Annual and seasonal variability of precipitation in Vojvodina,Serbia

Annual and seasonal variability of precipitation observed at 92 stations in Vojvodina (Serbia) were analyzed during the period 1946–2006. The rainfall series were examined by means of the empirical orthogonal functions (EOF). The first set of singular vectors explains from 68.8 % (in summer) to 81.8 % (in winter) of the total variance. The temporal variability of the time series associated with the main EOF configurations (the principal components, PCs) was examined using the Mann–Kendall test and the spectral analysis. The time series of PC1 revealed decreasing trend in the winter and spring precipitation and increasing trend in the autumn, summer, and annual precipitation. The relationships between the first PC and circulation patterns, such as the North Atlantic Oscillation (NAO), the East Atlantic (EA) pattern, and East Atlantic/West Russia pattern, were also investigated. The PC1, displaying temporal behavior of the first mode, demonstrated evident correspondence with the NAO index in analysis of the annual, winter, and autumn precipitation. Power spectra of the PC1 show statistically significant oscillations of about 3.3 years for the spring precipitation and about 8 and 15 years for the winter precipitation. Comparisons with spectral analysis of authors for some regions in Europe, most of them in the Mediterranean domain, show that similar periodicities are detected.     

A critical evaluation of using bulk sediment instead of fine fraction in environmental marine studies, investigated on example of Rijeka harbor, Croatia

This work tested the preferential use of fine (<63 μm) or bulk sediment (<2 mm) in environmental research of marine sediments in the Eastern Adriatic. Fine fraction sediment containing silt and clay (<63 μm), predominating in the studied area, was examined to evaluate past and present anthropogenic inputs and to test our hypothesis that investigation of bulk sediment should be preferred. Following aqua regia digestion, chemical analyses of 58 elements were performed by ICP/OES, ICP-MS and cold vapor AAS, and statistical analysis was performed. The concentrations of the majority of the analyzed elements increased with age of the sediment, except for Ag and Sn, which had higher concentrations in recent sediments. The previous main sources of metal contamination in Rijeka harbor were now abandoned municipal-sewage outflow and oil refinery, and continuing harbor activities and antifouling paint use. All activities except of antifouling paint use have been decreasing significantly. Anomalies of selected elements were determined by the box-plot method. More anomalies were found in the bulk sediment than in the fine fraction. Results of Q-modality clustering and factor analysis in the fine fraction almost correlate with that applied on bulk sediments. Thus, it can be said that the differences between the element distribution in the bulk and fine fraction are not statistically significant. Our conclusion is that analysis of bulk marine sediment gives a better insight into the state of pollution and supports previous recommendations to use bulk sediment as a chosen media for environmental studies.     

Effects of sinuosity factor on hydrodynamic parameters estimation in karst systems: a dye tracer experiment from the Beyyayla sinkhole (Eskişehir,Turkey)

The sinuosity factor (SF) is a critical value in karst systems in terms of estimating their hydrodynamic parameters including groundwater velocity, coefficient of dispersion, etc., through dye tracer experiments. SF has been used in a number of different dye tracer experiments in karstic systems to estimate a representative flow path. While knowing SF is crucially important in the estimation of hydrodynamic parameters, its calculation is associated with significant uncertainty due to the complexity of subsurface karstic features. And yet, only a few studies have discussed its uncertainties, which might lead some errors in estimation of hydrodynamic parameters from dye tracer experiment. In this study, dye tracer experiments were conducted in two consecutive years (2003 and 2004) representing low and high flow conditions in the Beyyayla sinkhole (Eski?ehir, Turkey) where the flow path is well known. Uranine was used in experiments as a tracer and QTRACER computer program was used to determine the hydrodynamic properties of the Beyyayla karst system as well as to gain insights into the effects of SF from dye tracer experiments on estimated parameters. The results showed that the breakthrough curve follows a unimodal and a bimodal distribution in low and high flow conditions, respectively. These different distributions stem from the water transport mechanisms, where velocities were calculated as 58.2 and 93.6 m h^?1 during low and high flow conditions observed in a spring emerging from the south side of the studied system. The results also show that the coefficient of dispersion, Reynolds number, and Peclet number increased and longitudinal dispersivity decreased with the higher flow rate. Furthermore, the estimated parameters did not vary with either the flow conditions or the tracer transit time, but they have shown some variations with SF. When SF was increased by 50 %, a change in these parameters was obtained in the range of 50–125 %.     

Atmospheric pollution in North Africa (ecosystems–atmosphere interactions): a case study in the mining basin of El Guettar–M’Dilla (southwestern Tunisia)

Air quality transcends all scales with in the atmosphere from the local to the global with handovers and feedbacks at each scale interaction. Air quality has manifold effects on health, ecosystems, heritage and climate. New insights into the characterisation of both natural and anthropogenic emissions are reviewed looking at both natural (e.g. dust and lightning) as well as plant emissions. In the phosphate mining area (El Guettar–M’Dilla basin: Southwestern Tunisia), several diseases have been known as cancer, respiratory, allergies, cardiovascular, dental fluorosis, stress, etc. These diseases are directly related with the installation of the industrial sector of the CPG (from 1896) and the deforestation and the ecosystem degradation (fauna and flora).     

Preservation of diagenetic products of β-carotene in sedimentary rocks from the Lopare Basin (Bosnia and Herzegovina)

Sedimentary rocks from the saline formation of the Lopare Basin were investigated. Sediments contain a moderate amount of immature to marginally mature algal organic matter deposited under slightly reducing to anoxic and slightly saline to hypersaline conditions. Almost all of the samples contain β-carotane in a relatively high quantity, and in some, it represents the most abundant compound in the total distribution of hydrocarbons. The objective of the study was to determine the conditions that are favourable to precursors of β-carotene and/or the preservation of the carotenoid hydrocarbon skeleton. Moreover, the dominant transformation pathways of β-carotene under different redox and salinity conditions, which lead to the formation of aromatic carotenoids were defined.     

青海省都兰县阿拉克湖地区水系沉积物地球化学特征及找矿方向

分析了区内的水系沉积物地球化学参数特征及其元素的相关性,认为元素(地球化学)异常(高值区)严格受东昆中断裂带、东昆南断裂带、布青山南坡乌断裂带,以及阿尼玛卿蛇绿岩带和东昆中蛇绿岩带,古-中元古代地层、岩体接触带、热液活动、脉岩等因素联合控制。根据异常特征与成矿地质条件,圈定了找矿远景区5个,且为该区下一步的找矿工作指明了方向。     

Direct detection of the secondary spectrum of the interacting eclipsing binary TX UMa

Eclipsing binary TX UMa was observed with the D.A.O. high-dispersion spectrographs in 1969–1970, with emphasis on the detailed coverage of the primary minimum. One spectrum was taken exclusively within totality, thus exhibiting an uncontaminated spectrum of the secondary component. This leads to spectral reclassification of the secondary (F6 IV). The narrowing of the line profile of the H-line in totality is interpreted in terms of synchronous rotation of the secondary (v sini80 km s^–1) while the primary rotates faster (v sini130 km s^–1) than synchronously (v sini50 km s^–1). Although the secondary does not fill in its Roche lobe fully, the system exhibits pronounced indications of rather strong physical interaction. This is now supported also by the profound changes of the line profiles of the H-line with phase.     

Coherence of river and ocean conditions along the US West Coast during storms

The majority of water and sediment discharge from the small, mountainous watersheds of the US West Coast occurs during and immediately following winter storms. The physical conditions (waves, currents, and winds) within and acting upon the proximal coastal ocean during these winter storms strongly influence dispersal patterns. We examined this river–ocean temporal coherence for four coastal river–shelf systems of the US West Coast (Umpqua, Eel, Salinas, and Santa Clara) to evaluate whether specific ocean conditions occur during floods that may influence coastal dispersal of sediment. Eleven years of corresponding river discharge, wind, and wave data were obtained for each river–shelf system from USGS and NOAA historical records, and each record was evaluated for seasonal and event-based patterns. Because near-bed shear stresses due to waves influence sediment resuspension and transport, we used spectral wave data to compute and evaluate wave-generated bottom-orbital velocities. The highest values of wave energy and discharge for all four systems were consistently observed between October 15 and March 15, and there were strong latitudinal patterns observed in these data with lower discharge and wave energies in the southernmost systems. During floods we observed patterns of river–ocean coherence that differed from the overall seasonal patterns. For example, downwelling winds generally prevailed during floods in the northern two systems (Umpqua and Eel), whereas winds in the southern systems (Salinas and Santa Clara) were generally downwelling before peak discharge and upwelling after peak discharge. Winds not associated with floods were generally upwelling on all four river–shelf systems. Although there are seasonal variations in river–ocean coherence, waves generally led floods in the three northern systems, while they lagged floods in the Santa Clara. Combined, these observations suggest that there are consistent river–ocean coherence patterns along the US West Coast during winter storms and that these patterns vary substantially with latitude. These results should assist with future evaluations of flood plume formation and sediment fate along this coast.     

Aquifer heterogeneity determination through the slope method

In arid‐region wadis, groundwater storage lies within shallow Quaternary alluvium deposits, which are connected with the present‐day hydrological cycle and, therefore, are replenished due to occasional runoff and flash flood occurrences. The groundwater resources are precious in these environments; therefore, their potentiality must be assessed with care in the best manner. The aquifer potentiality is calculated after the storativity and transmissivity parameter estimations, which require rather long‐duration field tests with restrictive assumptions in the theoretical model developments, such as the homogeneity and isotropy. It is the main purpose of this paper to expose the fundamentals of the slope‐matching procedure (SMP) and its application for short‐duration field tests in arid‐region aquifers. In this manner, the subsurface hydrogeological behaviours of the bored land pieces at and around the well locations are prospected in a detailed and refined manner. It is shown that in many cases the classical techniques are appropriate, inconvenient and inapplicable with conclusive reliable results and conclusions. The application of the SMP is presented for some aquifer tests from the central western part of the Kingdom of Saudi Arabia. Copyright © 2007 John Wiley & Sons, Ltd.