利用全台网垂直摆倾斜仪数据检测日本MW9.0地震激发的低频自由振荡

首次利用全台网多台垂直摆倾斜仪观测数据检测地球自由振荡。2011年日本MW9.0大地震发生后,43台仪器记录到其所激发的自由振荡信号。谱分析结果显示,垂直摆倾斜仪检测到了低频段（1~5 mHz）地球自由振荡振型,并且在超低频部分（<1.5 mHz）仍然还有较高的信噪比。选取43个台站中观测质量较好的36个台站数据进行叠积以增强信号,可以探测到一些非常微弱的模态,最终得到频率高于4.7 mHz的所有零阶球型振荡0S3~0S38（其中7个振型的观测频率与理论值的偏差近似为0）和环型振荡0T3~0T28几乎所有振型,此外还检测到21个谐频振型。     

Total Synthesis of Marine Cyclic Enol-Phosphotriester Salinipostin Compounds

Due to their structural diversity and variety of biological activities, marine natural products have been the subject of extensive study. These compounds, especially phospholipid polycyclic aromatic hydrocarbons, have a wide range of pharmacological applications, including embedded DNA and central nervous system, anti-tumor, anti-virus, anti-parasite, anti-bacterial, and antithrombotic effects. Unfortunately, the insufficient drug sources have limited the development of these compounds. In this study, we isolated salinpostin compounds from a fermentation solution of marine-derived Salinospora sp., which has a common bicyclic enol-phosphotriester core framework, as well as potent and selective antimalarial activities against P. falciparum with EC_(50)=50 nmolL~(-1). The chemical synthesis of these compounds in greater quantities is necessary for their use in bioactivity studies. Thus we explored a short route with high yields and mild reaction conditions, which can generate combinatorial libraries for drug discovery and lead optimization. We developed a new total synthesis method for six cyclic enol-phosphotriester salinipotin compounds and their diastereomers. For the total synthesis of cyclipostin P, we prepared cyclic enol-phosphotriester salinipostin compounds in 10 steps from a readily accessible starting material, 1,3-dihydroxyacetone, and obtained an overall yield of 1.29%. We fully characterized these compounds by proton nuclear magnetic resonance(~1H-NMR), carbon-13 NMR(~(13)C-NMR), and high-resolution mass spectrometry(HRMS) analyses, and found they coincide absolutely with the same compounds reported previously.     

Spatial Variations of b-Values in the Coastal Area of Guangdong

We used earthquake catalogs recorded by Guangdong Seismological Network from 2008 to 2014 to resolve the spatial variations of b-values in the coastal area of Guangdong, particularly in three key research areas(Yangjiang, Heyuan, and offshore Nanao Island) with strong seismicity. Our results revealed that b-values exhibited significant spatial variations, and zones with low b-values could indicate the most likely seismogenic area of large earthquakes. We observed three clear low b-value patches in the offshore Nanao Island. We found a distinct high b-value peak at the depth of 11 km and two minimum peaks at about 14 and 7–8 km in the Yangjiang area. The overall b-values generally decrease with depth in the Heyuan area. The spatial variations of b-values reflect tectonic anomalies; that is, the ‘low-high-low' distribution of b-values in the offshore Nanao Island and the Yangjiang area may indicate the anomaly of the crustal structure with a weak layer. The b-values of reservoir-induced seismicity are obviously lower than that induced by tectonism. This finding indicates that the reservoir area is generally at high stress state under the condition of high pore pressure. We inferred that large earthquakes might be prone to occur at 10–12 km depth in the offshore Nanao Island, at 12–15 km depth in the Yangjiang area, and at the lower part of the seismic activity zone in the Heyuan area. Moreover, the upstream area of the Xinfengjiang reservoir is the most likely area of future large earthquakes in the Heyuan area.     

开孔率对明基床上开孔沉箱波浪反射系数影响的数值研究

开孔率是开孔沉箱波浪反射系数的重要影响因素,迄今为止关于开孔沉箱的物模试验研究成果(包括《防波堤设计与施工规范》)中,开孔率μ通常以线性关系反映在开孔沉箱波浪反射系数的计算关系式中,适用范围为0.2~0.4。但当μ0.2或μ0.4时,开孔率μ对波浪反射系数Kr的影响规律尚需进一步的研究探讨。现借助二维数值波浪水槽,在扩大了的开孔率取值范围内,模拟不规则波与可渗明基床上开孔沉箱的相互作用。结果表明:在0.2≤μ≤0.4的范围内,用线性关系描述开孔率μ对波浪反射系数Kr的影响是合适的;在μ0.4时,数模值和物模试验拟合的经验关系式的趋势是一致的;在μ0.2时,开孔沉箱反射系数K_r随开孔率μ的减小而增大,用物模试验拟合的经验关系式及《防波堤设计与施工规范》中计算公式的线性关系来描述开孔率μ对反射系数K_r的影响是不恰当的。研究成果对开孔沉箱消浪机理的深入认识和开孔沉箱结构的优化设计具有重要意义。     

南海北部冷泉区深水珊瑚的发现及其特征

冷水珊瑚也称为深水珊瑚, 在生物多样性、生态资源和科研价值等方面具有重要意义。文章对采自南海北部冷泉区的冷水珊瑚骨骼碎屑进行测定, 鉴定出冷水珊瑚2个种(Crispatotrochus sp.1和Crispatotrochus sp.2), 以及4个属[Balanophyllia (Balanophyllia)、Balanophyllia (Eupsammia)、Lochmaeotrochus和Enallopsammia]。测定的冷水珊瑚的δ¹³C为-7.36‰~-1.15‰, δ¹⁸O为-1.38‰~3.67‰, 与全球冷水珊瑚碳氧同位素组成相似, 但明显不同于南海暖水珊瑚、冷泉碳酸盐岩及低温热液成因碳酸盐岩的碳氧同位素组成。     

南海北部陆坡深水区浅层天然气藏特征

南海北部陆坡深水区的浅层天然气藏是一种伴随天然气水合物的新型油气藏, 具有埋藏浅、规模大的特点, 其埋藏深度一般小于300m。浅层天然气藏由深部裂解气沿断裂上升被天然气水合物封盖而形成, 识别似海底反射(BSR)是寻找浅层天然气藏有效方法。浅层天然气藏的气源主要有热解气、生物气和混合气, 陆坡张性断裂是气体运移的主要通道, 水合物下部的砂层是浅层天然气藏的主要储集层, 水合物层则是封盖层。从南海发现的天然气水合物分布特征看, 浅层天然气藏在陆坡深水区广泛分布且气藏厚度大, 潜在资源量非常可观, 是一种新型的开采成本相对低廉的油气藏。     

辽西凌源牛营子盆地晚三叠世--中侏罗世地层层序及区域对比

本文根据重新理清的辽西凌源牛营子盆地晚三叠世-中侏罗世地层层序及时代,讨论其区域地层对比.晚三叠世晚期的邓杖子组是一套崩滑流为主的碳酸盐角砾,其为区域印支期构造运动的造山记录,与京西、冀北杏石口组、辽西北票羊草沟组(坤头菠罗组)可以对比;早侏罗世水泉沟组与京西、冀北南大岭组、辽西北票兴隆沟组层位相当,且各组火山岩时代基本相同;中侏罗世早期郭家店组底部含煤段与京西上窑坡组、冀北下花园组中部、辽西北票组中上部植物组合面貌一致;中侏罗世中期郭家店组砾岩段是燕山期构造变形主幕的产物,北京西山龙门组、冀北下板城下花园组上部、辽西北票海房沟组都是该期的记录,层位相当;辽西中侏罗世中晚期蓝旗组底部的时代为158±1Ma,与京西、冀北髫髻山组安山岩的同位素年龄总体一致.这说明差异较大的燕山板内造山带三叠纪-中侏罗世盆地的沉积记录显示了相似的演化规律.     

俯冲带火山岩硼及其同位素特征：华南中生代玄武岩初步研究

硼及其同位素能够有效地反映由于俯冲板片脱水引起的湿地幔楔部分熔融过程在火山岩中存留的地球化学信息。本次研究中使用同位素稀释法对华南中生代玄武岩进行了硼含量的测定，结合稀土与微量元素分析结果对玄武岩成因及构造背景进行探讨。玄武岩的硼含量主要集中在（1~5)×10-6，只有几个样品具有较高的含量（最高可达19×10-6)，按时代和空间位置划分出的3组样品在硼含量上没有明显差别。在B/Ce, Nb/Be的协变图解上，中侏罗世玄武岩表现出OIB特征。最临近太平洋板块的白坚世东区玄武岩富集LILE，并出现Nb-Ta亏损，具有岛弧火山岩特征，但硼没有富集。进行系统的B-Li-O同位素分析能有效地揭示华南中生代玄武岩的形成过程及该区的构造演化。     

震前卫星热红外环形应力场特征

本文包括两部分内容:①描述了1996年2月3日云南丽江Ms7.0级地震,震前几天的卫星热红外图像呈现圆形,它的NNW、NW、SN、及NE向的热旋扭面往S收敛。该地震地表破裂由一系列张扭性裂缝组成,呈左旋左列,水平位错不明显,垂直断距数厘米。垂直力对构造变动的作用较为明显;而丽江地震震源机制解破裂面II的走向NNE6o,倾向W,倾角44o,P轴方位为NNE3o、仰角75o,近于直立,综合热旋扭面展布、地震地表破裂特征及震源机制解,得出该旋扭椭圆为地幔外侧右旋上涌所造成;②菲律宾萨马岛Ms7.0～7.5强震群及青海共和Ms7.0地震前热应力环椭圆的推进路径。根据这一特征得出交变潮汐力的地球动力学解释。卫星热红外图像震前应力热场的方法是临震预测地震的有效方法,卫星热红外技术辅以震源机制解和地表破裂带力学分析是研究地球动力学有力工具。地球自转速度变化,交变潮汐力和地幔旋扭上涌力是地球动力学的主因。     

云南个旧锡矿床花岗岩接触带的交代现象

我国个旧锡矿是闻名中外最大的锡矿床之一,矿床中除含锡外,还伴生铜、钴、锌、钨、铋、铍及稀有元素。矿化主要产于燕山期花岗岩接触带及其附近的三叠纪碳酸盐围岩中的交代岩。本文着重讨论含锡花岗岩接触带交代岩的类型。矿物组合、分带性、岩石化学特征及其与矿化的关系,把各类含矿交代建造作为一个有成团联系的统一体——交代系列来考虑。