镜光学观察、阴极发光测试、包裹体测温和激光拉曼分析,结合埋藏-生烃-热史模拟,对裂缝脉体中的气-液两相盐水包裹体和高密度甲烷包裹体进行了系统研究.研究表明:松坎地区五峰组裂缝中主要存在着两期脉体充填,M1裂缝脉体形成时间距今约103~86 Ma,脉体较宽、阴极发光颜色为橘红色,其内甲烷包裹体捕获压力为82.6~91.5 MPa,反映燕山中期盆缘地区页岩气藏处在超压状态;M2裂缝脉体生长于M1裂缝脉体两侧,形成时间距今约90~72 Ma,脉体较窄、阴极发光颜色为暗红色,其内甲烷包裹体捕获压力为43.6~47.3 MPa.综合分析认为,川东南盆缘松坎地区五峰组在燕山期经历了由超压至常压的转变.燕山期以来的抬升剥蚀与褶皱变形导致地层内大量页岩气沿着滑脱层发生侧向运移和散失,地层压力快速下降.燕山晚期时,盆内稳定构造区页岩气藏仍处于超压状态,而盆缘地区已降至常压.