安徽沿江地区晚石炭世黄龙组白云岩地球化学特征及其成因研究

安徽沿江地区晚石炭世黄龙组白云岩广泛发育,主要为晶粒白云岩,其次是角砾白云岩和残余颗粒白云岩。地球化学分析表明,安徽沿江地区黄龙组白云岩中Fe、Mn、Sr、Na含量分别为:2 567×10^-6(1 600×10^-6～4 400×10^-6)、353×10^-6(166×10^-6～742×10^-6)、109.7×10^-6(69.0×10^-6～176.5×10^-6)、288×10^-6(100×10^-6～700×10^-6),稀土元素总量为7.29×10^-6(2.56×10^-6～20.82×10^-6),ΣLREE/ΣHREE比值平均为3.07(1.16～10.17),经海水标准化后,显示LREE富集,HREE相对亏损,δCe平均为4.53(2.82～7.78),正异常显著,δEu平均为1.85(0.94～2.92),配分模式曲线显示白云岩化流体来自海水。白云岩中可见蒸发岩类或蒸发构造。综合分析认为该地区白云岩主要为准同生成因,部分为埋藏成岩成因,其中角砾白云岩为准同生成因,怀宁地区白云岩δEu平均为2.38(1.91～2.92),正异常显著,表明后期受到热液流体影响。     

Correlations between 11B NMR parameters and structural characters in borate and borosilicate minerals investigated by high-resolution MAS NMR and ab initio calculations

Borates consisting of diverse fundamental building blocks (FBB) formed from complex polymerization of planar triangular [Bϕ₃] groups and tetrahedral [Bϕ₄] groups, where ϕ = O and OH, provide an excellent opportunity for investigation of correlations between the NMR parameters and local structures. However, previous studies suggested that the ¹¹B NMR parameters in borates are insensitive to local structural environments other than the B coordination number, in contrast to those documented for ²⁹Si, ²³Na and ²⁷Al in silicates, and no correlation between ¹¹B chemical shifts and the sum of bond valences has been established for borate minerals with hydroxyl groups or molecular water in the structures. In this study, high-resolution NMR spectra have been acquired at the ultra high field of 21 T as well as at 14 T for selected borate and borosilicate minerals, and have been used to extract high-precision NMR parameters by using combined ab initio theoretical calculations and spectral simulations. These new NMR parameters reveal subtle correlations with various structural characters, especially the effects of the ¹¹B chemical shifts from the bridging oxygen atom(s), site symmetry, symmetry of FBB, the sum of bond valences, as well as the next-nearest-neighbor cations and hydrogen bonding. Also, these results provide new insights into the shielding mechanism for ¹¹B in borate and borosilicate minerals. In particular, this study demonstrates that the small variation in ¹¹B chemical shifts can still be used to probe the local structural environments and that the established correlations can be used to investigate the structural details in borates and amorphous materials.     

四川盆地基底断裂对长兴组生物礁的控制作用研究

四川盆地长兴组生物礁油气藏是国内外该类型油气藏的一个典型代表。在前人主要针对川东北地区提出台地边缘是生物礁发育有利部位的基础上,从盆地更广的尺度,结合国内外已有实例,着重从基底断裂角度,分析了其对生物礁发育的影响与控制作用。结果表明,盆地内长兴组发育有大量NE和NW向深大断裂,地层、岩相和构造证据均反映这些断裂在晚二叠世处于正断活动期,并形成了台—槽相间和台内棋盘格状堑垒构造格局。基底正断活动通过对古地理的影响来实现对生物礁的控制,生物礁受张性正断层上升盘"断隆"控制,分布于基底断裂古上升盘断阶处,如环海槽的台地边缘和台地内部断垒周缘。因此,除已获得重大突破的"环海槽礁滩气藏富气带"外,在台地内部靠基底断裂带附近,礁滩也可能发育,可作为今后油气勘探重点考虑的对象。这一研究新认识有助于拓展区域油气勘探思路,并为生物礁型油气成藏理论研究提供新的参考信息。     

超声电视测井图像中异常点剔除算法

针对超声电视测井图像中经常会出现的异常点问题,提出了一种采用全变分的修复算法（TV算法）来剔除异常点。该方法先在选定的区域里根据阈值来确定要剔除的异常点,然后利用全变分的图像修复算法去修复这些异常点。实验结果证明,该方法能够很好地对异常点进行剔除,保证测井图像的完整性,明显地改善图像质量,对实际测井资料的处理具有很重要实际意义。     

NITON矿石元素分析仪在古鲁韦镍矿上的应用效果

用NITON矿石元素分析仪测定圈定镍矿体地表出露边界,能基本查明矿体数量、规模、成矿规律、成矿地质条件,达到了快速评价矿床,能取得较好的找矿成果。     

四川里伍铜矿田控矿构造特征与找矿方向

里伍铜矿田位于扬子地台西缘江浪变质核杂岩穹隆构造中。现已发现里伍、黑牛洞等中小型铜矿床7处,为扬子地台西缘地区铜矿集中产出区之一。中深构造层次的江浪变质核杂岩构成了矿区构造主体。通过对里伍铜矿田内矿床的地质特征、控矿因素和控矿构造特征等的系统研究表明,矿田中由变质核杂岩穹隆构成的构造组合及其韧性剪切滑脱带控制了铜矿体的定位、形态以及矿床的规模。变质核杂岩穹隆中的韧性剪切滑脱带是主要控矿构造。在综合研究的基础上,提出了矿田和区域找矿方向。     

Petroleum pollution and evolution of water quality in the Malian River Basin of the Longdong Loess Plateau,Northwestern China

The possible sources of water pollution and the evolution of water quality in the Malian River Basin of China’s Longdong Loess Plateau were studied based on chemical analysis. Concentrations of major chemicals in the river were related to the distance downstream from the source of the river and the surface water in the upstream had good quality, while the river from Southern Huanxian County to Qingcheng County was seriously polluted. Groundwater quality was generally good in the phreatic aquifer beneath the loess plateau, with bicarbonate and calcium dominant, but salinity was high and petroleum pollution was present in many parts of the study area. Both surface water and groundwater quality have declined rapidly during the past 20 years, leading to much of the water unsafe to drink and unsuitable for use in irrigation. The substances released into the water included industrial wastes, domestic sewage, organic and inorganic fertilizers, and pesticides, as well as a range of other substances that are harmful to humans. However, petroleum contamination caused by the oil industry in the Longdong oilfield is the largest source of pollution that infiltrates surface water and groundwater, leading to deterioration of water quality. It is recommended that oilfield management must be improved and the petroleum products and wastes must be disposed carefully to reduce the risk of further spills and pollution.     

川东北地区三叠系聚盐成钾机制及富集模式

川东北地区三叠系发育巨厚的蒸发岩层,并赋存优质的深层富钾卤水.因构造沉积条件的整体差异,川东北富钾卤水的成因机制与富集规律未有详尽研究.以"气钾兼探"为指导思想,综合利用野外露头?岩心?测井等资料,对川东北地区三叠系蒸发岩分布规律以及岩相古地理演化进行分析,明确了膏盐盆在T1j4?5?T2l1期间规模逐渐缩小、向SW逐...     

蛇绿混杂岩区1:5万填图工作方法研究 ——以云南省多条蛇绿混杂岩带的研究为例

近几年来,笔者依托大面积的1:5万区域地质调查及新一轮《云南省区域地质志》(第二版,修编)工作,梳理了云南省内存在10条蛇绿混杂岩带,通过对比研究,获得了一系列全新的认识.蛇绿混杂岩代表了地质历史时期已经消失了的古大洋残迹.古大洋受俯冲作用被压缩在板块之间,形成具有代表不同构造古地理单元、不同成因的岩石构造的异地堆垛体...     

智能遥感卫星系统

：分析了当前遥感卫星系统存在的一些不足,论述了新一代“智能遥感卫星系统”的概念及其主要特点,对其 中自适应遥感成像和星上数据实时处理两个核心部分进行重点介绍,并对其涉及的关键科学问题和关键技术进行阐 述。设计了一套具有自适应成像和应用模式优化能力的智能高光谱卫星有效载荷系统。该系统由用于区域背景信息获 取的前视预判遥感器、用于地表详细观测的主遥感器以及星上数据实时处理和分析3部分组成。对智能高光谱卫星的工 作原理和流程进行介绍,并呼吁中国尽快围绕智能遥感卫星系统开展一些前沿性的科学理论和关键技术研究,以实现 中国在卫星遥感领域的跨越式发展。