Comparison of marine gas hydrates in sediments of an active and passive continental margin

Two sites of the Deep Sea Drilling Project in contrasting geologic settings provide a basis for comparison of the geochemical conditions associated with marine gas hydrates in continental margin sediments. Site 533 is located at 3191 m water depth on a spit-like extension of the continental rise on a passive margin in the Atlantic Ocean. Site 568, at 2031 m water depth, is in upper slope sediment of an active accretionary margin in the Pacific Ocean. Both sites are characterized by high rates of sedimentation, and the organic carbon contents of these sediments generally exceed 0.5%. Anomalous seismic reflections that transgress sedimentary structures and parallel the seafloor, suggested the presence of gas hydrates at both sites, and, during coring, small samples of gas hydrate were recovered at subbottom depths of 238m (Site 533) and 404 m (Site 568). The principal gaseous components of the gas hydrates wer methane, ethane, and CO₂. Residual methane in sediments at both sites usually exceeded 10 mll^?1 of wet sediment. Carbon isotopic compositions of methane, CO₂, and ΣCO₂ followed parallel trends with depth, suggesting that methane formed mainly as a result of biological reduction of oxidized carbon. Salinity of pore waters decreased with depth, a likely result of gas hydrate formation. These geochemical characteristics define some of the conditions associated with the occurrence of gas hydrates formed by in situ processes in continental margin sediments.     

Organotemplate silica deposition in Neoproterozoic deep-marine environments: evidence from the Penganga Group, Adilabad, India

Silica in bedded cherts interstratified with manganese carbonates in a deep‐water carbonate ramp succession of the Neoproterozoic Penganga Group, India, displays film‐like, spherical to rod‐shaped, and tubular branching microstructures. The microstructures resemble mineralized extracellular polysaccharides, biofilms and bacterial morphologies. The microstructures suggest silicification by nucleation of silica on organic‐templates or indirectly as sorbed species accumulating on organic templates. Given that similar microstructures have also been documented in Archean cherts it is proposed that organotemplates might have been an important sink for the deposition of silica in Precambrian deep‐water marine environments.     

Sonar cross sections of bodies partially insonified by finite sound beams

An object that is partially insonified by a collimated sound beam may have a scattering cross section sometimes much larger than when the object is totally covered by the incident beam. We quantitatively study this partial insonification problem here, under the classical method of physical optics. The importance of this study stems from the fact that partial coverage of the target by the beam is the situation most likely to occur in many cases of practical importance. We consider several basic target shapes partially insonified by finite beams. These shapes include the spherical, the infinite and finite cylinder, the flat plate, and the capped sphere. High-frequency approximations of the resulting integrals, obtained by means of the saddle-point method, show the relative importance of the scattering centers located at the beam's specular reflection points, or at the edges of the spots that the beam shines on the scatterers. The physical-optics method is extended to obtain formulas for the bistatic cross sections of partially insonified objects. The results are numerically evaluated and graphically displayed in many pertinent instances and compared to the predictions of approaches, such as the Fresnel-zones method and the Geometrical Theory of Diffraction (GTD). The predictions of the physical-optics method have all the advantages and deficiencies of this method and, with very minor modifications, hold equally well for the partial illumination of objects by beams of electromagnetic radiation.     

A critical state model for sands dependent on stress and density

An elastoplastic model for sands is presented in this paper, which can describe stress–strain behaviour dependent on mean effective stress level and void ratio. The main features of the proposed model are: (a) a new state parameter, which is dependent on the initial void ratio and initial mean stress, is proposed and applied to the yield function in order to predict the plastic deformation for very loose sands; and (b) another new state parameter, which is used to determine the peak strength and describe the critical state behaviour of sands during shearing, is proposed in order to predict simply negative/positive dilatancy and the hardening/softening behaviour of medium or dense sands. In addition, the proposed model can also predict the stress–strain behaviour of sands under three-dimensional stress conditions by using a transformed stress tensor instead of ordinary stress tensor. Copyright © 2004 John Wiley & Sons, Ltd.     

Plane of elastic non-resisting tension material under foundation structures

In the frame of 2D-static problems one approaches the problem of elastic-NRT (not-resisting tension) semi-plane loaded on its limit line. This problem is intended to model the stress situation induced in the soil by a foundation structure. The solution, in terms of activated stress field, is searched for in the class of stress fields satisfying equilibrium and admissibility conditions, by applying an energy approach. Copyright © 2004 John Wiley & Sons, Ltd.