Regional differences in plant-soil mercury relations in Equisetum, Plantago and Taraxacum

The mercury contents of Equisetum, Plantago and Taraxacum growing in the Prince George area of British Columbia varied with soil mercury level. In contrast, mercury in the same plant species growing around Mount St. Helens was soil-concentration independent. Both regions are mercury-rich, but the former is relatively thermally inactive at present. It is suggested that both populations limit their tissue mercury levels to about 100–500 ppb but that those around Mount St. Helens, where soil levels remain moderate, equilibrate tissues with atmospheric mercury from the volcano, whereas those in British Columbia depend more upon biovolatilization as a partial control process.     

The effect of montmorillonite on the thermal decomposition of fatty acids under “bulk flow” conditions

The decomposition of palmitic (C₁₆), stearic (C₁₈) and behenic (C₂₂) acids with and without montmorillonite was studied in an inert atmosphere under isothermal (250 C) “bulk flow” conditions, using a CDS-820ZA automated pyro-analyser. The C₈C₂₁ hydrocarbons and the CO₂ evolved were determined. It appears that in this open system montmorillonite affected the retention time of the acids and hence the kinetics of the reactions rather than the nature of the hydrocarbons formed. The reaction kinetics were very sensitive to changes in experimental conditions.The rate of hydrocarbon formation depended on the chain length of the carboxylic acid. In the absence of montmorillonite palmitic acid tended to sublimate before appreciable amounts of hydrocarbons were formed, stearic acid decomposed to give a range of n alkanes and alkanes while behenic acid yielded only very minor amounts of hydrocarbons. The presence of montmorillonite retarded hydrocarbon evolution with stearic acid. The hydrocarbon with one carbon atom less than the parent acid predominated in all one hour runs and the yield was increased by the presence of montmorillonite. The amount of CO₂ evolved never exceeded 10% of the maximum possible. It appears that the reaction mechanism is complex with several processes occurring concurrently.     

Corrigenda

Corrigendum

Corrigenda     

Simulation of hydraulic fracture propagation near a natural fracture using virtual multidimensional internal bonds

A virtual multidimensional internal bond (VMIB) model developed to simulate the propagation of hydraulic fractures using the finite‐element method is formulated within the framework of the virtual internal bond theory (VIB) that considers a solid as randomized material particles in the micro scale, and derives the macro constitutive relation from the cohesive law between the material particles with an implicit fracture criterion. Hydraulic pressure is applied using a new scheme that enables simulation of hydraulically driven cracks. When the model is applied to study hydraulic fracture propagation in the presence of a natural fracture, the results show the method to be very effective. It shows that although the in situ stress ratio is the dominant factor governing the propagation direction, a natural fault can also strongly influence the hydraulic fracture behavior. This influence is conditioned by the shear stiffness of the fault and the distance to the original hydraulic fracture. The model results show that when the fault is strong in shear, its impact on hydraulic fracture trajectory is weak and the hydraulic fracture will likely penetrate the fault. For a weak fault, however, the fracture tends to be arrested at the natural fault. The distance between the fault and the hydraulic fracture is also important; the fault influence increases with decreasing distance. The VMIB does not require selection of a fracture criterion and remeshing when the fracture propagates. Therefore, it is advantageous for modeling fracture initiation and propagation in naturally fractured rock. Copyright © 2010 John Wiley & Sons, Ltd.     

Pyroxenite xenoliths from an alkali trachybasalt in the Glen Innes area,northeastern New South Wales

Pyroxenite xenoliths are relatively common in an alkali trachybasalt in the Glen Innes area in northeastern New South Wales where they coexist with peridotite xenoliths, probably lherzolitic. The pyroxenites vary widely in modal composition. Several pyroxenite xenoliths are characterised by megacrystals of subcalcic clinopyroxene and enstatite, the former comprising a unique group of high pressure pyroxenes in which exsolution of orthopyroxene has proceeded on a megascopic scale. Garnet is absent from all mineral assemblages. Mineralogical and experimental data suggest that the subcalcic clinopyroxene and orthopyroxene megacrystals equilibrated initially at temperatures and pressures of the order of 1350–1450° C and 10–23 kb respectively. The most common xenoliths, namely diopsideorthopyroxene assemblages in which there is evidence of subsolidus annealing, equilibrated at comparable pressures but a significantly lower temperatures (ca. 1000° C). It is suggested that the pyroxenites and associated peridotite xenoliths are samples of essentially unmodified layered upper mantle.     

Distribution and diagenesis of organic compounds in JOIDES sediment from Gulf of Mexico and western Atlantic

Fifteen sediment samples were studied from five drill sites recovered by the ‘Glomar Challenger’ on Legs I and IV in the Gulf of Mexico and western Atlantic. This study concentrated on compounds derived from biogenic precursors, namely: (1) hydrocarbons, (2) fatty acids, (3) pigments and (4) amino acids.Carbon isotope (δC¹³) data (values < ? 26%, relative to PDB), long-chain n-alkyl hydrocarbons ( ?C₂₇7) with odd carbon numbered molecules dominating even carbon numbered species, and presence of perylene proved useful as possible indicators for terrigenous contributions to the organic matter in some samples. Apparently land-derived organic matter can be transported for distances over 1000 km into the ocean and their source still recognized.The study was primarily designed to investigate: (i) the sources of the organic matter present in the sediment, (ii) their stability with time of accumulation and (iii) the conditions necessary for in situ formation of new compounds.     

Seismic studies of low-velocity layers and horizontal inhomogeneities within the crust and upper mantle on the territory of the U.S.S.R.

Recent seismological studies of low-velocity layers in the U.S.S.R. have led to the development of new methods of investigation. The most important results obtained are presented in this paper. Several new techniques of record treatment and advanced computer programs make it possible to solve two-dimensional problems of seismic wave propagation in complex media and to outline zones of velocity inversion in the crust and mantle of many regions in the U.S.S.R.Zones of this type seem to occur only locally and are typical of some particular geostructures. Lateral inhomogeneities are also found to be closely related to geological features. Their depths sometimes can reach 300–400 km.     

Comparison of arsenic concentrations in simultaneously-collected groundwater and aquifer particles from Bangladesh,India, Vietnam,and Nepal

One of the reasons the processes resulting in As release to groundwater in southern Asia remain poorly understood is the high degree of spatial variability of physical and chemical properties in shallow aquifers. In an attempt to overcome this difficulty, a simple device that collects groundwater and sediment as a slurry from precisely the same interval was developed in Bangladesh. Recently published results from Bangladesh and India relying on the needle-sampler are augmented here with new data from 37 intervals of grey aquifer material of likely Holocene age in Vietnam and Nepal. A total of 145 samples of filtered groundwater ranging in depth from 3 to 36 m that were analyzed for As (1–1000 μg/L), Fe (0.01–40 mg/L), Mn (0.2–4 mg/L) and S (0.04–14 mg/L) are compared. The P-extractable (0.01–36 mg/kg) and HCl-extractable As (0.04–36 mg/kg) content of the particulate phase was determined in the same suite of samples, in addition to Fe(II)/Fe ratios (0.2–1.0) in the acid-leachable fraction of the particulate phase. Needle-sampler data from Bangladesh indicated a relationship between dissolved As in groundwater and P-extractable As in the particulate phase that was interpreted as an indication of adsorptive equilibrium, under sufficiently reducing conditions, across 3 orders of magnitude in concentrations according to a distribution coefficient of 4 mL/g. The more recent observations from India, Vietnam and Nepal show groundwater As concentrations that are often an order of magnitude lower at a given level of P-extractable As compared to Bangladesh, even if only the subset of particularly reducing intervals characterized by leachable Fe(II)/Fe >0.5 and dissolved Fe >0.2 mg/L are considered. Without attempting to explain why As appears to be particularly mobile in reducing aquifers of Bangladesh compared to the other regions, the consequences of increasing the distribution coefficient for As between the particulate and dissolved phase to 40 mL/g for the flushing of shallow aquifers of their initial As content are explored.     

Levels, seasonal variations, and health risks assessment of ambient air pollutants in the residential areas

People living in the urban area and the surrounding suburban area have disparities in exposure and health risks due to different levels of ambient air pollutants. The main objective of this study is to investigate the concentrations, seasonal variations, and related health risks of ambient air pollutants (PM₁₀, NO₂, and SO₂) in urban and suburban areas of Ningbo, China. The results showed that the average PM₁₀, NO₂, and SO₂ concentrations in the urban area were 85.2, 49.3, and 37.4 μg/m³, which were 1.13, 1.25, and 1.41 times the values of the suburban area during the period of March 2009 to February 2010. For the potential health risk analysis, the residents have been divided into four age categories namely, infants, children (1 year), children (8–10 years), and adults. The analysis took into account age-specific breathing rates, body weights for different age categories. The results showed that the potential health risks to respiratory disease for all age categories living in urban area were higher than those in suburban area.