热处理金红石晶体结构及其光催化活性分析

本文以在氢气气氛中加热和退火处理的天然金红石样品(采自山西某变质矿床)为研究对象,利用单晶和粉晶X-射线衍射(XRD)、环境扫描电子显微镜(ESEM)、紫外-可见漫反射吸收光谱(UV-vis)等矿物学常规测试方法,结合Rietveld方法对实验数据计算和精修的结果,对系列样品的晶体结构及对光催化活性影响进行了系统的研究...     

镇江市新一代暴雨强度公式研制及雨型设计

用镇江市1980—2013年连续34 a的降水观测资料,通过数据审核处理建立暴雨统计样本。对镇江市近34 a的暴雨特征进行统计分析,发现其存在较为显著的阶段性变化特征,具备开展新一代暴雨强度公式研制的必要。基于此,采用年最大值法展开修订,基于皮尔逊III型分布确定概率曲线并进行参数推求,研制了镇江市新一代暴雨强度公式。在此基础上,开展镇江市短历时暴雨雨型设计研究。统计发现:短历时暴雨以单峰型分布为主,其雨峰位置大部分出现在整个暴雨过程的前半段。进而采用芝加哥法雨型进行雨型设计,确定雨峰位置系数,得到镇江市短历时暴雨的雨型设计过程,短历时暴雨的瞬时雨强最高达5.9 mm/min,过程累计降水最高达105 mm。     

Numerical and experimental studies on flow and pollutant dispersion in urban street canyons

In this study numerical simulations and water tank experiments were used to investigate the flow and pollutant dispersion in an urban street canyon. Two types of canyon geometry were tested. The studies indicate that in a step-up notch canyon （higher buildings on the downstream side of the canyon）, the height and shape of the upstream lower buildings plays an important role in flow pattern and pollutant dispersion, while in a step-down notch canyon （lower buildings on the downstream side）, the downstream lower buildings have little influence. The studies also show that the substitution of tall towers for parailelepiped buildings on one side of the canyon may enhance the street ventilation and decrease the pollutant concentration emitted by motor vehicles.     

列车振动荷载作用下南京细砂动强度变化规律研究

以南京细砂为研究对象,采用空心圆柱扭剪仪模拟列车振动荷载作用对应的土体单元所受应力路径,考虑试样围压、加载幅值和排水条件,研究列车振动荷载作用下土体动强度的变化规律。试验结果分析表明:在模拟列车振动荷载作用对土体竖向应变的影响时,采用椭圆应力路径来代替心形应力路径是切实可行的,能克服试验仪器高频加载时无法有效模拟心形应力路径的缺点;其次,当围压和加载幅值都较小时南京细砂主要表现为在振动初期强度强化特征,当振动次数达到一定数量后强度也达到一个稳定阶段;当试验围压较大时,随振动次数增加,南京细砂的强度变化主要以强度弱化阶段为主;同时,排水条件对其强度变化的主要影响表现为对其振动前期强度强化阶段的影响,对其强度弱化阶段的影响并不明显。     

Eddy Covariance Tilt Corrections over a Coastal Mountain Area in South-east China: Significance for Near-Surface Turbulence Characteristics

Turbulence characteristics of an atmospheric surface layer over a coastal mountain area were investigated under different coordinate frames.Performances of three methods of coordinate rotation:double rotation(DR),triple rotation(TR),and classic planar-fit rotation(PF) were examined in terms of correction of eddy covariance flux.Using the commonly used DR and TR methods,unreasonable rotation angles are encountered at low wind speeds and cause significant run-to-run errors of some turbulence characteristics.The PF method rotates the coordinate system to an ensemble-averaged plane,and shows large tilt error due to an inaccurate fit plane over variable terrain slopes.In this paper,we propose another coordinate rotation scheme.The observational data were separated into two groups according to wind direction.The PF method was adapted to find an ensemble-averaged streamline plane for each group of hourly runs with wind speed exceeding 1.0 m s 1.Then,the coordinate systems were rotated to their respective bestfit planes for all available hourly observations.We call this the PF10 method.The implications of tilt corrections for the turbulence characteristics are discussed with a focus on integral turbulence characteristics,the spectra of wind-velocity components,and sensible heat and momentum fluxes under various atmospheric stabilities.Our results show that the adapted application of PF provides greatly improved estimates of integral turbulence characteristics in complex terrain and maintains data quality.The comparisons of the sensible heat fluxes for four coordinate rotation methods to fluxes before correction indicate that the PF10 scheme is the best to preserve consistency between fluxes.     

TOPOGRAPHIC DEPENDENT HORIZONTAL LOCALIZATION SCALE SCHEME IN GRAPES-MESO HYBRID EN-3DVAR ASSIMILATION SYSTEM

Based on the GRAPES-MESO hybrid En-3DVAR (Ensemble three-dimension hybrid data assimilation for Global/Regional Assimilation and Prediction system) constructed by China Meteorological Administration, a 7-day simulation (from 10 July 2015 to 16 July 2015) is conducted for horizontal localization scales. 48h forecasts have been designed for each test, and seven different horizontal localization scales of 250, 500, 750, 1000, 1250, 1500 and 1750 km are set. The 7-day simulation results show that the optimal horizontal localization scales over the Tibetan Plateau and the plain area are 1500 km and 1000 km, respectively. As a result, based on the GRAPES-MESO hybrid En-3DVAR, a topography-dependent horizontal localization scale scheme (hereinafter referred to as GRAPES-MESO hybrid En-3DVAR-TD-HLS) has been constructed. The data assimilation and forecast experiments have been implemented by GRAPES-MESO hybrid En-3DVAR, 3DVAR and GRAPES-MESO hybrid En-3DVAR-TD-HLS, and then the analysis and forecast field of these three systems are compared. The results show that the analysis field and forecast field within 30h of GRAPES-MESO hybrid En-3DVAR-TD-HLS are better than those of the other two data assimilation systems. Particularly in the analysis field, the root mean square error (RMSE) of u_wind and v_wind in the entire vertical levels is significantly less than that of the other two systems. The time series of total RMSE indicate, in the 6-30h forecast range, that the forecast result of En-3DVAR-TD-HLS is better than that of the other two systems, but the En-3DVAR and 3DVAR are equivalent in terms of their forecast skills. The 36-48h forecasts of three data assimilation systems have similar forecast skill.     

预制+现浇装配式地铁地下车站结构地震反应的三维有限元分析

目前对装配式结构的抗震性能研究较少,尤其对装配式地下结构的抗震性能研究尤为缺乏。鉴于此,本文以实际新型预制装配+现浇钢筋混凝土箱型框架式地铁地下车站结构为研究对象,通过建立土-地连墙-装配式地下车站结构的二维和三维两种非线性整体有限元模型,分析了该类新型车站结构的整体抗震性能。结果表明:采用带肋梁预制装配板与现浇钢筋混凝土板的叠合楼板和钢管混凝土中柱的施工工艺能够明显增强结构抗震性能;同时发现二维有限元模型的计算结果高估了车站结构中柱顶底端的地震损伤程度,而低估了车站结构纵梁与中柱连接部位的地震损伤程度。在强地震作用下,建议采用土与地下结构非线性动力相互作用的三维有限元分析模型来真实反应车站结构中柱和纵梁的抗震性能。     

西藏南部聂拉木地区前寒武纪岩石磁组构及其构造意义

通过对西藏南部聂拉木地区前寒武纪岩石磁组构进行研究表明:该区岩石磁化率百分率的各向异性H值较高,均大于10%,这说明岩石曾经历了较强烈的韧性变形。根据岩石最小磁化率从主轴K3方向推断的岩石变形期,最大的主压应力方位主要有SN向、NE-SW向、NW-SE向。岩石磁组构费林(Flinn)图解表明,大部分岩石磁组构具有磁面理发育、磁线理不发育,岩石磁化率量值椭球体呈压扁状的特点。部分岩石磁组构还具有磁线理发育、磁面理不发育,岩石磁化率量值椭球体呈拉长形的特点。因此,该区域构造应变型式具有压缩应变和拉伸应变二种型式。岩石磁组构研究还表明,该区具有SN向挤压、NW-SE向挤压、NW-SE向伸展滑脱三期构造应力。这说明高喜马拉雅结晶基底岩石曾经历了SN向逆冲推覆构造作用,NW-SE向逆冲推覆构造作用和NW-SE向伸展滑脱构造作用过程。构造应力场的转变及其构造作用,为印度板块与欧亚板块之间,自白垩纪末~始新世晚期发生的弧~陆、陆~陆碰撞,和始新世晚期以来,强烈的陆内汇聚造山与青藏高原剧烈隆升,及区域伸展滑脱构造作用过程的响应。     

互层土的动参数试验研究及其地震反应分析

通过对两个工程场地的淤泥质粉质粘土、粉土、粘土、粉细砂及粉土与（粉质）粘土、粘土与粉砂互层土的自振柱试验结果进行分析,给出了部分土的 - 和 - 曲线,与Seed和Idriss建议的砂土和粘性土的 - 和 - 曲线变化范围进行了对比;同时分析了这两个场地的地震反应,结果表明：在强震时互层土对地震波有很强的滤波作用,且互层土的最大剪应变远大于一般土,在水平地震作用下很容易接近或达到破坏状态。初步分析结果表明：互层土具有软土的动力特性,这主要是由互层土的特殊物理构造造成的,即在互层土中存在很密的水平薄弱面。     

清代江苏省冬季冷暖等级序列的重建及特征分析

通过对历史文献资料的收集整理,重建了清代江苏省冬季逐年冷暖等级序列,并利用Morlet复小波变换分析方法对序列进行了多时间尺度特征的综合分析。结果表明:(1)整个清代江苏省冬季气候变化大致可分为2个冷时段(1644—1730年、1821—1900年)和1个暖时段(1731—1820年);(2)重建的冷暖等级序列存在多尺度下的周期变化特征,其中有较明显的周期变化尺度是38～42 a、18～20 a、13～15 a和8 a,38～42 a和8 a特征时间尺度的周期变化相对具有全域性,18～20 a尺度的周期变化在1690—1790年之间比较明显,13～15 a尺度的周期变化在1720年之前和1830年之后比较明显;(3)重建序列的第1主周期为42 a,第2、3、4主周期依次是20 a、 8 a和3 a;在42 a尺度下,清代江苏省冬季气候可划分为6个偏冷时段和6个偏暖时段。