Anomalous optical variations in the grossular garnet from the Eden Mills,Belvidere Mountain (Vermont,USA)

The optical anomalies, and surface and lamellar textures of a birefringent grossular garnet crystal from the Eden Mills, Belvidere Mountain, Vermont, USA, have been investigated by optical polarizing microscope, electron-probe micro-analyzer, back-scattered electron imaging, infrared spectroscopy, and single-crystal X-ray diffractometer from the standpoint of crystal growth. This grossular shows one-to-one correlation between natural surface features and its internal textures under crossed polarizers. Electron-probe micro-analyzer (EPMA) gave average chemical composition in (110) thin section, of bright lamella {Ca_2.97Mn_0.06}_∑3.03 [Al_1.59Fe_0.37Ti_0.01]_∑1.97(Si_3.00)_∑3.00 (Gros_79.5And_18.9Sps_1.6) and of dark host {Ca_2.99Mn _0.06}_∑3.05 [Al_1.73Fe_0.26 Ti_0.01]_∑2.00(Si_2.97OH_0.03)_∑3.00 (Gros_85.4And₁₃Sps_1.6). The correspondence of surface features and the internal textures with spiral or pyramidal growth mechanism suggest that the internal textures of the Eden Mills grossular are formed during growth process. The optical vibrational orientations and the growth steps inclination along [001] and \( \left[\overset{-}{1}10\right] \) directions predict monoclinic symmetry. With X-ray diffractometer (XRD) method, pseudocubic parameters are a = 11.839(2) Å, b = 11.855(1) Å, and c = 11.868(2) Å with interaxial angles α = 90.00(1)°, β = 89.99(1)°, and γ = 90.02(2)° that show orthorhombic symmetry of this crystal. Lamellar texture of Al³⁺-rich host with Fe³⁺-rich lamella infers cation ordering at octahedral site of the garnet structure. IR data favors the non-cubic orientation of [(OH) ₄] at tetrahedral position in this grossular structure.     

Benthic Carbon Mineralization and Nutrient Turnover in a Scottish Sea Loch: An Integrative In Situ Study

Based on in situ microprofiles, chamber incubations and eddy covariance measurements, we investigated the benthic carbon mineralization and nutrient regeneration in a ~65-m-deep sedimentation basin of Loch Etive, UK. The sediment hosted a considerable amount of infauna that was dominated by the brittle star A. filiformis. The numerous burrows were intensively irrigated enhancing the benthic in situ O₂ uptake by ~50 %, and inducing highly variable redox conditions and O₂ distribution in the surface sediment as also documented by complementary laboratory-based planar optode measurements. The average benthic O₂ exchange as derived by chamber incubations and the eddy covariance approach were similar (14.9 ± 2.5 and 13.1 ± 9.0 mmol m^?2 day^?1) providing confidence in the two measuring approaches. Moreover, the non-invasive eddy approach revealed a flow-dependent benthic O₂ flux that was partly ascribed to enhanced ventilation of infauna burrows during periods of elevated flow rates. The ratio in exchange rates of ΣCO₂ and O₂ was close to unity, confirming that the O₂ uptake was a good proxy for the benthic carbon mineralization in this setting. The infauna activity resulted in highly dynamic redox conditions that presumably facilitated an efficient degradation of both terrestrial and marine-derived organic material. The complex O₂ dynamics of the burrow environment also concurrently stimulated nitrification and coupled denitrification rates making the sediment an efficient sink for bioavailable nitrogen. Furthermore, bioturbation mediated a high efflux of dissolved phosphorus and silicate. The study documents a high spatial and temporal variation in benthic solute exchange with important implications for benthic turnover of organic carbon and nutrients. However, more long-term in situ investigations with like approaches are required to fully understand how environmental events and spatio-temporal variations interrelate to the overall biogeochemical functioning of coastal sediments.     

Low multipath antennas for GNSS-based attitude determination systems applied to high-altitude platforms

High-altitude platforms (HAPs) are a flexible and attractive technology for providing innovative wireless services. These aerial platforms can be successfully employed for mobile or broadband communications and for disaster monitoring or response. However, one of the open issues is whether HAP stations can provide reliable services without temporal outages owing to stratospheric winds that can cause positional and attitude instabilities thus affecting the communication system operation. To counteract this issue, one possible solution is to use reconfigurable antennas whose pointing direction can be adjusted depending on the platform spatial orientation. However, this would require real-time three-axial attitude data. As a possible solution, this paper will review the potential of GNSS-based attitude determination systems with reference to HAP stations. In particular, it will be shown how the use of a particular class of low multipath and lightweight antennas can provide a high degree of accuracy without altering the avionic ballast.     

Effects of temporally correlated infiltration on water flow in an unsaturated–saturated system

Effects of temporally correlated infiltration on water flow in an unsaturated–saturated system were investigated. Both white noise and exponentially correlated infiltration processes were considered. The moment equations of the pressure head (ψ) were solved numerically to obtain the variance and autocorrelation functions of ψ at 14 observation points. Monte Carlo simulations were conducted to verify the numerical results and to estimate the power spectrum of ψ (S _ψψ ). It was found that as the water flows through the system, the variance of the ψ (\( \sigma_{\psi }^{2} \)) were damped by the system: the deeper in the system, the smaller the \( \sigma_{\psi }^{2} \), and the larger the correlation timescale of the infiltration process (λ _I ), the larger the \( \sigma_{\psi }^{2} \). The unsaturated–saturated system gradually filters out the short-term fluctuations of ψ and the damping effect is most significant in the upper part of the system. The fluctuations of ψ is non-stationary at early time and becomes stationary as time progresses: the larger the value of λ _I , the longer the non-stationary period. The correlation timescale of the ψ (λ _ψ ) increases with depth and approaches a constant value at depth: the larger the value of λ _I , the larger the value of λ _ψ . The results of the estimated S _ψψ is consistent with those of the variance and autocorrelation function.     

Pulsatory characteristics of wind velocity in sand flow over typical underlying surfaces

Pulsatory characteristics of wind velocity in sand flow over Gobi and mobile sand surface have been investigated experimentally in the wind tunnel. The primary goal of this paper is to reveal the relation- ship between pulsatory characteristics of instantaneous wind speed in sand flow and the motion state of sand grains. For a given underlying surface, pulsation of wind velocities in sand flow on different heights has a good correlation. As the space distance among different heights increases, fluctuation of instantaneous wind speed presents a decreasing trend and its amplitude is closely related to the mo- tion state of sand grains and their transport. Pulsatory intensity increases with the indicated wind speed, but its relative value does not depend on it, only agrees with height.     

Groundwater sustainability and groundwater/surface-water interaction in arid Dunhuang Basin,northwest China

The Dunhuang Basin, a typical inland basin in northwestern China, suffers a net loss of groundwater and the occasional disappearance of the Crescent Lake. Within this region, the groundwater/surface-water interactions are important for the sustainability of the groundwater resources. A three-dimensional transient groundwater flow model was established and calibrated using MODFLOW 2000, which was used to predict changes to these interactions once a water diversion project is completed. The simulated results indicate that introducing water from outside of the basin into the Shule and Danghe rivers could reverse the negative groundwater balance in the Basin. River-water/groundwater interactions control the groundwater hydrology, where river leakage to the groundwater in the Basin will increase from 3,114?×?10⁴ m³/year in 2017 to 11,875?×?10⁴ m³/year in 2021, and to 17,039?×?10⁴ m³/year in 2036. In comparison, groundwater discharge to the rivers will decrease from 3277?×?10⁴ m³/year in 2017 to 1857?×?10⁴ m³/year in 2021, and to 510?×?10⁴ m³/year by 2036; thus, the hydrology will switch from groundwater discharge to groundwater recharge after implementing the water diversion project. The simulation indicates that the increased net river infiltration due to the water diversion project will raise the water table and then effectively increasing the water level of the Crescent Lake, as the lake level is contiguous with the water table. However, the regional phreatic evaporation will be enhanced, which may intensify soil salinization in the Dunhuang Basin. These results can guide the water allocation scheme for the water diversion project to alleviate groundwater depletion and mitigate geo-environmental problem.     

Observed daily large-scale rainfall patterns during BOBMEX-1999

A daily rainfall dataset and the corresponding rainfall maps have been produced by objective analysis of rainfall data. The satellite estimate of rainfall and the raingauge values are merged to form the final analysis. Associated with epochs of monsoon these rainfall maps are able to show the rainfall activities over India and the Bay of Bengal region during the BOBMEX period. The intra-seasonal variations of rainfall during BOBMEX are also seen using these data. This dataset over the oceanic region compares well with other available popular datasets like GPCP and CMAP. Over land this dataset brings out the features of monsoon in more detail due to the availability of more local raingauge stations.     

Damping characteristics of friction damped braced frame and its effectiveness in the mega-sub controlled structure system

Based on energy dissipation and structural control principle, a new structural configuration, called the mega- sub controlled structure (MSCS) with friction damped braces (FDBs), is first presented. Meanwhile, to calculate the damping coefficient in the slipping state a new analytical method is proposed. The damping characteristics of one-storey friction damped braced frame (FDBF) are investigated, and the influence of the structural parameters on the energy dissipation and the practical engineering design are discussed. The nonlinear dynamic equations and the analytical model of the MSCS with FDBs are established. Three building structures with different structural configurations, which were designed with reference to the conventional mega-sub structures such as used in Tokyo City Hall, are comparatively investigated. The results illustrate that the structure presented in the paper has excellent dynamic properties and satisfactory control effectiveness.