Design and performance of a novel multi-function debris flow mitigation system in Wenjia Gully,Sichuan

The post-earthquake debris flows in the Wenjia Gully led to the exposure of the shortcomings in the design of the original conventional debris flow mitigation system. A predicament for the Wenjia mitigation system is a large amount of loose material (est. 50 × 10⁶ m³) that has been deposited in the gully by the co-seismic landslide, providing abundant source material for debris flows under saturation. A novel design solution for the replacement mitigation system was proposed and constructed, and has exhibited excellent performance and resilience in subsequent debris flows. The design was governed by the three-phase philosophy of controlling water, sediment, and erosion. An Early Warning System (EWS) for debris flow that uses real-time field data was developed; it issues alerts based on the probabilistic and empirical correlations between rainfall and debris flows. This two-fold solution reduces energy of the debris flow by combining different mitigation measures while minimizing the impact through event forecasting and rapid public information sharing. Declines in the number and size of debris flows in the gully, with increased corresponding rainfall thresholds and mean rainfall intensity-duration (I-D) thresholds, indicate the high efficacy of the new mitigation system and a lowered debris flow susceptibility. This paper reports the design of the mitigation system and analyzes the characteristics of rainfall and debris flow events that occurred before and after implementation of the system; it evaluates the effectiveness of one of the most advanced debris flow mitigation systems in China.     

Successful application of multiscale methods in a real reservoir simulator environment

For the past 10 years or so, a number of so-called multiscale methods have been developed as an alternative approach to upscaling and to accelerate reservoir simulation. The key idea of all these methods is to construct a set of prolongation operators that map between unknowns associated with cells in a fine grid holding the petrophysical properties of the geological reservoir model and unknowns on a coarser grid used for dynamic simulation. The prolongation operators are computed numerically by solving localized flow problems, much in the same way as for flow-based upscaling methods, and can be used to construct a reduced coarse-scale system of flow equations that describe the macro-scale displacement driven by global forces. Unlike effective parameters, the multiscale basis functions have subscale resolution, which ensures that fine-scale heterogeneity is correctly accounted for in a systematic manner. Among all multiscale formulations discussed in the literature, the multiscale restriction-smoothed basis (MsRSB) method has proved to be particularly promising. This method has been implemented in a commercially available simulator and has three main advantages. First, the input grid and its coarse partition can have general polyhedral geometry and unstructured topology. Secondly, MsRSB is accurate and robust when used as an approximate solver and converges relatively fast when used as an iterative fine-scale solver. Finally, the method is formulated on top of a cell-centered, conservative, finite-volume method and is applicable to any flow model for which one can isolate a pressure equation. We discuss numerical challenges posed by contemporary geomodels and report a number of validation cases showing that the MsRSB method is an efficient, robust, and versatile method for simulating complex models of real reservoirs.     

Alakit and Daldyn kimberlite fields,Siberia,Russia:Two types of mantle sub-terranes beneath central Yakutia?

Mineral data from Yakutian kimberlites allow reconstruction of the history of lithospheric mantle.Differences occur in compositions of mantle pyropes and clinopyroxenes from large kimberlite pipes in the Alakit and Daldyn fields.In the Alakit field.Cr-diopsides are alkaline,and Stykanskaya and some other pipes contain more sub-calcic pyropes and dunitic-type diamond inclusions,while in the Daldyn field harzburgitic pyropes are frequent.The eclogitic diamond inclusions in the Alakit field are sharply divided in types and conditions,while in the Daldyn field they show varying compositions and often continuous Pressure-Temperature(P-T) ranges with increasing Fe~# with decreasing pressures.In Alakit,Crpargasites to richterites were found in all pipes,while in Daldyn,pargasites are rare Dalnyaya and Zarnitsa pipes.Cr-diopsides from the Alakit region show higher levels of light Rare Earth Elements(LREE)and stronger REE-slopes,and enrichment in light Rare Earth Elements(LREE),sometimes Th-U,and small troughs in Nb-Ta-Zr.In the Daldyn field,the High Field Strength Elements HFSE troughs are more common in clinopyroxenes with low REE abundances,while those from sheared and refertilized peridotites have smooth patterns.Garnets from Alakit show HREE minima,but those from Daldyn often have a trough at Yand high U and Pb.PTX/O2 diagrams from both regions show similarities,suggesting similar layering and structures.The degree of metasomatism is often higher for pipes which show dispersion in P-Fe~# trends for garnets.In the mantle beneath Udachnaya and Aykhal,pipes show 6-7 linear arrays of P-Fe~# in the lower part of the mantle section at 7.5-3.0 GPa,probably reflecting primary subduction horizons.Beneath the Sytykanskaya pipe,there are several horizons with opposite inclinations which reflect metasomatic processes.The high dispersion of the P—Fe~# trend indicating widespread metasomatism is associated with decreased diamond grades.Possible explanation of the differences in mineralogy and geochemistry of the mantle sections may relate to their tectonic positions during growth of the lithospheric keel.Enrichment in volatiles and alkalis possibly corresponds to interaction with subduction-related fluids and melts in the craton margins.Incorporation of island arc peridotites from an eroded arc is a possible scenario.     

Kinetic,equilibrium and thermodynamic studies of thiamethoxam adsorption by multi-walled carbon nanotubes

Because of their high adsorption capacity, carbon nanotubes have caught the attention of the scientific community and a number of experimental results confirmed their ability to adsorb many toxins from water. The aim of this work was to study the kinetics, equilibrium and thermodynamics of thiamethoxam adsorption by multi-walled carbon nanotubes in aqueous solutions. To further elucidate the influence of nanotube structure on the adsorption mechanism, the experiments were performed on both fresh (pristine) and nitric acid-modified multi-walled carbon nanotubes. The results of the kinetic studies were analyzed using three kinetic models, while the adsorption equilibrium was tested against four different adsorption models. Based on the results, and the physico-chemical properties of the adsorbent and adsorbate, it is proposed that the dominant mechanism for thiamethoxam molecules attaching to multi-walled carbon nanotubes is caused by aromatic π–π interactions (electron donor–acceptor interactions). The results of thermodynamic calculations based on the adsorption data indicate the exothermic nature of the process, regardless of the carbon nanotube type used. The decrease in entropy and the consequent negative change in Gibbs free energy, as expected, confirm the spontaneity of thiamethoxam adsorption on both pristine and functionalized multi-walled carbon nanotubes.     

Feasibility,emission and fuel requirement analysis of hybrid car versus solar electric car: a comparative study

The problem regarding environment has been considered as contemporary issue, and to cater this, various technologies have been revolutionized in vehicle transport field. Efforts have been made to make vehicle engine efficient and introducing hybridized vehicles with the aim of reducing emissions and less fuel dependency. In essence of this, trends of solar electric cars in different countries have been reviewed. Feasibility analysis is done by doing fuel cost analysis of two cases, i.e., simple hybrid vehicle and hybrid vehicle equipped with solar module and increased battery energy storage capacity for a specific round trip distance between two cities, i.e., Rawalpindi and Islamabad in comparison with feasibility of third case, i.e., proposed solar electric car model. The solar module selection along with desired number of batteries with charging and discharging time and motor power required to carry five persons weight (70 kg each) is calculated for third case. Moreover, total carbon dioxide emission analysis has been carried out from car material production to its assembly, manufacturing solar module and nickel metal hydride battery for each case. The annual carbon dioxide emitted from fuel in first two cases relative to electric outlet in third case for specific distance has been analyzed. On large scale, emission analyses for hundred cars of each case have been done at 100 km distance. From calculations, it is revealed that overall emissions in third case on large scale and from its material production, assembly, solar module and batteries manufacturing perspective are comparatively less than other cases.     

Catalytic ozonation of dimethyl phthalate by Ce-substituted goethite

Dimethyl phthalate (DMP) is ubiquitous in aquatic environments due to extensively used as plasticizer, which has received increasing attention in recent years. In this study, the catalytic ozonation of dimethyl phthalate was performed using Ce-substituted goethite as a novel catalyst, which was prepared by isomorphous substitution method. The specific surface area, pHpzc and surface hydroxyl density of the catalyst were determined. The catalyst was characterized using X-ray diffraction, scanning electron microscope and Fourier transform infrared spectroscopy. The removal efficiency of DMP was almost 100% after 30 min, and about 40% DMP was mineralized after 60 min, which was nearly four times higher than single ozonation. During catalytic ozonation process, anions (PO₄ ^3?, SO₄ ^2?, Cl^?) affected DMP degradation, indicating that surface hydroxyl groups on the surface of catalyst were main active sites. The electron transfer process by redox reaction between Ce³⁺/Ce⁴⁺, Fe²⁺/Fe³⁺ was proposed, and their interaction could also promote the formation of hydroxyl radicals. Ce-substituted goethite was an efficient catalyst for degradation of DMP by catalytic ozonation.     

Structure,Matter Composition,and Deep Structure of the Oceanic Slope of the Central Kuril Islands: New Evidence

The results of reinterpretation of the geophysical data obtained during the study of the central sector of the Kuril Island Arc (2005–2010) are reported. The new boundaries of the shallow bedding of the basement and its block uplifts of varied composition are defined within the previously discovered zone of tectonic stretching and destruction of the Vityaz submarine ridge and interarc trough. Interblock depressions filled with sedimentary and volcanogenic-sedimentary rocks are distinguished. Areas represented by volcanoplutonic complexes including basic and sialic series (up to granite) are distinguished within the unbroken basement of the Vityaz Ridge. Intrusions and volcanic edifices composed of basic rocks are registered on the whole area studied. The relationship between the formation of the destruction zone and the geodynamic processes in the mantle is illustrated by the map of the Moho relief and structural-density model of the Earth’s crust.     

Laboratory investigation of hydraulic fracture propagation using real-time ultrasonic measurement in shale formations with random natural fractures

The significance of natural fractures in unconventional shale hydrocarbon formations has opened new research frontiers in hydraulic fracturing. Among many of its unique contributions to gas production, the interaction between natural fractures and hydraulic fractures has long been experimentally and computationally investigated. Here, we experimentally investigated the evolution of the fracturing network with a self-developed ultrasonic testing system. Laboratory experiments are proposed to study the propagation of hydraulic fracture in naturally fractured model blocks that contain random micro-fractures. Our analysis suggests that the total fracture width obtained by ultrasonic pulse velocity (UPV) can reflect the dynamic evolution of the fracturing network. The nonlinear fracturing network evolution process is closely related to the variation of the total fracture width. It is suggested from the total fracture width that the maximum fracture network can be realized with greater natural fracture density, large injection rate, and smaller stress ratio. The study presents a better insight into the response of random naturally fractured shale formation under hydraulic fracturing treatment by analyzing the variation of UPV in real time.