Electrical conductivity of rocks in the heating and cooling cycle

Summary The values of the electrical conductivity, recorded during the heating and cooling cycle, of eclogites and basalts are compared. The observed difference in the values is explained by reversible and irreversible changes which take place in the samples.     

Changes in the internal spatial structure of post-communist Prague*

The article overviews the most important changes in the internal urban structure of Prague since 1989. Post-communist urban development has been influenced by government-directed reforms of political and economic system, internationalisation and globalisation, public policies favouring unregulated market development, economic restructuring in terms of deindustrialisation and growth of producer services, and increasing social differentiation. The three most transparent processes of urban change in Prague have been (1) commercialisation of the historical core; (2) revitalisation of some inner city neighbourhoods; and (3) residential and commercial suburbanisation in the outer city. This revised version was published online in July 2006 with corrections to the Cover Date.     

Chemical composition and physical properties of lithium-iron micas from the Krušné hory Mts. (Erzgebirge)

Compositions of natural lithium-iron micas are approximated best by the sidero-phyllite-polylithionite join. These micas contain little or no magnesium and manganese. Their octahedral sheets contain close to two trivalent cations (mainly aluminum) in small crystallographic sites and a variable quantity of lithium and R⁺² (mainly iron) in large sites. Octahedral vacancies are situated mostly in large sites. Lithium and R⁺² approach a 44 replacement relationship in micas with octahedral occupancy close to six. Lithium and fluorine show a good positive correlation (small excess of fluorine over lithium), which indicates a crystallochemical association between them. There is a less distinct positive correlation between lithium and R⁺⁴.Based on simplifications, a calculation shows that about two-thirds of octahedral vacancies are caused by substitutions within the octahedral sheet, one-third, by tetrahedral substitutions. Different methods of calculating the crystallochemical formula yield slightly different numbers of octahedral vacancies, but do not affect the mica's position in plots of physical parameters against composition. If a crystallochemical formula is calculated from analysis of a mica contaminated with quartz, topaz, or feldspar, the apparent number of octahedral vacancies increases; such a formula exhibits unusual behavior in composition plots.     

Arsenic in contaminated soils and anthropogenic deposits at the Mokrsko,Roudný, and Kašperské Hory gold deposits,Bohemian Massif (CZ)

Soil, mine tailing, and waste dump profiles above three mesothermal gold deposits in the Bohemian Massif with different anthropogenic histories have been studied. Their mineralogical, major element, and arsenic (As) contents and the contents of secondary arsenic minerals were analyzed. The As-bearing minerals were concentrated and determined using X-ray diffraction (XRD) analysis, the Debye-Scherrer powder method, scanning electron microscopy (SEM), and energy-dispersive microanalysis (EDAX). The amorphous hydrous ferric oxides (HFO), As-bearing goethite, K-Ba- or Ca-Fe- and Fe- arsenates pharmacosiderite, arseniosiderite, and scorodite, and sulfate-arsenate pitticite were determined as products of arsenopyrite or arsenian pyrite oxidation. The As behaviour in the profiles studied differs in dependence on the surface morphology, chemical and mineralogical composition of the soil, mine wastes or tailings, oxidation conditions, pH, presence of (or distance from) primary As mineralization in the bedrock, and duration of the weathering effect. Although the primary As mineralization and the bedrock chemical composition are roughly similar, there are distinct differences in the As behaviour amongst the Mokrsko, Roudný and Kaperské Hory deposits.     

Seismically active fracture zones and distribution of large accumulations of metals in the central part of Andean South America

 The analysis of the geometry of distribution of earthquake foci in the central part of Andean South America between 18° and 34°S made the delineation of several seismically active fracture zones in the continental wedge overlying the subducting Nazca plate possible. Correlation of their position with the distribution of hypogene accumulations of metals revealed that the majority of large mineral deposits and mining districts are situated in the outcrops of these fracture zones. We present geometrical documentation (map of epicentres, vertical and longitudinal cross sections) of the most important fracture zones and data on mineralogical composition, genetic type and available radiometric ages of mineral deposits. Sixteen mining districts in Chile, and 24 in Argentina, were attributed to the seismically active fracture zones. Major mining districts and individual large mineral deposits occur in six seismically active fracture zones roughly parallel to the axis of the Peru-Chile trench (Carachas-Portillo, Choquelimpie, Iquique, Domeyko, Río Blanco-Los Bayos and Farellones F.Z.), in six fracture zones roughly perpendicular to the trench (El Salvador, Maricunga, Jaroma, Ujina, Tumbaya and Incahuasi-León Muerto F.Z.) and in two fracture zones oriented at an angle of about 45° in relation to the direction of the presently active Andean subduction (Aconcagua and Sierra del Volcán F.Z.). The occurrences of large mineral deposits of different ages show that these fracture zones were also active in the geological past and represent sites of permanent re-opening of paths allowing ore-bearing solutions and long-term accumulation of large amounts of metals to occur in relatively restricted domains of the Earth's crust. The mining districts with dated mineral deposits are arranged into four periods of hypogene mineralization: Upper Miocene-Pliocene, Upper Oligocene-Middle Miocene, Upper Eocene-Middle Oligocene, Lower Paleocene-Upper Eocene. These periods of metallogenic activity correlate well with four supposed Andean subduction cycles active in the Tertiary. The occurrence of mineral deposits of different ages in recently active fracture zones can be used as an important evidence in favour of long-term spatial permanence and activity of these zones and as a guide for the discovery of further mineral deposits hidden under young sedimentary and volcanic cover in the fracture zones. Received: 6 November 1997 / Accepted: 20 April 1999