Phase characteristic analysis of continuous depth air-gun source wavelet

Air guns are important sources for marine seismic exploration. Far-field wavelet of air gun arrays, as a necessary parameter for pre-stack processing and source models, plays an important role during marine seismic data processing and interpretation. When an air gun fires, it generates a series of air bubbles. Similar to onshore seismic exploration, the water forms a plastic fluid near the bubble; the farther the air gun is located from the measurement, the more steady and more accurately represented the wavelet will be. In practice, hydrophones should be placed more than 100 m from the air gun; however, traditional seismic cables cannot meet this requirement. On the other hand, vertical cables provide a viable solution to this problem. This study uses a vertical cable to receive wavelets from 38 air guns and data are collected offshore Southeast Qiong, where the water depth is over 1000 m. In this study, the wavelets measured using this technique coincide very well with the simulated wavelets and can therefore represent the real shape of the wavelets. This experiment fills a technology gap in China.     

Provenance of buried esker groundwater: the case of Vars-Winchester esker aquifer,Eastern Ontario,Canada

An innovative mode of groundwater recharge to a buried esker aquifer is considered. The current conceptual model affords a natural safeguard to underlying aquifers from the overlying muds. A hypothesis of groundwater recharge to a buried esker aquifer via preferential pathways across its overlying muds is tested here by heuristic numerical one-dimensional and two-dimensional modeling simulations. The hypothesis has been tested against two other conventionally accepted scenarios involving: (1) distal esker outcrop areas and (2) remote shallow-bedrock recharge areas. The main evidence comes from documented recharge pressure pulses in the overlying mud aquitard and in the underlying esker hydraulic-head time series for the Vars-Winchester esker aquifer in Eastern Ontario, Canada. These perturbations to the potentiometric surface are believed to be the aquifer response to recharge events. The migration rate of these pressure pulses is directly related to the hydraulic diffusivity of the formation. The measured response time and response amplitude between singular radar precipitation events and well hydrographs constituted the heuristic model calibration targets. The main evidence also includes mud-layering deformation (water escape features) which was observed in seismic surveys of the over-esker muds. These disturbed stratigraphic elements provide a realistic mechanism for migrating water to transit through the muds. The effective hydraulic conductivities of these preferential pathways in the muds were estimated to be between 2?×?10^?6 and 7?×?10^?6 m/s. The implications of these findings relate to the alleged natural safeguard of these overlying muds.     

Tectonics and metallogeny of the junction zone between the North Asian craton and Pacific tectonic belt

The tectonics and metallogeny of the junction zone between the North Asian craton and Pacific tectonic belt are considered. This zone is characterized by a wide variety of structures superposed on the metamorphic basement, which was formed in the course of a multistage geologic development of the craton from the Precambrian to the Cenozoic. They are related to the craton evolution and its response to the collision and subduction processes in the adjacent orogenic belt, processes in the passive and active continental margins, and plume magmatism. The geological structure of the region includes blocks of metamorphic rocks of the Aldan–Stanovoi shield, Paleoproterozoic volcanogenic troughs, Mesoproterozoic–Neoproterozoic and Early Paleozoic structures of the platform cover, Late Paleozoic volcanic and terrigenous troughs, structures of the Late Mesozoic Okhotsk–Chukotka volcanic belt of the active continental margin, and Late Cretaceous riftogenic structures formed in response to plume magmatism. In total, six metallogenic epochs are recognized in the development of ore mineralization: Archean–Early Paleoproterozoic, Late Paleoproterozoic, Mesoproterozoic, Neoproterozoic, Late Paleozoic, and Late Mesozoic. The minerageny of the junction zone between the craton and Pacific belt is highly diversified, being characterized by distinct evolution in time and space. Each development stage features its own set of mineral resources.     

Application of a square wave potentiometry technique for electroreductive sulfur removal from a thiophenic model fuel

Thiophene-containing solutions were electroreductively desulfurized by a dynamic method. Initially, cyclic voltammetry was utilized to study thiophene electroadsorption from aqueous solution onto a platinum electrode surface and also to investigate the thiophene electroreductive behavior. Then, the solution was desulfurized via a square wave potentiometry method. The objective of this study was to find the optimal conditions. In this regard, the best adsorption potential, electroreduction potential, and square wave frequency were found to be ?0.54 V, ?0.95 V, and 1 Hz, respectively. Finally, a model fuel (containing 294 part per millions thiophene) was desulfurized by the square wave potentiometry method. Gas chromatography and Fourier transform infrared spectroscopy were used to examine the feed and product solutions. Gas chromatographic measurements revealed that sulfur content decreased to 55 part per millions. Based on the acquired results, electroreductive desulfurization could be designated as an efficient superseded for the commercial hydrodesulfurization process. However, more studies must perform to overcome technical limitations of electroreductive desulfurization technique and to guarantee its reliability.     

Effectiveness of vegetative filter strips in abating fecal coliform based on modified soil and water assessment tool

Pathogenic bacteria are a serious public health concern. Exposure to these microorganisms can result in illnesses or even death. Therefore, it is important to control pathogenic bacteria sources, transport mechanisms and fate. Best management practices proved to be very effective in the control of non-point source pollution. In this study, the soil and water assessment tool (SWAT) was modified and used to simulate the fecal coliform in Chao River of Miyun Reservoir watershed, China. The model was then used to explore the effectiveness of vegetative filter strips (VFS) in reducing fecal coliform abundance throughout the watershed. The water temperature equation within the SWAT was modified to align the model more closely with the characteristics of the study area and generate a more accurate simulation. The DAFS_ratio (20, 50, 80, 120 and 150) and DF_con (0.25, 0.4, 0.6 and 0.75) parameters were considered for VFS to see their effects on removal efficiency. The results show that calibration and validation results for fecal coliform and flow can be accepted. Different values for DAFS_ratio and DF_con have great influence on VFS. Increasing values resulted in a decrease in the removal efficiency of VFS.     

Preparation of iron phosphate from sludge sourced from the electrocoagulation treatment of source-separated urine

In order to prepare iron phosphate by waste sludge, we report a method for effective utilization of the sludge obtained from the electrocoagulation treatment of source-separated urine. The sludge was dissolved with hydrochloric acid and pretreated with H₂O₂ and Na₃PO₄; finally, NaOH was added to precipitate iron phosphate from the solution. Thermal treatment of the precipitate at 750 °C in air yielded crystalline quartz-like anhydrous FePO₄. The precipitate was characterized by a number of thermal techniques such as thermogravimetry/differential thermal analysis, scanning electron microscopy, and X-ray powder diffraction.     

Bioadsorption by sugarcane bagasse for the reduction in oil and grease content in aqueous effluent

Several techniques have been used to reduce the oil and grease content in aqueous streams; one excellent is bioadsorption. With a view to provide a sustainable method for the treatment of oily effluents, the aim of this study was to evaluate sugarcane bagasse as bioadsorbent to reduce the oil and grease content of aqueous effluents. Analysis of the material was performed, and the adsorption experiments were in a batch system, using a synthetic effluent. The results showed that the kinetic equilibrium occurred in 0.08 h of contact. The study of influence of pH of the aqueous phase and the temperature showed that the adsorption capacity was proportional to the pH value, but inversely proportional to the temperature. The adsorption isotherm was obtained at a temperature of 298.15 K using the Langmuir and Langmuir–Freundlich models, and the maximum adsorption capacity obtained was 6.65 kg of hydrocarbon per kg of bioadsorbent. It was verified that sugarcane bagasse represents an excellent material for application in the treatment of oily aqueous effluents, since it is associated with low cost and a high adsorption capacity. The variation in the adsorption capacity observed as a function of pH of the aqueous phase was not found to be significant. This is an important characteristic of the material in terms of its industrial application, verifying the possibility for its implementation in any treatment process, demonstrating the great potential of sugarcane bagasse for use as a sustainable alternative in the reduction in oil and grease in aqueous effluents.     

Adsorption of aqueous Pb(II), Cu(II), Zn(II) ions by amorphous tin(VI) hydrogen phosphate: an excellent inorganic adsorbent

Amorphous tin(VI) hydrogen phosphate (ATHP) was synthesized using the liquid phase precipitation method and served as an adsorbent to remove Pb(II), Cu(II), and Zn(II) from aqueous solutions. The ATHP was characterized by powder X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and nitrogen adsorption–desorption techniques. Adsorption properties were evaluated as a function of pH, reaction time, concentration of reactants, and salinity. Their equilibrium adsorption data were modeled using Freundlich, Langmuir, and Dubinin–Kaganer–Radushkevich isotherms, respectively. The results revealed that adsorption equilibrium reached within 180 min. ATHP indicated good adsorption even below the pH_ZPC, and best adsorption at pH 5 for Pb(II) and Cu(II) and at pH 5.5 for Zn(II) was observed. Equilibrium data fitted better to the Langmuir model for Pb(II) and Cu(II) and fitted better to the Freundlich model for Zn(II). The saturated adsorption capacities deduced from the Langmuir model were 2.425, 1.801, and 0.600 mmol/g for Cu(II), Pb(II), and Zn(II), respectively, indicating an adsorption affinity order of Cu > Pb > Zn. There is a negative correlation between the concentration of NaCl and adsorption capacity of ATHP, yet ATHP still exhibited excellent adsorption having an adsorption capacity of 19.35, 15.16, 6.425 mg/g when the concentration of NaCl was 0.6 mol/L. The free energy (E) was 12.33, 10.70, and 14.74 kJ/mol for Pb(II), Cu(II), and Zn(II), respectively. An adsorption mechanism based on ion exchange between heavy metal ions and H⁺ in the ATHP is proposed. Furthermore, the used ATHP was regenerated by HCl solution and the adsorbent was used repeatedly.