Surface analysis of pyrite in the No. 9 coal seam, Wuda Coalfield, Inner Mongolia, China, using high-resolution time-of-flight secondary ion mass-spectrometry

The chemical composition of pyrite in coal can be used to investigate its geological and mineralogical origin. In this paper, high-resolution time-of-flight secondary ion mass spectrometry (TOF-SIMS) was used to study the chemical composition of various pyrite forms in the No. 9 coal seam (S_t,d=3.46%) from the Wuda Coalfield, Inner Mongolia, northern China. These include bacteriogenic, framboidal, massive, cell-filling, fracture-filling, and nodular pyrites. In addition to Fe⁺ (⁵⁴Fe⁺, ⁵⁶Fe⁺, ⁵⁷Fe⁺), other fragment ions were detected in bacteriogenic pyrites, such as ²⁷Al⁺, Si⁺ (²⁸Si⁺, ²⁹Si⁺, ³⁰Si⁺), ⁴⁰Ca⁺, Cu⁺ (⁶³Cu⁺, ⁶⁵Cu⁺), Zn⁺ (⁶⁴Zn⁺, ⁶⁶Zn⁺, ⁶⁷Zn⁺, ⁶⁸Zn⁺), Ni⁺ (⁵⁸Ni⁺, ⁶⁰Ni⁺, ⁶²Ni⁺), and C₃H₇⁺. TOF-SIMS images show bacteriogenic pyrites are relatively rich in Cu, Zn, and Ni, suggesting that bacteria probably play an important role in the enrichment of Cu, Zn, and Ni during their formation. Intense positive secondary ion fragments from framboidal aggregates, such as ²⁷Al⁺, ²⁸Si⁺, ²⁹Si⁺, AlO⁺, CH₂⁺, C₃H₃⁺, C₃H₅⁺, and C₄H₇⁺, indicate that formation of the framboidal aggregates may have occurred together with clay mineral and organic matter, which probably serve as the binding substance. The intense ions of ²⁸Si⁺ and ²⁷Al⁺ from massive pyrites also suggest that their pores incorporated clay minerals during crystallization. Together with the lowest ²⁸Si⁺/²³Na⁺ value, the intense organic positive secondary ion peaks from cell-filling pyrites, such as C₃H₃⁺, C₃H₅⁺, C₃H₇⁺, and C₄H₇⁺, indicate that pyrite formation may have accompanied dissolution or disintegration of the cell. The intense P⁺ peak was observed only in the fracture-filling pyrite and the highest ²⁸Si⁺/²³Na⁺ value of fracture-filling pyrite reflects its epigenetic origin. Together with XRD and REEs data, the stronger ⁴⁰Ca⁺ in nodular pyrite than other pyrite forms shows seawater influence during its formation.     

吉林六批叶沟金矿床绢云母40Ar-39Ar 快中子活化法定年研究

在六批叶沟金矿石中,精选出与金矿物同期生成的绢云母作为样品,采用40Ar-39Ar快中子活化法测年,获得8个一致相连的平坦型绢云母年龄谱,tp=(190.28±0.30) Ma,氩同位素计算得等时线年龄为(189.98±0.58) Ma,两者完全吻合.等时线截距为(296.9±10.0) Ma,与大气氩的该值(295.5 Ma)相比较,两者完全吻合,表明该样品出自未受明显后期热力作用影响的非扰动体系.锁定六批叶沟金矿床主要成矿年龄为190 Ma左右,属早侏罗世的燕山早期.     

安徽峙门口铜—铁—金—硫矿床地球化学特征

峙门口铜—铁—金—硫矿床发育上部层状矿体和下部脉状矿体。上部层状矿石重晶石的δ~(34)S值为+14.10‰～+18.90‰。上部层状矿石黄铁矿和方铅矿的δ~(34)S值为+3.50‰～+5.84‰,下部脉状矿石黄铁矿的δ~(34)S值为+4.80‰～+6.80‰。下部脉状矿石中脉石英的δ~(18)O值为+14.3‰～+1 8.5‰,δ~(30)Si值为-0.3%0～-0.2‰。下部脉状矿石黄铁矿Re/Os比值为78.342～175.540,上(顶)部层状矿石中黄铁矿Re/Os比值为62.298～169.545。从下部脉状矿石到上部层状矿石,δ~(34)S值、Re/Os比值和流体包裹体温度249 ℃→97 ℃逐渐降低,~(206)Pb/~(204)Pb、~(207)Pb/~(204)Pb、~(208)Pb/~(204)Pb平均值和Os_总、Re、~(187)Re等含量逐渐增高。矿石黄铁矿Re-Os同位素等时线年龄303±33 Ma。地质地球化学特征反映峙门口铜—铁—金—硫矿床为海底热水喷流沉积成因。     

青海湖沉积物生物硅的环境意义初步研究

湖泊沉积物中生物硅含量的变化已经被广泛应用于评价湖泊生产力和古气候变化研究,但大型湖泊不同位置生物硅含量的时空变化及其与环境要素之间的关系仍缺乏详细的现代过程研究。通过对青海湖不同位置表层沉积样品的生物硅含量测定,建立其空间分布模式及最近数百年生物硅含量的时间序列。结果表明,青海湖表层沉积物生物硅含量变化范围是1.75 ％ ~2.98 ％ ,平均值为2.25 ％ 。与世界其他湖泊相比,青海湖生物硅含量处于相对较低水平,可能与其特殊的地理位置和气候条件有关。青海湖生物硅含量的空间分布规律与沉积物质量堆积速率以及陆源组分含量(如SiO2)相反,而与化学/生物沉积组分(如CaCO3)含量的空间分布规律大体一致,说明生物硅的空间分布受到陆源碎屑物质的"稀释效应"影响。时间序列上,生物硅含量与SiO2含量呈相反变化趋势,与指示降雨量变化的 C/N 比值也是反相变化,说明生物硅含量在时间序列上也受与气候条件密切相关的陆源输入的影响。青海湖湖心低沉积速率区域的生物硅指标具有指示古气候变化的潜力。     

太行山红层磁学性质及古环境意义初探

环境磁学研究磁性矿物特征（磁性矿物类型、含量和颗粒大小）及其转化与环境关系,在不同地质时期古气候和古环境重建中得到广泛应用。本文将磁学方法应用于太行山中元古界红层研究,并从其磁学性质角度初步探讨太行山红层的古环境。对太行山红色石英砂岩和紫红色砂质泥岩样品进行了高温磁学和常温磁学系统测试。结果显示,太行山红层主要以硬磁性的赤铁矿为主,包含少量磁铁矿,部分样品赤铁矿是唯一磁性矿物;磁性颗粒大小以单畴为主;红色石英砂岩不同样品间磁性差别显著,反映沉积环境的不稳定性。紫红色砂质泥岩中的青灰色层表现为顺磁性特征,原因可能是紫红色砂质泥岩中的赤铁矿在后期还原环境下溶解或转化为弱磁性矿物所致,说明紫红色层并非形成于长期的水下还原环境。太行山红层中普遍存在的红色波痕和泥裂说明水环境对其有短暂影响,但是红层及赤铁矿的富集说明其长时间处于氧化环境,推断太行山红层可能形成于高度氧化的陆地环境。     

利用QuikSCAT/NCEP混合风场及WAVEWATCH模拟东中国海风浪场

将国际上比较成熟的海浪模式WAVEWATCH-Ⅲ移植到东中国海,采用QuikSCAT卫星遥感资料与NCEP数据混合风场作为强迫项,对该海区2000年1月23日至31日的一个大风天气过程下的风浪场进行了模拟计算。计算结果与浮标观测资料的对比结果说明,所获得的风浪场数值结果不但具有较高的时空分辨率,其精度也是比较高的。     

广东三水盆地晚自垩世—始新世古地磁研究及构造意义

对广东三水盆地上白垩统三水组、大　山组、古新统莘庄组及始新统　心组、宝月组的系统的古地磁研究结果表明：（１）旋转运动是该区构造运动的主要形式，顺时针旋转盆地拉张发育，这时针旋转盆地挤压衰亡，发育的程度与旋转角度有关；（２）始新世该区旋转方向由顺时针旋转变为道时针旋转，对应于太平洋－库拉板块对欧亚板块作用方向的改变，说明三水盆地的形成发育与太平洋－库拉板块对欧亚板块的作用密切相关；（３）三水盆地所在的华南地块从晚白垩世至始新世在纬向上不存在明显的运动，一直停留在略低于现今纬度的位置上。     

The Characteristics and Related Problems of the Orbits Around the Earth-Moon Libration Points

Due to the specific dynamics, the probes located at the halo orbits or Lissajous orbits around the Earth-Moon collinear libration point L₁ or L₂ are always studied in the synodic system to understand their trajectories. In fact, they are also orbiting the Earth in a distant Keplerian ellipse. Because of their intrinsic orbital instability, in the orbit prediction the initial errors propagate more prominently than those of the normal orbiting satellites, this requires special attention in the orbit design, maneuver, and control. Despite of all this, they are similar to the normal orbiting satellites in orbit determination and hardly require other special attentions. In this paper, the quantitative results of error propagation under the unstable dynamics, together with the theoretical analysis are presented. The results of precise orbit determination and short-arc orbit predictions are also shown, and compared with the results from the Beijing Aerospace Control Center.     

莱州湾温带风暴潮预报研究

本文依据莱州湾羊角沟、夏营两站建国以来的风暴增水资料，对莱州湾建国后发生的风暴潮进行了统计分析，并探讨了温带风暴潮产生的物理机制，此外还对莱州湾温带风暴增水以及诱发增水的天气形势进行了分析分类。在此基础上建立了莱州湾温带风暴潮统计预报方法，并在作业预报中对模型进行了检验，取得较为理想的效果。     

混凝土核心筒的水平双向循环加载试验研究

为了研究地震多维性对于混凝土核心筒抗震性能的影响,对大尺寸混凝土核心筒试件进行了水平双向加载下的拟静力试验.重点研究在双向加载下,核心筒的破坏形态与机理、承载能力、变形性能、刚度退化等方面的问题.结果表明,由于水平双向加载下简体一个方向的损伤影响到另一个方向的性能,因而对混凝土核心筒的抗震能力造成不利影响.因此,在实际工程中应合理地考虑这种影响,这对于确保混凝土核心筒的抗震安全具有重要意义.