珠江三角洲湖库水体嗅味物质分布及其去除

采用固相微萃取-气质联用技术对珠江三角洲9个城市共48个湖库水体中的土臭素（GSM）、2-甲基异茨醇（MIB）和2,3,6-三氯苯甲醚（TCA）等5种嗅味物质进行检测,并探讨污水处理厂和自来水厂处理工艺中嗅味物质的浓度变化规律,同时研究强化混凝沉淀工艺对嗅味物质的去除效果.结果表明：珠江三角洲湖库水体中嗅味问题最严重的是广州、佛山、肇庆、东莞、惠州和深圳6个城市,各市湖库的嗅味物质平均浓度为70.93~116.61 ng/L;中山、珠海与江门3个城市的嗅味问题不明显,各市湖库的嗅味物质平均浓度为22.78~58.82 ng/L;珠江三角洲的湖库中浓度最高的嗅味物质是MIB、TCA和GSM,这3种嗅味物质占了嗅味物质总浓度的80.18%~100.00%;污水处理厂和自来水厂中的处理工艺对嗅味物质均有一定的去除效果,嗅味物质的去除主要发生在混凝沉淀阶段;污水处理厂对MIB、TCA和GSM的平均去除率分别为53.55%、57.40%和72.90%;自来水厂对MIB、TCA和GSM的平均去除率分别为64.14%、69.63%和36.86%;强化混凝沉淀实验中,当嗅味物质初始浓度为200 ng/L时,Al₂O₃投加量为13.75 mg/L可使得混凝沉淀工艺对嗅味物质的去除效果最佳且保证铝盐不超标,嗅味物质浓度增大时Al₂O₃投加量也需增大;反应体系的pH值处于5~8时,混凝沉淀工艺对嗅味物质的去除效果最佳;混凝搅拌速率越快,嗅味物质的去除率越高且越快达到稳定.     

26Al/10Be ratios reveal the source of river sediments in the Kimberley,NW Australia

We use cosmogenic ¹⁰Be and ²⁶Al in both bedrock and fluvial sediments to investigate controls on erosion rates and sediment supply to river basins at the regional scale in the Kimberley, NW Australia. The area is characterised by lithologically controlled morphologies such as cuestas, isolated mesas and extensive plateaus made of slightly dipping, extensively jointed sandstones. All sampled bedrock surfaces at plateau tops, ridgelines, and in the broader floodplain of major rivers over the region show similar slow lowering rates between 0.17 and 4.88 m.Myr^-1, with a mean value of 1.0 ± 0.6 m.Myr^-1 (n=15), whilst two bedrock samples collected directly within river-beds record rates that are one to two orders of magnitude higher (14.4 ± 1.5 and 20.9 ± 2.5 m.Myr^-1, respectively). Bedrock ²⁶Al/¹⁰Be ratios are all compatible with simple, continuous sub-aerial exposure histories. Modern river sediment yield lower ¹⁰Be and ²⁶Al concentrations, apparent ¹⁰Be basin-wide denudation rates ranging between 1.8 and 7.7 m.Myr^-1, with a median value of 2.6 m.Myr^-1, more than double the magnitude of bedrock erosion rates. ²⁶Al/¹⁰Be ratios of the sediment samples are lower than those obtained for bedrock samples. We propose that these depleted ²⁶Al/¹⁰Be ratios can largely be explained by the supply of sediment to river basins from the slab fragmentation and chemical weathering of channel gorge walls and plateau escarpments that result in diluting the cosmogenic nuclide concentration in river sediments measured at the basin outlets. The results of a mass-balance model suggest that ~60–90% of river sediment in the Kimberley results from the breakdown and chemical weathering of retreating vertical sandstone rock-walls in contrast to sediment generated by bedrock weathering and erosion on the plateau tops. This study emphasises the value of analysing two or more isotopes in basin-scale studies using cosmogenic nuclides, especially in slowly eroding post-orogenic settings. © 2019 John Wiley & Sons, Ltd.     

亚热带常绿阔叶林8种樟科树种细根化学计量特征

为了研究亚热带常绿阔叶林樟科树种的细根化学计量特征,以福建省建瓯市万木林自然保护区天然常绿阔叶林中具有代表性的8种樟科树种(沉水樟Cinnamomum micranthum;浙江桂Cinnamomum chekiangense;黄绒润楠Machilus grijsii;桂北木姜子Litsea subcoriacea;闽楠Phoebe bournei;新木姜子Neolitsea aurata;香樟Cinnamomum camphora;黄毛润楠Machilus chrysotricha)为研究对象,分析细根C、N、P化学计量学特征随序级的变化规律及种间变异情况。结果表明:(1)树种、序级以及二者交互作用对细根C、N、P浓度及C/N、C/P和N/P均具有极显著影响(P<0.01)。(2)随序级增加,大部分树种的细根N和P浓度降低,而C/N和C/P比增大;随序级变化的变异系数C浓度最小,而P浓度最大。(3)不同序级的细根C浓度的种间变异系数均最低,而P浓度的则均最高,N/P比的种间变异系数亦低于C/N比和C/P比;不同序级细根的N、P浓度之间均具有显著的正相关。     

广西岩溶区土壤铁锰结核重金属富集的地质特征

广西岩溶区农田土壤重金属污染形势严峻。该地区土壤含有大量铁锰结核,其主要成分为铁和锰的氧化物,对重金属有着较强的富集作用。铁锰结核伴随着土壤形成过程而产生,也是反映土壤形成过程及成土环境变化的良好载体。研究铁锰结核中重金属的富集特征有助于了解广西岩溶区土壤中重金属元素的富集过程和富集特征。文章对广西柳江和桂平的土壤与其中的铁锰结核进行了成分分析,通过微量元素分析得到铁锰结核对Ni、Cu、Cd、Zn、Pb、Co、Ba、As、Cr等重金属元素的富集特征,通过Ti/Al2O3的比值关系推断了铁锰结核与土壤的物质来源。此外,还对铁锰结核进行了激光共聚焦显微拉曼光谱仪（Laser Microscopic Confocal Raman Spectrometer）、扫描电镜和能谱仪（SEM-EDS）分析。通过铁锰结核内部同心环带状圈层结构及其内部的元素分布周期性变化的特征,推测结核形成机制。铁锰结核的形成固定了大量重金属元素,减轻了土壤重金属污染负担;但如果铁锰结核发生了溶解则会导致Mn及受其控制的部分重金属（Co、Cu、Ni、Ba）重新释放回到土壤,加重重金属污染。     

电感耦合等离子体发射光谱法测定西藏日多温泉地热水中11种主次量元素

西藏地热水的矿化度普遍较高,矿物质种类丰富,本文建立了采用电感耦合等离子体发射光谱(ICP-OES)同时测定西藏日多温泉地热水中11种主次量元素(钾钠钙镁硅硼锂锶砷铁和硫酸根)的分析方法。使用双向观测模式可确保不同浓度元素的同时检出,且地热水采用1%硝酸介质保存,在5周时间内11种元素含量的测定值基本稳定。方法检出限为0.0006~0.0162 mg/L,加标回收率为95.5%~105.8%,精密度(RSD,n=10)均小于6%,实际水样的测试结果与传统方法基本吻合。本方法为西藏温泉的水文地球化学研究提供了大量可靠的数据。     

荡坪钨矿宝山矿区复杂地层钻进工艺

江西荡坪钨矿宝山矿区地层复杂,岩石硬度高,破碎松散,钻进难度大,易出现坍塌、缩径、卡钻、埋钻等事故。针对该矿区复杂地层特点及施工难点,从设备选择、钻孔结构、钻头选用、冲洗液及护壁堵漏等方面,总结了一套有针对性的钻探技术措施,并在现场取得了较好的效果。     

川西新元古界苏雄组层型剖面底部豆状熔结凝灰岩LA-ICP-MS锆石U-Pb年龄及其地质意义

采用LA-ICP-MS方法,首次对四川西部新元古界苏雄组层型剖面底部豆状熔结凝灰岩进行了锆石U-Th-Pb同位素测定,获得了两组谐和度极高的年龄数据:805.9±4.4 Ma(N=11,MSWD=0.58)和849.4±6.2 Ma(N=6,MSWD=0.34)。其中,805.9±4.4 Ma代表凝灰岩沉积年龄,与前人报道的苏雄组流纹岩SHRIMP锆石U-Pb年龄(803±12 Ma)高度一致,进一步约束了苏雄组底部火山喷发的起始年代。构造岩浆热事件分析表明,805.9±4.4Ma代表了华南扬子古大陆800 Ma左右的火山喷发事件;而849.4±6.2 Ma则与Rodinia超大陆初始裂解(~850Ma)的同裂谷岩浆活动相对应。     

白云石(岩)有机成因研究现状及进展

白云岩是地质历史中常见的一种碳酸盐岩,但在现代近地表环境下却很难见其踪迹,因此其成因问题成为研究热点。近年来的研究表明,白云石的形成与有机物密不可分。本文在调研大量文献的基础上,从形成白云石动力学障碍这一微观机制出发,探究了其成因。结果表明,微生物的新陈代谢所起的调节作用是白云石形成过程中的关键因素。另外,有机大分子如多糖、羧甲基纤维素、羧基等也能以与硫酸盐还原菌类似的方式促进白云石的形成,这为研究白云石的成因机制提供了新的思路。     

Climate change scenarios of precipitation extremes in Central Europe from ENSEMBLES regional climate models

The study examines future scenarios of precipitation extremes over Central Europe in an ensemble of 12 regional climate model (RCM) simulations with the 25-km resolution, carried out within the European project ENSEMBLES. We apply the region-of-influence method as a pooling scheme when estimating distributions of extremes, which consists in incorporating data from a ‘region’ (set of gridboxes) when fitting an extreme value distribution in any single gridbox. The method reduces random variations in the estimates of parameters of the extreme value distribution that result from large spatial variability of heavy precipitation. Although spatial patterns differ among the models, most RCMs simulate increases in high quantiles of precipitation amounts when averaged over the area for the late-twenty-first century (2070–2099) climate in both winter and summer. The sign as well as the magnitude of the projected change vary only little for individual parts of the distribution of daily precipitation in winter. In summer, on the other hand, the projected changes increase with the quantile of the distribution in all RCMs, and they are negative (positive) for parts of the distribution below (above) the 98% quantile if averaged over the RCMs. The increases in precipitation extremes in summer are projected in spite of a pronounced drying in most RCMs. Although a rather general qualitative agreement of the models concerning the projected changes of precipitation extremes is found in both winter and summer, the uncertainties in climate change scenarios remain large and would likely further increase considerably if a more complete ensemble of RCM simulations driven by a larger suite of global models and with a range of possible scenarios of the radiative forcing is available.