Geochemistry of pore waters from the Xisha Trough, northern South China Sea and their implications for gas hydrates

This paper reports all available geochemical data on sediments and pore waters from the Xisha Trough on the northern continental margin of the South China Sea. The methane concentrations in marine sediments display a downhole increasing trend and their carbon isotopic compositions (δ ¹³C = −25 to −51‰) indicate a thermogenic origin. Pore water Cl⁻ concentrations show a range from 537 to 730 mM, and the high Cl⁻ samples also have higher concentrations of Br⁻, Na⁺, K⁺, and Mg²⁺, implying mixing between normal seawater and brine in the basin. The SO₄ ²⁻ concentrations of pore waters vary from 19.9 to 36.8 mM, and show a downhole decreasing trend. Calculated SMI (sulfate-methane interfaces) depths and sulfate gradients are between 21 and 47 mbsf, and between −0.7 and −1.7 mM/m, respectively, which are similar to values in gas hydrate locations worldwide and suggest a high methane flux in the basin. Overall, the geochemical data, together with geological and geophysical evidence, such as the high sedimentation rates, high organic carbon contents, thick sediment piles, salt and mud diapirs, active faulting, abundant thermogenic gases, and occurrence of huge bottom simulating reflector (BSR), are suggestive of a favorable condition for occurrence of gas hydrates in this region.     

Dissolved inorganic carbon (DIC) and its carbon isotopic composition in sediment pore waters from the Shenhu area,northern South China Sea

The Shenhu area is one of the most favorable places for the occurrence of gas hydrates in the northern continental slope of the South China Sea. Pore water samples were collected in two piston cores (SH-A and SH-B) from this area, and the concentrations of sulfate and dissolved inorganic carbon (DIC) and its carbon isotopic composition were measured. The data revealed large DIC variations and very negative δ ¹³C-DIC values. Two reaction zones, 0–3 mbsf and below 3 mbsf, are identified in the sediment system. At site SH-A, the upper zone (0–3 mbsf) shows relatively constant sulfate and DIC concentrations and δ ¹³C-DIC values, possibly due to bioturbation and fluid advection. The lower zone (below 3 mbsf) displays good linear gradients for sulfate and DIC concentrations, and δ ¹³C-DIC values. At site SH-B, both zones show linear gradients, but the decreasing gradients for δ ¹³C-DIC and SO₄ ²⁻ in the lower zone below 3 mbsf are greater than those from the upper zone, 0–3 mbsf. The calculated sulfate-methane interface (SMI) depths of the two cores are 10.0 m and 11.1 m, respectively. The depth profiles of both DIC and δ ¹³C-DIC showed similar characteristics as those in other gas hydrate locations in the world oceans, such as the Blake Ridge. Overall, our results indicate an anaerobic methane oxidation (AMO) process in the sediments with large methane flux from depth in the studied area, which might be linked to the formation of gas hydrates in this area.     

KCl对方斑东风螺浮游幼虫变态的诱导作用

报道了KCl对方斑东风螺(Babylonia aerolatoLink)浮游幼虫变态的诱导作用。结果表明,在水体200 mL,幼虫20只,KCl连续作用12 h的条件下,当KCl浓度不超过8×10-3mol/L且幼虫日龄小于12 d时,诱导变态率为0~15%,诱导效果不稳定;当KCl浓度达到11×10-3mol/L且幼虫日龄达到15 d时,浮游幼虫变态率超过95%。在水体850 L,幼虫2.0×105~2.5×105只,KCl连续作用9 h的条件下,KCl浓度为17×10-3mol/L,日龄15 d的幼虫变态率达90%。浮游幼虫日龄越大,KCl添加浓度越高,作用时间越长,KCl诱导变态作用越明显。KCl对方斑东风螺幼虫有毒性作用,日龄越小,浓度越大,作用时间越长,毒性越大。日龄12 d的浮游幼虫,KCl添加浓度11×10-3mol/L作用20 h诱导变态的稚螺,未发现其生长和存活受到KCl的不良影响。综合本实验的结果,KCl诱导变态较为安全有效的条件是:浮游幼虫日龄不小于15 d,添加浓度11×10-3~14×10-3mol/L,作用时间不超过12 h。     

南麂列岛大沙岙沙滩贝类的时空分布

南麂列岛作为观光旅游的休闲去处正在日益升温,其中沙滩游玩是最大的活动亮点,大沙岙是南麂列岛最具代表性的沙滩,沙滩内生活着较多贝类,随大量人员的涌入和沿岸环境污染的日趋加重,大沙岙沙滩贝类的栖息地环境受到了较大程度的危害、人为活动正影响着贝类的生长发育。为探明近年来大沙岙贝类种类、数量及群落结构的变化,在南麂列岛国家海洋自然保护区建立初期(1992年)生态调查的基础上,于2003年再次对大沙岙贝类进行了采样分析,结果表明:大沙岙沙滩12种贝类的平均生物量和栖息密度分别为30.16g/m2和20个/m2,北断面开放区贝类的平均生物量和栖息密度(13.98g/m2和11个/m2)明显少于受监控的南断面核心区(46.33g/m2和30个/m2),贝类的平均生物量和栖息密度的垂直分布低潮区(48.43g/m2和31个/m2)高于中潮区(28.03g/m2和20个/m2),贝类的平均栖息密度7月高于3月,北断面贝类的季节变化、多样性和均匀度指数大于南断面。与建区初期同季调查资料比对发现,2003年北断面贝类数量下降幅度(14倍)显著大于南断面贝类下降幅度(1倍)。分析认为,自然环境变化和人为采捕是影响沙滩贝类数量下降的主要外部因子。     

Cr^3＋在改善三元复合驱中的作用实验研究

在三元复合驱矿场应用实践中,由于三元复合体系自身流度控制能力的局限性,必须通过聚合物凝胶前置段塞来改善吸液剖面,这就涉及到聚合物凝胶与三元复合体系的配伍性。通过向三元复合体系中加入有机铬,考察Cr^3＋对三元复合体系黏度、界面张力和阻力系数等性能影响,进而对Cr^3＋聚合物凝胶与三元复合体系配伍性以及Cr^3＋在改善三元复合体系性能方面的作用做出评价。结果表明,Cr^3＋的加入对三元复合体系黏度和界面张力影响不大,但阻力系数和残余阻力系数却明显增加。当采用Cr^3＋聚合物凝胶作为前置段塞或采用添加Cr^3＋的三元复合体系进行复合驱油实验时,其采收率增加幅度都要高于普通三元复合驱。这不仅显示出Cr^3＋聚合物凝胶与三元复合体系间良好的配伍性,而且为改善三元复合驱增油效果提供了新的途径。     

数码相机检验中出现的问题及解决方法

数码相机的检验是近景摄影测量中经常碰到的问题。最常用的主要还是基于共线方程的后方交会法。但由于普通数码相机存在较大的镜头畸变,内方位元素也未知,所以仅用单片进行后方交会求取有关参数时,法方程可能会出现病态现象,从而影响最后的检验结果。文中对此现象进行了讨论,并给出了一些实用的解决方法。     

地面三维激光雷达点云误差分析及校正方法

分析了地面三维激光雷达点云误差来源,提出了相应的误差校正模型。通过实测数据验证,该模型能够消除系统误差,提高了点云精度。     

Aequorea taiwanensis n. sp. (Hydrozoa, Leptomedusae) and mtCOI sequence analysis for the genus Aequorea

Aequorea taiwanensis, a new hydrozoan species from the Taiwan Strait was described using morphological and molecular characteristics. Both morphological and mitochondrial cytochrome oxidase subunit I (mtCOI) data supported A. taiwanensis n. sp. as a valid species. Sequence divergence and genetic distance of A. taiwanensis n. sp., A. papillata and A. conica were analysed based on the mtCOI gene sequences. The mtCOI sequences from these three species of the genus Aequorea showed high variation frequency, with sequence divergences ranging from 9.10% to 11.9%, and pairwise genetic distances ranging from 0.097 to 0.130. MtCOI sequence analysis provided diagnostic molecular systematic characteristics for accurate identification and discrimination of the species of Aequorea or their populations, and will be used to resolve evolutionary relationships among them.It was suggested that 10%—20% pairwise mtCOI sequence differences indicated the specieslevel divergence among congeneric species in the Hydromedusae.     

The application of hyperspectral remote sensing to coast environment investigation

Requirements for monitoring the coastal zone environment are first summarized. Then the application of hyperspectral remote sensing to coast environment investigation is introduced, such as the classification of coast beaches and bottom matter, target recognition, mine detection, oil spill identification and ocean color remote sensing. Finally, what is needed to follow on in application of hyperspectral remote sensing to coast environment is recommended.     

东海陆架两期沙脊的时空对比东海陆架两期沙脊的时空对比

基于高分辨率的单道地震和多波束测深数据,识别并对比了东海陆架中部同一海区相距20余万年的层U14和层U2两期沙脊群,其中层U14期沙脊属于埋藏沙脊,位于东海海底以下90 m深处,推测属于距今320~200 ka的海侵体系域(TST),沙脊顶界面是该期海侵的最大洪泛面(MFS);层U2期沙脊位于东海陆架,属于衰退沙脊,系末次盛冰期(LGM)以来的TST,顶界面是LGM以来的MFS。尽管两期沙脊形成年代相距20余万年,地层层位相距近90 m,但是沙脊群总体走向一致,表明距今2×105 a以来东海陆架潮波基本格局稳定。从层U2期可识别出4个亚期沙脊,通过多波束海底地形图可识别出4组走向的沙脊,多亚期、多走向沙脊是LGM以来海平面阶梯状波动在海底地形演变过程中的响应证据。