Effects of Deep Fluids on Hydrocarbon Generation and Accumulation in Chinese Petroliferous Basins

Deep fluids in a petroliferous basin generally come from the deep crust or mantle beneath the basin basement, and they transport deep substances(gases and aqueous solutions) as well as heat to sedimentary strata through deep faults. These deep fluids not only lead to large-scale accumulations of CO_2, CH_4, H_2, He and other gases, but also significantly impact hydrocarbon generation and accumulation through organic-inorganic interactions. With the development of deep faults and magmatic-volcanic activities in different periods, most Chinese petroliferous basins have experienced strong impacts associated with deep fluid activity. In the Songliao, Bohai Bay, Northern Jiangsu, Sanshui, Yinggehai and Pearl Mouth Basins in China, a series of CO_2 reservoirs have been discovered. The CO_2 content is up to 99%, with δ~(13)C_(CO2) values ranging from-4.1‰ to-0.37‰ and ~3He/~4He ratios of up to 5.5 Ra. The abiogenic hydrocarbon gas reservoirs with commercial reserves, such as the Changde, Wanjinta, Zhaozhou, and Chaoyanggou reservoirs, are mainly distributed in the Xujiaweizi faulted depression of the Songliao Basin. The δ~(13)CCH4 values of the abiogenic alkane gases are generally -30‰ and exhibit an inverse carbon isotope sequence of δ~(13)C_(CH4)δ~(13)C_(C2H6)δ~(13)C_(C3H8)δ~(13)C_(C4H10). According to laboratory experiments, introducing external H_2 can improve the rate of hydrocarbon generation by up to 147% through the kerogen hydrogenation process. During the migration from deep to shallow depth, CO_2 can significantly alter reservoir rocks. In clastic reservoirs, feldspar is easily altered by CO_2-rich fluids, leading to the formation of dawsonite, a typical mineral in high CO_2 partial pressure environments, as well as the creation of secondary porosity. In carbonate reservoirs, CO_2-rich fluids predominately cause dissolution or precipitation of carbonate minerals. The minerals, e.g., calcite and dolomite, show some typical features, such as higher homogenization temperatures than the burial temperature, relatively high concentrations of Fe and Mn, positive Eu anomalies, depletion of 18 O and enrichment of radiogenic ~(87)Sr. Due to CO_2-rich fluids, the development of high-quality carbonate reservoirs is extended to deep strata. For example, the Well TS1 in the northern Tarim Basin revealed a high-quality Cambrian dolomite reservoir with a porosity of 9.1% at 8408 m, and the Well ZS1 C in the central Tarim Basin revealed a large petroleum reserve in a Cambrian dolomite reservoir at ~6900 m. During the upward migration from deep to shallow basin strata, large volumes of supercritical CO_2 may extract petroleum components from hydrocarbon source rocks or deep reservoirs and facilitate their migration to shallow reservoirs, where the petroleum accumulates with the CO_2. Many reservoirs containing both supercritical CO_2 and petroleum have been discovered in the Songliao, Bohaiwan, Northern Jiangsu, Pearl River Mouth and Yinggehai Basins. The components of the petroleum trapped with CO_2 are dominated by low molecular weight saturated hydrocarbons.     

盛夏苏北地区一次飑线过程的数值模拟研究

对一次盛夏苏北飑线过程采用区域三重嵌套WRF模式进行了数值模拟和结果分析,给出了飑线径向剖面的概念模型图。结果表明:模拟的飑线与实际飑线非常接近,两者具有相同的性质和特点,利用模拟的线状强降水带及其降水强度来确定模拟飑线的位置和强度是可行的。飑线成熟期,飑线处存在强辐合区、强垂直上升运动区以及假相当位温的高值区,三者均呈柱状向上伸展;飑线前方(飑线移动的方向),低层有位温高值的入流,为飑线带入大量水汽和能量,后方低层有浅薄入流;飑线过境时地面风向发生急剧变化;飑线中层位温值大致不变呈中性层结,这与对流凝结潜热释放有关。该飑线过程可大体看成是假绝热过程,并具有重力波的非平衡性质,其生成演变中存在多尺度的相互作用。     

太湖流域排污权交易优化目标模型及方案配置研究

根据江苏省太湖流域水环境与社会经济特征,建立主要污染物排污权交易优化目标模型;以重点工业污染企业为样本,对排污权交易初始方案实施的预期效果进行定量分析,提出开展排污权交易制度的政策建议.     

南海成因及其演化模式探讨

尽管南海已进行深入的调查与研究,提出多种成因模型,包括挤出模型、弧后扩张模型、古南海俯冲拖曳模型等,但因其所处构造位置特殊,周边构造环境经历了复杂的改造,所有成因模式均未能得到广泛的认可。本文从三大板块相互作用入手,结合南海实测数据,提出南海形成的弧后扩张—左旋剪切模型。认为南海是古南海往北俯冲的弧后盆地,菲律宾海板块往北漂移形成的大规模左旋走滑是南海扩张的触发因素。印度—欧亚碰撞产生中南半岛挤出主要影响西南海盆扩张方向,使得扩张轴从近东西向转为北东向。南海及邻区晚中生代以来的演化可以分为以下阶段：1）早白垩世开始澳大利亚板块往北漂移,新特提斯洋往北俯冲消亡,导致弧后扩张,形成古南海;2）晚白垩世末—始新世,古南海往北俯冲,导致弧后拉张形成陆缘裂谷;3）早渐新世,受菲律宾海板块西缘大型左旋走滑影响,在原有裂谷的基础上从东往西海底扩张,形成南海;4）渐新世末,受俯冲后撤的影响,扩张中心往南跃迁,同时受西缘断裂左旋活动的影响,扩张轴从近东西西逐步转为北东向;5）早中新世晚期,南沙地块—北巴拉望地块与卡加延脊碰撞,南海扩张停止。     

A Quantitative Evaluation of Shale Gas Content in Different Occurrence States of the Longmaxi Formation: A New Insight from Well JY-A in the Fuling Shale Gas Field,Sichuan Basin

Comprehensive quantitative evaluation of shale gas content and the controlling factors in different occurrence states is of great significance for accurately assessing gas-bearing capacity and providing effective well-production strategies. A total of 122 core samples from well JY-A in the Fuling shale gas field were studied to reveal the characteristics of S_1 l shale,15 of which were selected to further predict the shale gas content in different occurrence states, which are dependent on geological factors in the thermal evolution process. Geological parameters were researched by a number of laboratory programs, and the factors influential in controlling shale gas content were extracted by both PCA and GRA methods and prediction models were confirmed by the BE method using SPSS software. Results reveal that the adsorbed gas content is mainly controlled by TOC, Ro, SSA, PD and pyrite content, and the free gas content is mainly controlled by S_2, quartz content, gas saturation and formation pressure for S_1 l in well JY-A. Three methods, including the on-site gas desorption method, the empirical formula method, and the multiple regression analysis method were used in combination to evaluate the shale gas capacity of well JY-A, all of which show that the overall shale gas content of well JY-A is in the range of 2.0–5.0 m~3/t and that the free gas ratio is about 50%, lower than that of well JY-1. Cause analysis further confirms the tectonics and preservation conditions of S_1 l in the geological processes, especially the influence of eastern boundary faults on well JY-A, as the fundamental reasons for the differences in shale gas enrichment in the Jiaoshiba area.     

江苏金坛新石器时代环境变迁研究

对江苏金坛三星村新石器遗址ＪＳ９８Ｔ０８２０号探坑南壁剖面进行采磁,对样品帮了粒度、地球化学、孢粉、微体古生物（有孔虫和介形类）等环境替代指标的测定与分析,并据此初步研究和恢复了该区新石器时代古定变状况,得出以下几点认识：（１０地球化学分析结果本区知全新世以来,气候有从暖湿向干冷变化的总趋势。（２）Ｐ２Ｏ５的含量在马家浜墓葬层和崧泽文化层可达生土层的５～６倍,充分反映了当时人类活动日益频繁,同时也     

北极楚科奇海海冰面积多年变化的研究

北极气候系统正在发生显著变化,其中,海冰面积和厚度的减小是其最主要的特征.楚科奇海是海冰面积变化最有代表性的区域.文章利用积累了9a的高分辨率海冰分布数据研究海冰面积的多年变化特征.结果表明,各年的冰情有显著的季节内变化,海冰面积距平曲线体现了不同时期海冰面积变化的动态过程.在1997~2005年间,楚科奇海海冰面积经历了轻(1997年)-重(2000~2001年)-轻(2002~2005年)的变化过程.9a的数据总体上体现了海冰面积减小的趋势,2005年的冰情呈现了历史新低.每年融冰期的长短与冰情轻重有密切的关系,冰轻年份融冰开始时间早,冻结结束时间晚.各年海冰面积最小值发生在9月下旬至10月初,各个年份海冰最小面积差别很大.有的年份只有4%,而重冰年可以大于50%.文章采用4个重要参数表达海冰多年变化.其中海冰面积指数反映了当年总体平均的海冰面积距平;海冰最小面积反映了融冰期海冰的极限情况;上一个冬季的气温积温也与翌年海冰面积有良好的关联;分析了风场对海冰的影响,表明风场在融冰期能够在短时间内改变海冰的覆盖面积.     

空间数据库系统的数据模型、存储方法及实现策略

空间数据库在天文、地理信息、城市规划等领域有广泛的应用,是目前研究的热点之一.详细介绍了空间数据库的数据模型、空间数据的操作、空间数据库上的查询及查询语言、空间数据库的存储方法,最后给出实现空间数据库的几个策略.     

基于IKONOS数据的矿山开发占地信息提取

以IKONOS数据为信息源,对甘肃省白银铜矿区进行矿山开发占地信息提取实验研究.在经过预处理的图像上对研究区内的地物进行光谱采样,分析地物的光谱特征;并进一步建立合适的波段计算经验公式,用密度分割函数将矿山背景与占地信息区分开,消除了背景干扰;再根据光谱特征建立新的波段处理模型,对只有矿山占地的图像进行第二次密度分割,将矿山占地信息细分,通过目视解译为占地信息赋予属性.实地查证结果表明,利用计算机提取矿山占地信息能弥补目视解译的不足,不仅节省人力、物力、财力和时间,而且信息提取结果准确,具有实际应用的意义,对同类地区的矿山占地信息提取具有一定的参考价值.     

重庆城口地区早前寒武系黑色岩系研究:(1)铂族元素成矿潜力评估

重庆城口地区从震旦统到下寒武统发育有丰富的黑色岩系,20世纪末期在该地区黑色岩系中开展了大量的铂族元素(PGE)的找矿工作,但是由于种种原因,关于该地区是否存在PGE矿化异常,还没有得到最终的结论.本次研究在PGE分析方法论证的基础上,进行了大量样品的PGE分析和微量元素分析.主要结论如下①区域上上震旦统槽区和断块区两套黑色岩系在原始的沉积环境和物源供给上有较大的差异,虽然槽区上震旦统的黑色岩系具有和下寒武统黑色岩系相似但强度较低的V-Cu-Y-Mo-U异常,但基本上不具有明显的PGE-Au-Ag异常.②断块区水井沱组黑色岩系和平剖面西段新发现的U-V-Mo-PGE异常可能是今后工作的重点,Pt＋Pd最高达248.9×10-9,局部U-V都达到了工业品位.③槽区巴山组硅质岩四个剖面都揭示了在硅质岩中广泛存在连续的PGE异常,87个碳质硅质岩平均含Pt＋Pd 57.2×10-9,有10个样品Pt Pd》100×10-9,最高达196.5×10-9;大部分碳质硅质岩都具有不同程度的V-Cu-Y-Mo-Tl-U组合异常,V都达到了独立矿床的品位要求,其中猪草河、燕子河等剖面还存在厚度较大的富矿地段,特别是燕子河剖面,局部还存在REE＋Y的高异常,值得深入研究.④城巴地区下寒武统黑色岩系存在广泛的PGE异常,但没有达到PGE的矿化要求,建议加强该地区的钒矿和铀矿勘探研究,PGE可以综合评价.