Taxonomic sufficiency for soft-bottom sublittoral mollusks assemblages in a tropical estuary, Guanabara Bay, Southeast Brazil

Guanabara Bay (GB) is considered to be one of the most polluted environments of the southern Brazilian coastline. This typical estuarine system is impacted by the heavy discharge of both industrial and domestic waste from the Rio de Janeiro metropolitan area. The mollusc community structure and distribution was investigated between 2000 and 2001, using a three month sampling design of 38 stations, according to austral seasons. Species abundance was aggregated into progressively higher taxa matrices (genus, family, order) and were analysed using multivariate techniques. Mollusc distribution in GB varied significantly in space and time and was probably ruled by the organic enrichment effects of hypoxia and altered redox conditions coupled with prevailing patterns of circulation. Within the sectors of GB an increasing gradient in mollusc diversity and occurrence was observed, ranging from the azoic and impoverished stations in the inner sector to a well-structured community in terms of species composition and abundance inhabiting the outer sector. The non-metric multidimensional scaling (nMDS) and cluster analysis showed similar results when species were aggregated into genera and families, while greater difference occurred at coarser taxonomic identification (order). The literature about taxonomic sufficiency has demonstrated that faunal patterns at different taxonomic levels tend to become similar with increased pollution. In Guanabara Bay, an analysis carried out solely at family level is perfectly adequate to describe the ecophysiological stress. Further aggregation to order level changed the perceived patterns of differences. However, a different taxonomic resolution can be chosen depending on the type of ecological patterns investigated.     

Occurrence and fate of polycyclic aromatic hydrocarbons in the coastal surface microlayer

Polycyclic aromatic hydrocarbons (PAHs) were measured in the coastal sea surface microlayer (SML), the sub-surface waters (SSW) and the overlying atmosphere in order to investigate the influence of the SML on contaminant enrichment and air-sea exchange. Samples were collected at two contrasting locations of the NW Mediterranean, one urban influenced (off Barcelona, Spain) and another comparatively clean (off Banyuls-sur-Mer, France). Statistical data analysis confirmed the accumulation of PAHs in the SML with respect to the SSW (20.3+/-9.1 vs. 13.1+/-10.0 ng L(-1) in the dissolved phase; 709+/-207 vs. 158+/-111 ng g(-1) in the particulate phase). This accumulation was higher at the contaminated location (Barcelona station) compared with the more pristine one, with PAH enrichments 1.5 and 4.5 times higher for the dissolved and particulate phases, respectively, indicating that the enrichment of PAHs in the SML is dominated by particle transport processes.     

Medium-term responses of rocky bottoms to sewage discharges from a deepwater outfall in the NE Atlantic

An investigation on the effects of deepwater outfall discharges on the status of rocky reef communities was carried out. The sanitation system was found to be an environmentally suitable option for the protection of those habitats situated in high energy coastal environments. Sediments occurring between the predominating rocky substrates showed low values of the fine fraction (<63microm) and organic matter content. In addition, high average concentrations of Cd, Hg and Zn were found in these sediments, though these values were similar to those registered in non-affected sites, far away from the outfall. On the other hand, those assemblages typical of hard substrates that settled near the outfall showed an increase in total richness and abundance of macroinvertebrates. Moreover, the average number of species of each taxonomic group, a good indicator of the maintenance of the previous trophic structure, only varied considerably over time at the rip-rap protection. In a global context, those changes were not directly related to the discharge disturbances, but to the natural variability or the successional processes occurring within those communities. Only communities dwelling in the rip-rap protection area were affected by the proximity of the discharges.     

High-pressure granulite from Western Kunlun,northwestern China: Its metamorphic evolution,zircon SHRIMP U-Pb ages and tectonic implication

High-pressure mafic granulites occurring as lenticular bodies within garnet-amphibolites in Kangxiwar Fault have been first reported in this paper. The P-T conditions of two metamorphic stages were ob-tained using calibrated geothermal barometers and ThermoCalc Program. The peak metamorphic con-dition of these high-pressure granulites is about 760―820℃,1.0―1.2 GPa and the retrograde meta-morphic condition is about 620―720℃,0.7―0.8 GPa. The petrological studies show that they have a near-isobaric cooling P-T...     

Observations of tectonic microdisplacements in Europe in relation to the Iran 1997 and Turkey 1999 earthquakes

Long-term repeated measurements of microdisplacements in tectonic fault structures of various parts of Central Europe and the Balkan Mountains showed that displacement trends changed significantly at several points in the period from 1997 through 2000; afterward, long-term trends were restored. This phenomenon took place in the periods of strong (M > 7) earthquakes in Iran (1997) and in the North Anatolian fault zone in Turkey (1999). Two strong Izmit earthquakes of 1999 in Turkey at distances of 600 km from the Balkan Peninsula and 1400 km from observation points in Central Europe were the main seismic events of the period studied. Apparently, the crustal deformation due to the sources of the aforementioned earthquakes reaches the central part of the European craton. Anomalous displacements in some areas occurred due to deformation propagating for great distances in the heterogeneous block medium of the West European part of the Eurasian plate. Changes in stresses can be caused by impulsive deformations of various intensities acting on some structural units (fault segments) at various distances.     

Heat capacity, entropy, and magnetic properties of jarosite-group compounds

Jarosite phases are common minerals in acidic, sulfate-rich environments. Here, we report heat capacities (C _p) and standard entropies (S°) for a number of jarosite samples. Most samples are close to the nominal composition AFe₃(SO₄)₂(OH)₆, where A = K, Na, Rb, and NH₄. One of the samples has a significant number of defects on the Fe sites and is called the defect jarosite; others are referred to as A-jarosite. The samples, their compositions, and the entropies at T = 298.15 K are:

A parallel global-implicit 2-D solver for reactive transport problems in porous media based on a reduction scheme and its application to the MoMaS benchmark problem

In this article, an approach for the efficient numerical solution of multi-species reactive transport problems in porous media is described. The objective of this approach is to reformulate the given system of partial and ordinary differential equations (PDEs, ODEs) and algebraic equations (AEs), describing local equilibrium, in such a way that the couplings and nonlinearities are concentrated in a rather small number of equations, leading to the decoupling of some linear partial differential equations from the nonlinear system. Thus, the system is handled in the spirit of a global implicit approach (one step method) avoiding operator splitting techniques, solved by Newton’s method as the basic algorithmic ingredient. The reduction of the problem size helps to limit the large computational costs of numerical simulations of such problems. If the model contains equilibrium precipitation-dissolution reactions of minerals, then these are considered as complementarity conditions and rewritten as semismooth equations, and the whole nonlinear system is solved by the semismooth Newton method.