Land surface coupling in regional climate simulations of the West African monsoon

Coupling of the Community Land Model (CLM3) to the ICTP Regional Climate Model (RegCM3) substantially improves the simulation of mean climate over West Africa relative to an older version of RegCM3 coupled to the Biosphere Atmosphere Transfer Scheme (BATS). Two 10-year simulations (1992–2001) show that the seasonal timing and magnitude of mean monsoon precipitation more closely match observations when the new land surface scheme is implemented. Specifically, RegCM3–CLM3 improves the timing of the monsoon advance and retreat across the Guinean Coast, and reduces a positive precipitation bias in the Sahel and Northern Africa. As a result, simulated temperatures are higher, thereby reducing the negative temperature bias found in the Guinean Coast and Sahel in RegCM3–BATS. In the RegCM3–BATS simulation, warmer temperatures in northern latitudes and wetter soils near the coast create excessively strong temperature and moist static energy gradients, which shifts the African Easterly Jet further north than observed. In the RegCM3–CLM3 simulation, the migration and position of the African Easterly Jet more closely match reanalysis winds. This improvement is triggered by drier soil conditions in the RegCM3–CLM3 simulation and an increase in evapotranspiration per unit precipitation. These results indicate that atmosphere–land surface coupling has the ability to impact regional-scale circulation and precipitation in regions exhibiting strong hydroclimatic gradients.     

Trace element and molecular markers of organic carbon dynamics along a shelf–basin continuum in sediments of the western Arctic Ocean

Molecular organic biomarkers together with trace element composition were investigated in sediments east of Barrow Canyon in the western Arctic Ocean to determine sources and recycling of organic carbon in a continuum from the shelf to the basin. Algal biomarkers (polyunsaturated and short-chain saturated fatty acids, 24-methylcholesta-5,24(28)-dien-3β-ol, dinosterol) highlight the substantial contribution of organic matter from water column and sea-ice primary productivity in shelf environments, while redox markers such as acid volatile sulfide (AVS), Mn, and Re indicate intense metabolism of this material leading to sediment anoxia. Shelf sediments also receive considerable inputs from terrestrial organic carbon, with biomarker composition suggesting the presence of multiple pools of terrestrial organic matter segregated by age/lability or hydrodynamic sorting. Sedimentary metabolism was not as intense in slope sediments as on the shelf; however, sufficient labile organic matter is present to create suboxic and anoxic conditions, at least intermittently, as organic matter is focused towards the slope. Basin sediments also showed evidence for episodic delivery of labile organic carbon inputs despite the strong physical controls of water depth and sea-ice cover. Principal components analysis of the lipid biomarker data was used to estimate fractions of preserved recalcitrant (of terrestrial origin) and labile (of marine origin) organic matter in the sediments, with ranges of 12–79%, 14–45%, and 37–66% found for the shelf, slope, and basin cores, respectively. On average, the relative preserved terrestrial organic matter in basin sediments was 56%, suggesting exchange of organic carbon between nearshore and basin environments in the western Arctic.     

Pfiesteria shumwayae (Pfiesteriaceae) in New Zealand

Pfiesteria shumwayae Steidinger et Burkholder is now known to be present in New Zealand and occurs in estuaries around the country. The presence of Pfiesteria was initially determined by a polymerase chain reaction (PCR)‐based detection assay, using oligonucleotide primers targeted at ribosomal DNA extracted from estuarine water and sediments. Presence was confirmed by isolation from fresh sediments in the presence offish (Oreochromis mossambicus), followed by identification by scanning electron microscopy. The New Zealand isolates of P. shumwayae were ichthyotoxic in bioassays, but there is no historic evidence offish kills in New Zealand associated with the dinoflagellate.     

Late- to post-orogenic basins of the Pan-African – Brasiliano collision orogen in southern Africa and southern Brazil

Late- to post-orogenic basins formed on both sides of the Pan-African – Brasiliano orogen when the Congo and Kalahari Cratons collided with the Rio de la Plata Craton during the formation of western Gondwana. Trace fossil evidence and radiometric age dating indicate that deposits on both sides are coeval and span the Cambrian–Precambrian boundary. A peripheral foreland basin, the Nama Basin, developed on the subducting southern African plate. Lower, craton-derived fluviomarine clastics are overlain by marine platform carbonates and deltaic flysch derived in part from the rising subduction complex along the northern (Damara Belt) and western (Gariep Belt) orogenic margins. Rare, thin volcanic ash layers (tuffs and cherts) are present. Upper sediments consist of unconformable red molasse related to collisional orogenesis. Orogenic loading from the north and west led to crustal flexure and the formation of a remnant ocean that drained to the south and closed progressively from north to south. During final collision SE-, E- and NE-verging nappes overrode the active basin margins. Although younger than most of the post-orogenic magmatism, its setting on the cratonic edge of the subducting plate precluded marked volcanism or granitic intrusion, the only exception being the youngest intrusions of the Kuboos-Bremen Suite dated at 521±6 Ma to 491±8 Ma. Two foreland-type basins, perhaps faulted remnants of a much larger NE–SW elongated retroarc foreland basin, are found west of the Dom Feliciano Belt on the edge of the Rio de la Plata Craton in southern Brazil. In the southern Camaqua Basin, basal fluvial deposits are followed by cyclical marine and coarsening-up deltaic deposits with a notable volcanic and volcaniclastic component. This lower deformed succession, comprising mainly red beds, contain stratabound Cu and Pb–Zn deposits and is overlain unconformably by a fluviodeltaic to aeolian succession of sandstones and conglomerates (with minor andesitic volcanics), derived primarily from an eastern orogenic source and showing southerly longitudinal transport. In the northern Itajaí Basin, sediments range from basal fluvial and platform sediments to fining-up submarine fan and turbidite deposits with intercalated acid tuffs. The Brazilian basins had faulted margins off which alluvial fans were shed. They also overlie parts of the Ribeira Belt. Thrust deformation along the orogenic margin bordering the Dom Feliciano Belt was directed westward in the Camaqua and Itajaí basins, but reactivated strike-slip and normal faults are also present. Late- to post-orogenic granitoids and volcanics of the Dom Feliciano Belt, ranging in age from 568±6 Ma to 529±4 Ma, occur in the foreland basins and are geochemically related to some of the synsedimentary volcanics.     

Sediment storage and release from Himalayan piggyback basins and implications for downstream river morphology and evolution

Piggyback basins developed at the mountain fronts of collisional orogens can act as important, and transient, sediment stores along major river systems. It is not clear, however, how the storage and release of sediment in piggyback basins affects the sediment flux and evolution of downstream river reaches. Here, we investigate the timing and volumes of sediment storage and release in the Dehra Dun, a piggyback basin developed along the Himalayan mountain front in northwestern India. Based on OSL dating, we show evidence for three major phases of aggradation in the dun, bracketed at ca. 41–33 ka, 34–21 ka and 23–10 ka, each accompanied by progradation of sediment fans into the dun. Each of these phases was followed by backfilling and (apparently) rapid fan‐head incision, leading to abandonment of the depositional unit and a basinward shift of the active depocentre. Excavation of dun sediment after the second and third phases of aggradation produced time‐averaged sediment discharges that were ca. 1–2% of the modern suspended‐sediment discharges of the Ganga and Yamuna rivers that traverse the margins of the dun; this sediment was derived from catchment areas that together comprise 1.5% of the drainage area of these rivers. Comparison of the timing of dun storage and release with upstream and downstream records of incision and aggradation in the Ganga show that sediment storage in the dun generally coincides with periods of widespread hinterland aggradation but that late stages of dun aggradation, and especially times of dun sediment excavation, coincide with major periods of sediment export to the Ganga Basin. The dun thus acts to amplify temporal variations in hinterland sediment supply or transport capacity. This conceptual model appears to explain morphological features of other major river systems along the Himalayan front, including the Gandak and Kosi Rivers, and may be important for understanding sediment flux variations in other collisional mountain belts.     

瞬变电磁扩散场到虚拟波场的精细积分变换算法

现有的瞬变电磁解释与反演方法主要对电阻率参数进行解释,较难给出准确的地质构造信息.为了能够较多获得地质构造信息,可将瞬变电磁扩散场信号转换为虚拟波场信号,提高瞬变电磁法的分辨率.本文采用精细积分法,实现了瞬变电磁扩散场到虚拟波场的转换.将一个高度病态的线性方程组转换成求积分的过程,大大降低了解决病态问题的难度.积分步长...     

Properties of iron at the Earth's core conditions

Summary. The phase diagram of iron up to 330 GPa is solved using the experimental data of static high pressure (up to 11 GPa) and the experimental data of shock wave data (up to 250 GPa). A solution for the highest triple point is found ( P = 280 GPa and T = 5760 K) by imposing the thermodynamic constraints of triple points. This pressure of the triple point is less than the pressure of the inner core–outer core boundary of the Earth. These results indicate that the density of iron at the inner core–outer core boundary pressure is close to 13 g cm⁻³, which lies close to the seismic solutions of the Earth at that pressure. It is thus concluded that the Earth's inner core is very likely to be virtually pure iron in its hexagonal close packed (hcp) phase.
It is shown that four properties of the Earth's inner core determined from seismology are close in value to the corresponding properties of hcp iron at inner core conditions: density, bulk modulus, longitudinal velocity, and Poisson's ratio. The density–pressure profile of hcp iron at inner core conditions matches the density–pressure profile of the inner core as determined by seismic methods, within the spread of values given by recent seismic models.
This indicates that the Earth is slowly cooling, the Earth's inner core is growing by crystallization, and the impurities of the core are concentrated in the outer core. The calculated temperature at the Earth's centre is 6450 K.     

Droninoite,Ni<Subscript>3</Subscript>Fe<Superscript>3+</Superscript>Cl(OH)<Subscript>8</Subscript> · 2H<Subscript>2</Subscript>O,a new hydrotalcite-group mineral species from the weathered Dronino meteorite

A new mineral, droninoite, was found in a fragment of a weathered Dronino iron meteorite (which fell near the village of Dronino, Kasimov district, Ryazan oblast, Russia) as dark green to brown fine-grained (the size of single grains is not larger than 1 μm) segregations up to 0.15 × 1 × 1 mm in size associated with taenite, violarite, troilite, chromite, goethite, lepidocrocite, nickelbischofite, and amorphous Fe³⁺ hydroxides. The mineral was named after its type locality. Aggregates of droninoite are earthy and soft; the Mohs hardness is 1–1.5. The calculated density is 2.857 g/cm³. Under a microscope, droninoite is dark gray-green and nonpleochroic. The mean (cooperative for fine-grained aggregate) refractive index is 1.72(1). The IR spectrum indicates the absence of S O ₄ ^2? and C O ₃ ^2? anions. Chemical composition (electron microprobe, partition of total iron into Fe²⁺ and Fe³⁺ made on the basis of the ratio (Ni + Fe²⁺): Fe³⁺ = 3: 1; water is calculated from the difference) is as follows, wt %: 36.45 NiO, 12.15 FeO, 17.55 Fe₂O₃, 23.78 H₂O, 13.01 Cl, ?O=Cl₂ ?2.94, total is 100.00. The empirical formula (Z = 6) is Ni_2.16Fe _0.75 ²⁺ Fe _0.97 ³⁺ Cl_1.62(OH)_7.10 · 2.28H₂O. The simplified formula is Ni₃Fe³⁺Cl(OH)₈ · 2H₂O. Droninoite is trigonal, space group R \(\bar 3\) m, R3m, or R32; a = 6.206(2), c = 46.184(18) Å; V = 1540.4(8) ų. The strong reflections in the X-ray powder diffraction pattern [d, Å (I, %) (hkl)] are 7.76(100)(006), 3.88(40)(0.0.12), 2.64(25)(202, 024), 2.32(20)(0.2.10), 1.965(0.2.16). The holotype specimen is deposited at the Fersman Mineralogical Museum, Russian Academy of Sciences, Moscow, registration number 3676/1.     

Ecology of the bottom fauna and bioaccumulation of trace metals along the Lena River–Laptev Sea transect

The first data on ecology and trace metal (As, Cd, Cr, Cu, Fe, Mn, Ni, Pb) bioaccumulation by macrozoobenthic organisms in area along the 130°E meridional transect from shallow water near the Lena River’s delta till the 78°N are presented. At the newly discovered methane seeps in the shallow Laptev Sea areas (72 m depth), a higher total abundance and biomass compared with background stations were recorded. In carbonate shells and soft tissues of Bivalvia Portlandia arctica and Astarte borealis, the high concentrations of Mn, Fe, Pb, Ni and Co were detected that varied in dependence from sampling site. In the dominating taxa of brittle stars (Ophiuroidea), there were found no significant differences between majority of trace metal content in organisms inhabiting the seeps area and background ones. An elevated content of some metals was detected in the Asteroidea bodies that may be attributed to its trophic behavior (deposit feeder).     

鄂尔多斯盆地中央古隆起的地质结构与成因机制

克拉通盆地内古隆起是了解板内变形机制的重要窗口,也是油气、煤、盐、铀等矿产勘查的主要对象,一直是盆地分析的热点领域。本文以鄂尔多斯盆地中央古隆起为例,利用新的高精度反射地震剖面与深探井资料,解剖古隆起的地质结构,刻画构造演化过程,探讨其形成机制。研究表明,鄂尔多斯盆地古生代隆起带发育在华北克拉通地块中西部,自伊盟—杭锦旗、乌审旗—定边,南延至镇原—正宁一带,呈“工”字形,面积达7.5×104 km2以上;伊盟凸起为基底隆起,镇原隆起为多阶段、间隙性发育的剥蚀与沉积型隆起,定边凸起为沉积型隆起。它是基底分异构造格局与周缘板块构造事件共同控制的产物,为在中元古代裂陷基础上早古生代被动大陆边缘背景下发育演化的古隆起;古生代早期,邻接周缘洋盆表现为台缘隆起;石炭纪晚期—二叠纪早期,因差异升降而具陆缘隆起性质;印支晚期—燕山期以来,隐伏于天环坳陷之下埋藏沉没。鄂尔多斯盆地中央隆起带为多机制复合成因,伊盟凸起为基底强烈伸展、长期剥露剥蚀型隆起;镇原凸起为西缘断阶迁移、南缘前缘隆起叠加的复合隆起;定边凸起为断阶迁移、挤压叠加的继承性隆起。鄂尔多斯盆地中央隆起带对盆地内部的构造—沉积分异施加了重要影响,其两翼斜坡带是油气聚集的有利区带。