Estimation of methane fluxes from bottom sediments of Lake Baikal

Methane bubble fluxes in gas flares from bottom sediments in Lake Baikal were estimated for the first time using hydroacoustic methods. Earlier work has demonstrated the occurrence of gas seeps both inside and outside of areas where bottom simulating reflectors were identified in seismic profiles. Fluxes ranged from 14 to 216 tons per year, with the flux for the entire area of the central and southern basins ranging from 1,400 to 2,800 tons per year. Comparison with other water bodies showed that fluxes from the most intensive Baikal flares were similar to those in the Norwegian and Okhotsk seas. Gas hydrates decompose at the lower boundary of the gas hydrate stability zone due to sedimentation. Calculation of the amount of methane produced due to sedimentation gave a total of between 2,600 and 14,000 tons per year for the central and southern basins of the lake. Based on rough estimation, the total flux from shallow- and deep-water gas seeps is similar to the amount of methane produced due to sedimentation. This suggests that gas hydrates possibly occupy much more than 10?% of the pore volume near the base of the gas hydrate stability zone, or that there are other reasons for gas hydrate dissociation and bubble flux from these bottom sediments.     

Authigenic iron oxide formation in the estuarine mixing zone of the Yangtze River

Estuaries are elementary geochemical fronts where river water and seawater mix. Within this mixing zone, iron and other non-conservative elements can undergo complex reactions to form new solid phases. In order to understand authigenic iron oxide formation in the Yangtze River Estuary, two onsite water-mixing sets of experiments were conducted, one by mixing variable amounts of unfiltered Yangtze River water with filtered East China Sea water of different salinity (set 1), the other by mixing variable amounts of filtered Yangtze River water with filtered East China Sea water of different salinity (set 2). In set 2, the minerals newly formed in the course of mixing were investigated by means of a scanning electron microscope fitted with an energy-dispersive X-ray analytical system. It was found that ferrihydrite and lepidocrocite were formed in these mixing experiments, coexisting in nearly equal amounts. These iron oxides appear as aggregated particles with a large grain-size range of several microns to more than 100 μm. The electrolytic properties of seawater played an important role in the formation of these authigenic iron oxides. Kaolinite and organic aggregates were also found in the experimentally mixed pre-filtered waters. Amounts of newly formed suspended matter (set 2) were one to three orders of magnitude lower than those of total suspended matter (TSM) (set 1). This implies that newly formed minerals represent only a very small proportion of TSM in the estuarine mixing zone of the Yangtze River.     

An integrated approach to assess the ecological and chemical status of lakes with HOD/AHOD: a case study of two lakes

The thermal strati?cation of the lakes impedes the transfer of atmospheric oxygen into the lower layers of the lake. In lakes which are af fected by diverse anthropogenic in?uences, the increasing organic matter amounts lead to a sharp decrease in hypolimnetic oxygen amounts, aided by thermal strati?cation,and anaerobic conditions arise. The determination of hypolimnetic oxygen demand(HOD) and areal hypolimnetic oxygen demand(AHOD) and their monitoring represent an integrated approach to investigate the oxygenation of lakes, the nutrient conditions, and the physicochemical dynamics. In this study, two lakes dif fering by size and af fected by dif ferent anthropogenic sources, are investigated in this respect. At?rst, bathymetric studies were conducted to determine the depth, surface area, and volume relationships.Then, based on monitoring studies conducted in 2013 and 2014, the thermal strati?cation dynamics and layer properties were established using the relative thermal resistance to mixing(RTRM) index based on temperature and density pro?les. Following this, the oxygen depletion rates were determined by oxygen and temperature pro?ling in the hypolimnion. For the years of 2013 and 2014, the AHOD values for the Borabey Pond which is far from anthropogenic in?uences, were found to be 0.848 and 0.569 g O 2/(m·d), respectively.The AHOD values for the Porsuk Reservoir which was overburdened for years by industrial and domestic pollution were found to be 4.263 and 5.099 g O 2/(m·d), larger than its counterpart by almost sevenfold. The HOD and AHOD monitoring can be considered to a valuable tool for assessing the ecological and chemical status of lakes within Annex 5 of the Water Framework Directive and as an integrated approach to assess and monitor the status of lakes.     

On the formation mode of the Guleman chromite deposits (Turkey)

Kefdag and Soridag chromite pods occur in upper mantle residual peridotites, which consist of harzburgite and dunites. The peridotites represent the residual of multistage, depleted upper-mantle peridotites. The chromitite bodies were formed during the uprising of chromium-rich picritic melts, through the residual upper mantle diapir, along the magma conduits. Chromitite grains were deposited in the caves of the magma conduits under the control of the convection currents.     

Electromagnetic inertio-gravity waves in the Earth's ionosphere

Propagation of electromagnetic inertio-gravity (IG) waves in the partially ionized ionospheric E- and F-layers is considered in the shallow water approximation. Accounting of the field-aligned current is the main novelty of the investigation. Existence of two new eigen-frequencies for fast and slow electromagnetic waves is revealed in the ionospheric E-layer. It is shown that in F-layer slowly damping new type of inertial-fast magnetosonic waves can propagate. Slowly damping low-frequency oscillations connected with the field-aligned conductivity are found. Broad spectrum of oscillations is investigated.     

High-resolution sediment echosounding off Peru: Late Quaternary depositional sequences and sedimentary structures of a current-dominated shelf

About 6000 km of both bathymetric and high-resolution acoustic profiles were acquired on the shelf and upper slope offshore Peru between 9° S and 14° S. Two new sediment echosounder systems – SEL-96 and SES-2000DS – provided details of the sedimentary structures of the Quaternary sequences within the Sechura-Salaverry, Huacho and Pisco Basins. To a great extent, the poleward undercurrent determines the distribution of sediments. The undercurrent has generated numerous erosional unconformities, it has winnowed hardgrounds and has created mudwaves common between 250 m and 400 m water depth. Distinct subbottom reflectors within sedimentary units represent hiatuses due to periods of intensified winnowing or non-deposition. Erosional unconformities usually marked by pronounced reflectors suggest shifts of the undercurrent system related to climatic changes and eustatic variations of sea level. On a larger scale, the stacked prograding depositional sequences reflect the sea-level cycles of the Middle Pleistocene to the Holocene. Based on the stratigraphy of our piston cores and that of Ocean Drilling Program (ODP) Site 680, the depositional sequences limited by extended unconformities were assigned to oxygen isotope stages 1 to 7. Other sedimentary structures are small straight channels that were conduits for downslope sediment transport. Deformed sediments associated with synsedimentary normal faults result from creep movements indicating beginning slope failure.     

Dynamics of an elastically moored floating body by the three-dimensional infinite element method

The three-dimensional problem of the dynamics of a moored floating object under the action of regular waves is solved numerically as a boundary value problem by use of the finite-infinite element method. The cross-sectional shape of the floating body and the mooring arrangements may all be arbitrary. The mathematical formulations of the problem and procedures of the numerical method are presented in this paper. A corresponding computer program WALOAD has been developed, which is capable of computing wave forces on fixed and floating structures. Numerical computations using this program could give very accurate results, even though rather coarse meshes were used. The program is easy to use and is readily applicable in many practical situations.     

Quaternary geology of the Amazonian Lowland

The Quaternary history of the Amazon lowlands is characterized by deposition of sediments of Andean provenance and by the influences of changing sea levels. Areas well above the present water tables were not reached by Pleistocene high-water stages. These areas have been intensively weathered since the Tertiary, forming hard lateritic weathering horizons. These weathering horizons are best explained by the relatively constant, humid tropical climate throughout the Quaternary. In the western Amazonian Lowland, flood plains corresponding to the different Pleistocene sea-level heights were formed. During low sea level, erosion in the drainage areas increased and the water levels of the central Amazon River system were lowered. Valleys drowned and lakes formed in the lower reaches of rivers and creeks during high sea-level stages. These lakes (ria lakes) remained in the valleys with rivers having a low sediment load. Seismic profiling (3.5 kHz) in some of these lakes clearly showed deposits of the three last periods of Quaternary high sea-level stages.