An empirical model of the daily evolution of the coronal index

Global changes of the solar activity can be expressed by the coronal index that is based upon the total irradiance of the coronal 530.3 nm green line from observations at five stations. Daily mean values of the coronal index of solar activity and other well-correlated solar indices are analyzed for the period 1966–1998 covering over three solar cycles. The significant correlation of this index with the sunspot number and the solar flare index have led to an analytical expression which can reproduce the coronal index of solar activity as a function of these parameters. This expression explains well the existence of the two maxima during the solar cycles taking into account the evolution of the magnetic field that can be expressed by some sinusoidal terms during solar maxima and minima. The accuracy between observed and calculated values of the coronal index on a daily basis reaches the value of 71%. It is concluded that the representative character of the coronal index is preserved even when using daily data and can therefore allow us to study long-term, intermediate and short-term variations for the Sun as a star, in association with different periodical solar–terrestrial phenomena useful for space weather studies.     

Melt Generation and Fluid Flow in the Thermal Aureole of the Bushveld Complex

Granite sheets emplaced into the migmatite zone of the easterncontact aureole of the Bushveld Complex resulted from fluid-enhanced,incongruent biotite melting of the underlying Silverton Formationshales during prograde metamorphism. Ba concentrations are extremein both the sheets (>1000 ppm) and the hornfels (>800ppm) into which they have been emplaced. We conclude that aBa-rich, hydrothermal fluid induced melting in the aureole,and that fluid transport of Ba²⁺, and to a lesser extent, Sr²⁺and Eu²⁺, persisted in the melt zones under subsolidus conditions.Sr-isotope systematics from high-Ba localities define an errorchronof 2161 ± 106 Ma with an initial (⁸⁷Sr/⁸⁶Sr) ratio of0·705 ± 0·001. Metasedimentary rocks unaffectedby fluid infiltration were homogenized at the same time butwith an increased initial ratio, suggesting that whereas isotopehomogenization was achieved between outcrops permeated by fluids,there is no evidence of regional homogenization. Oxygen-isotopecompositions of psammitic metasediments in the aureole are uncorrelatedwith distance from the contact, suggesting the infiltratingfluid equilibrated isotopically with the metasediments. Theirelevated     

Evidence for a mid‐Pleistocene shift of ice‐drift pattern in the Nordic seas

Sediment proxy records from a continuous, 1.5 million year long deep‐sea sediment core from a site in the western Norwegian Sea were used to obtain new insights into the nature of palaeoceanographic change in the northern North Atlantic (Nordic seas) during the climatic shift of the Mid‐Pleistocene Revolution (MPR). Red‐green sediment colour and magnetic susceptibility records both reveal significant differences in their mean values when comparing the intervals older than 700 000 yr (700 ka) with those from the past 500 kyr. The timing and duration of these changes indicates that the MPR in the Nordic seas is characterised by a gradual transition lasting about 200 kyr. Together with further sedimentological evidence this suggests that the mid‐Pleistocene climate shift was accompanied by a general change in ice‐drift pattern. It is further proposed that prior to the onset of the major late Pleistocene glaciations in the Northern Hemisphere a significant proportion of the ice in the eastern Nordic seas originated from a southern provenance, whereas later it dominantly came from the surrounding landmasses. Copyright © 2003 John Wiley & Sons, Ltd.     

Microtextures and crystal chemistry in P21/c pigeonites

Summary ?A single-crystal X-ray investigation was performed on crystals of P2₁/c natural pigeonite with varying Ca and Fe^* ( = Fe²⁺ + Mn²⁺) contents, in order to verify the effect of microtextural disorder on structure refinements and to constrain the crystal chemistry of pigeonite. Antiphase domains and exsolution lamellae affect differently the refinement results. In a crystal free of exsolution the structure obtained after refinement with all reflections is an average of that of the antiphase domains and of their boundaries, whereas in an exsolved crystal it represents only the structure of the prevailing pigeonite lamellae. The refinement using only h + k odd reflections seems to give the structure of the Ca-free pigeonite characteristic of the antiphase domains rather than that of Ca-rich domain walls. The ratio of the scale factors in refinements with all reflections and with only h + k odd reflections allows the ratios of the exsolved augite and pigeonite phases to be estimated. The crystal chemistry of the investigated samples follows the trends outlined by data on Ca-free and Fe-free synthetic samples. In particular, it is shown that Ca and Fe^* substitution for Mg induce similar changes in the average structure, i.e. both induce an expansion in the M1 polyhedron and decrease the difference between the M2–O3 distances. Received October 18, 2001; revised version accepted February 15, 2002     

A qualitative and quantitative evaluation of experimental model catchment evolution

Due to the geological time scales required for observation of catchment evolution, surrogates or analogues of field data are necessary to understand long‐term processes. To investigate long‐term catchment behaviour, two experimental model catchments that developed without rigid boundaries under controlled conditions are examined and a qualitative and quantitative analysis of their evolution is presented. Qualitatively, the experimental catchments have the visual appearance of field scale data. Observation demonstrates that changes in catchment shape and network form are conservative. Quantitative analysis suggests that the catchments reach an equilibrium form while a reduction in the channel network occurs. While the catchments are laboratory scale models, the results provide insights into field scale behaviour. Copyright © 2003 John Wiley & Sons, Ltd.     

Quantifying hydrogen‐deuterium exchange of meteoritic dicarboxylic acids during aqueous extraction

Abstract— Hydrogen isotope ratios of organic compounds in carbonaceous chondrites provide critical information about their origins and evolutionary history. However, because many of these compounds are obtained by aqueous extraction, the degree of hydrogen‐deuterium (H/D) exchange that occurs during the process needs to be quantitatively evaluated. This study uses compound‐specific hydrogen isotopic analysis to quantify the H/D exchange during aqueous extraction. Three common meteoritic dicarboxylic acids (succinic, glutaric, and 2‐methyl glutaric acids) were refluxed under conditions simulating the extraction process. Changes in δD values of the dicarboxylic acids were measured following the reflux experiments. A pseudo‐first order rate law was used to model the H/D exchange rates which were then used to calculate the isotope exchange resulting from aqueous extraction. The degree of H/D exchange varies as a result of differences in molecular structure, the alkalinity of the extraction solution and presence/absence of meteorite powder. However, our model indicates that succinic, glutaric, and 2‐methyl glutaric acids with a δD of 1800%***_o would experience isotope changes of 38_o, 10_o, and 6_o, respectively during the extraction process. Therefore, the overall change in δD values of the dicarboxylic acids during the aqueous extraction process is negligible. We also demonstrate that H/D exchange occurs on the chiral α‐carbon in 2‐methyl glutaric acid. The results suggest that the racemic mixture of 2‐methyl glutaric acid in the Tagish Lake meteorite could result from post‐synthesis aqueous alteration. The approach employed in this study can also be used to quantify H/D exchange for other important meteoritic compounds such as amino acids.     

Probing the nuclear activity with supermassive black holes

We report three new or updated techniques for probing the parameters of active galaxies based on the masses of their central black holes M_BH). First, we derived a near-IR analog of the bulge luminosity versus M_BH relationship. The low scatter makes it a promising new tool to study the black hole demographics. Next, we present relations between M_BH and the10 μm and 2-10 keV nuclear luminosity. They may help to study the M_BH evolution over wide redshift ranges. Finally, we measured M_BH in quasars from z ∼ 3.4 to z ∼ 0.3 to search directly for M_BH growth. Surprisingly, we found no evidence for growth implying that the majority of quasar host galaxies have undergone their last major merger at z ≥ 3. This revised version was published online in August 2006 with corrections to the Cover Date.