Imprint of North-Atlantic abrupt climate changes on western European loess deposits as viewed in a dust emission model

Western European loess sequences of the last glaciation (100,000–15,000 years BP) exhibit strong, cyclic variations of the sedimentation rate, which are coeval to the Greenland stadial/interstadial cycles and the Heinrich events. These North-Atlantic rapid climate changes appear, thus, as a potential cause for the sedimentation variations, via changes in dust intensity cycle. Here we make a first step in testing this hypothesis, by modelling the impact of the North-Atlantic abrupt climate variations on dust emission. Our dust emission calculations use meteorological fields generated by the LMDZ atmospheric general circulation model at a resolution down to 60 km over Western Europe. Three numerical experiments are run, representing a Greenland stadial, an interstadial and a Heinrich event. Orbital parameters and ice-sheet configuration correspond to conditions from Marine Isotope Stage 3 (60,000–25,000 years BP), a period characterized by strong millennial-scale climate variability. The only differences we impose in the boundary conditions regard the North-Atlantic surface temperature and sea-ice cover in the latitudinal band 30°–63°N. The changes in wind, precipitation, soil moisture and snow cover from one simulated state to another result in small differences in dust emission intensity. In contrast, when the inhibition of the aeolian erosion by vegetation is taken into account, the dust fluxes for the cold climate states (Greenland stadial and Heinrich event) become generally more than twice higher than those for the relatively warmer Greenland interstadial, in agreement with the loess data. These results support the hypothesis that the North-Atlantic millennial-scale variability is imprinted in Western European loess profiles, and point to vegetation changes as the main factor responsible for millennial-scale sedimentation variations. An analysis for the English Channel and southern North Sea areas, major potential dust sources, shows that the seasonality of dust emission is not controlled by the wind speed, as in modern large deserts, but by the surface conditions. Consequently, the dusty season lasts from late winter to early summer, with maximum activity in April–May, and is shifted towards summer when the climate is colder.     

长江三角洲近900年来气候变化对洪水事件的影响

Wide collection on the historic records of the climatic changes and flood events is performed in the Yangtze Delta. Man-Kendall (MK) method is applied to explore the changing trends of the time series of the flood discharge and the maximum high summer temperature. The research results indicate that the flood magnitudes increased during the transition from the medieval warm interval into the early Little Ice Age. Fluctuating climate changes of the Little Ice Age characterized by arid climate events followed by the humid and cold climate conditions give rise to the frequent flood hazards. Low-lying terrain made the study region prone to the flood hazards, storm tide and typhoon. MK analysis reveals that the jumping point of the time series of the flood discharge changes occurred in the mid-1960s, that of the maximum summer temperature changes in the mid-1990s, and the exact jump point in 1993. The flood discharge changes are on negative trend before the 1990s,they are on positive tendency after the 1990s; the maximum high summer temperature changes are on negative trend before the 1990s and on positive tendency after the 1990s. These results indicate that the trend of flood discharge matches that of the maximum high summer temperature in the Yangtze Delta. The occurrence probability of the maximum high summer temperature will be increasing under the climatic warming scenario and which will in turn increase the occurrence probability of the flood events. More active solar action epochs and the higher sea surface temperature index (SST index) of the south Pacific Ocean area lying between 4°N-4°S and 150°W-90°W correspond to increased annual precipitation, flood discharge and occurrence frequency of floods in the Yangtze Delta. This is partly because the intensified solar activities and the higher SST index give rise to accelerated hydrological circulation from ocean surface to the continent, resulting in increased precipitation on the continent.     

Separating wheat from chaff: Diatom taxon selection usingan artificial neural network pruning algorithm

This study addresses the question of what diatom taxa to includein a modern calibration set based on their relative contribution in apalaeolimnological calibration model. Using a pruning algorithm for ArtificialNeural Networks (ANNs) which determines the functionality of individual taxa interms of model performance, we pruned the Surface Water Acidification Project(SWAP) pH-diatom data-set until the predictive performance of thepruned set (as assessed by a jackknifing procedure) was statistically differentfrom the initial full-set. Our results, based on the validation at each5% data-set reduction, show that (i) 85% of the taxa canbe removed without any effect on the pH model calibration performance, and (ii)that the complexity and the dimensionality reduction of the model by theremoval of these non-essential or redundant taxa greatly improve therobustness of the calibration. A comparison between the commonly usedmarginal criteria for inclusion (species tolerance andHill's N2) and our functionality criterion shows that the importance ofeach taxon in an ANN palaeolimnological model calibration does not appear todepend on these marginal characteristics.     

Selective feeding of the oystercrassostrea gigas fed on a natural microphytobenthos assemblage

In estuarine ecosystems, microphytobenthos resuspended by tidal currents often represents a large part of the food supply available to bivalves which feed selectively. This study investigated the feeding behavior of the Pacific oysterCrassostrea gigas (Thunberg) relative to a natural microphytobenthic assemblage and the effect on the structure of this assemblage. Oysters were fed only benthic microalgae collected on the intertidal mud flats of Bourgneuf Bay (France) at a suspended particulate matter concentration above the threshold of pseudofeces production. All species in the assemblage were endemic diatoms characteritic of tidal mud flat environments. Four dominant ones, which were all solitary cells with spear-shaped frustules [Navicula ammophila (Grunow),Navicula rostellata (Kützing),Plagiotropis lepidoptera (Kuntze), andStaurophora amphioxys (Mann)] represented more than 95% of the 16 species involved. Analysis of feeding processes showed that the retention of the four main diatoms was not significantly different, but that two species, the smallest (N. ammophila [22×4 μm]) and the largest (P. lepidoptera [60×15 μm]), were preferentially ingested. The study of post-ingestive selection revealed that these two species were also preferentially digeted, i.e., preferentially directed into the digestive diverticulum, when they passed through the gut ofC. gigas. Cell size and shape did not appear to account for pre-ingestive and post-ingestive selection. The composition of the assemblage was significantly modified by oyster filtration, although the retention rates of the four main species were not significantly different. The composition of microalgae in pseudofeces and feces as a result of pre-ingestive and post-ingestive selection differed from that in seawater.     

Thermodynamic properties of solutions in metastable systems under negative or positive pressures

Metastable systems are created when the interface between the atmosphere (in which P_atm = 1 bar) and water forms a spherical meniscus either concave toward the air (water filling capillaries, wherein P_water < P_atm) or convex toward the air (fog water droplet, wherein P_water > P_atm). Soil water, undergoing negative pressure (“capillary potential”) remains bound to the solid matrix (instead of flowing downward) by the capillary meniscus, concave toward the undersaturated dry atmosphere. The positive counterpart of tensile water in soils is the pressurized water contained in fine droplets suspended in oversaturated humid air, as in clouds. All these systems are anisobaric domains the phases of which have different pressures. Geochemical consequences of such characteristics are assessed here by calculating the consequences of the positive or negative water potential on the equilibrium constants of reactions taking place in stretched or pressurized aqueous solutions. Thermodynamic properties of aqueous species are obtained by using the TH model, used explicitly for positive pressures but extrapolated to negative ones for soil solutions. It appears that soil water dissolves gases, offering an alternative explanation of the observed enrichment of atmospheric noble gases in groundwater and of carbonic gas in the unsaturated zone below the root zone. Water droplets obviously show the opposite behavior, that is, a decreasing dissolutive capability with decreasing droplet size (water pressure increases), inducing some climatic consequences. An application of this approach to the solid-solution equilibria is performed by comparing experimental solubility of amorphous silica in unsaturated media on the one hand, to theoretical calculations taking account of the negative water pressure on the other hand. This comparison outlines the potential complexity of anisobaric situations in nature and the necessity to develop a suitable approach for solid pressure.     

The early Paleozoic carbon cycle

A review of O, C, Sr and S isotope trends for the entire Phanerozoic shows that the present-day values of isotope signals are similar to those at the Proterozoic termination. The sharp rise in ⁸⁷Sr/⁸⁶Sr since 65 Ma has been attributed to an uplift and subsequent metamorphism and erosion associated with the Himalayas and Tibet. This orogenic evolution has been postulated to have influenced the global organic and inorganic carbon cycles and climate as well. A similar large-scale orogeny, the Pan-African event, also dominated the Neoproterozoic (Vendian) times, and the similarity of modern and Neoproterozoic isotope values for seawater may therefore have had a comparable tectonic cause. In this contribution, we present the results of a numerical model of the coupled C–alkalinity–S–Sr cycles suggesting that the early Paleozoic (from early Cambrian to late Devonian) evolution of Sr, O, C and S seawater isotope signals could have been the consequence of progressive oxidation of a large reduced carbon reservoir exhumed during the Pan-African orogeny. The δ¹⁸O measured in brachiopod shells is used as a forcing of the model, postulating that any change in the oxygen isotopic composition of seawater is the result of a disequilibrium in the organic carbon subcycle through the coupling of the oxygen isotopic and carbon cycles. The calculated δ¹³C, ⁸⁷Sr/⁸⁶Sr and δ³⁴S are in good agreement with the data, as is the reasonable calculated history for atmospheric pCO₂ and its relation to global climate.     

Integrated Upper Carnian to Lower Norian biochronology and implications for the Upper Triassic magnetic polarity time scale

We summarize the ammonoid, conodont and halobiid biochronology of the Upper Carnian to Lower Norian, based on a discussion of data in the Alps, Sicily, Balkans, Turkey, Himalayas and Timor. With this integrated biostratigraphic scale, the Pizzo Mondello section (Sicily) can be recalibrated and the Carnian-Norian boundary more precisely located there. As a result, the magnetostratigraphy of this section is now in good agreement with previous results from Turkey, although the latter series are more condensed. Cross-correlation of available magnetostratigraphic data from marine Tethyan sections allow us to construct a composite Upper Carnian to Upper Norian geomagnetic polarity time scale (GPTS). This GPTS leads us to question previously proposed magnetobiostratigraphic and chronostratigraphic correlations within the Upper Triassic Newark non-marine sedimentary sequence.     

Prediction of Gibbs energies of formation of compounds from the elements—II. Monovalent and divalent metal silicates

A parameter ΔO^2?, defined as the difference between the Gibbs energy of formation of a given oxide and its aqueous cation, was used to obtain linear relationships among Gibbs energies of formation from the elements of hydroxides, oxides and aqueous metallic ions (Tardy and Garrels, 1976). Use of this parameter has now been extended to meta- and orthosilicates for which the Gibbs energies of formation of silicates from their oxides are shown to be linear functions of the ΔO^2? values of their constituent cations. The function obtained for metasilicates is:

$\text{ΔG}{}^{\mathrm{o}}{}_{\mathrm{?}}\text{silicate}\text{? ∑ΔG}{}^{\mathrm{o}}{}_{\mathrm{?}}\text{oxides}\text{= ?}\text{2}\text{3}\text{(ΔO}{}^{\mathrm{2?}}\text{cation}\text{? ΔO}{}^{\mathrm{2?}}\text{silicon}$

and that for orthosilicates is:

$\text{ΔG}{}^{\mathrm{o}}{}_{\mathrm{?}}\text{silicate}\text{? ∑ΔG}{}^{\mathrm{o}}{}_{\mathrm{?}}\text{oxides}\text{= ?}\text{4}\text{4}\text{(ΔO}{}^{\mathrm{2?}}\text{cation}\text{? ΔO}{}^{\mathrm{2?}}\text{silicon}$

in which Δ^o_? silicate is the Gibbs energy of formation from the elements of a silicate of a given cation and ∑ΔG^o_? oxides is the sum of the Gibbs energies of formation from the elements of the constituent oxides of the silicate considered.These functions can be used to test for consistency within and between various sources of thermodynamic data and to estimate free energy of formation values for previously unstudied species.     

Numerical studies of heat island circulations

A two dimensional model has been set up to investigate the circulation induced by an urban heat island in the absence of synoptic winds. The boundary conditions need to be formulated carefully and due to difficulties arising here, we restrict our attention to cases of initially stable thermal stratification. Heat island circulations are allowed to develop from rest and prior to the appearance of the final symmetric double cell pattern, a transitional multi-cell pattern is observed in some cases. The influence on the steady state circulation of various parameters is studied, among which are eddy transfer coefficients, the heat island intensity, the initial temperature stratification and the heat island size. Some results are presented for a case in which differential surface cooling beneath an initially stable atmosphere produces a circulation and an unstable layer capped by an elevated inversion over the city. It is hoped that this case is vaguely representative of the night-time heat island with no geostrophic wind.Notation c_p Specific heat at constant pressure - g Acceleration due to gravity - H Top of integration region - K_z Vertical eddy transfer coefficient - K_x, K_xH, K_xm Horizontal eddy transfer coefficients for heat and momentum - l ixing length - p Pressure - p₀ Reference surface pressure (1000 mb) - P_H (x, t) Pressure at z = H - R Specific gas constant for dry air - t Time - u, w Horizontal and vertical velocities - x, z Horizontal and vertical coordinates - x₁, x₂ Positions of discontinuities in surface temperature field (see Figure 2) - x_a Heat island half-width - x_b Boundary of integration region - Parameter in formula for eddy coefficients (variable-K case) = 18.0 - _s Intensity of heat island - Potential temperature field - Reference absolute temperature (variable-K case) - _r Reference temperature (° C) - _s Surface temperature - Q Air density     

Methane and CO2 sorption and desorption measurements on dry Argonne premium coals: pure components and mixtures

Sorption and desorption behaviour of methane, carbon dioxide, and mixtures of the two gases has been studied on a set of well-characterised coals from the Argonne Premium Coal Programme. The coal samples cover a maturity range from 0.25% to 1.68% vitrinite reflectance. The maceral compositions were dominated by vitrinite (85% to 91%). Inertinite contents ranged from 8% to 11% and liptinite contents around 1% with one exception (Illinois coal, 5%). All sorption experiments were performed on powdered (−100 mesh), dry coal samples.Single component sorption/desorption measurements were carried out at 22 °C up to final pressures around 51 bar (5.1 MPa) for CO₂ (subcritical state) and 110 bar (11 MPa) for methane.The ratios of the final sorption capacities for pure CO₂ and methane (in molar units) on the five coal samples vary between 1.15 and 3.16. The lowest ratio (1.15) was found for the North Dakota Beulah-Zap lignite (VR_r=0.25%) and the highest ratios (2.7 and 3.16) were encountered for the low-rank coals (VR_r 0.32% and 0.48%) while the ratio decreases to 1.6–1.7 for the highest rank coals in this series.Desorption isotherms for CH₄ and CO₂ were measured immediately after the corresponding sorption isotherms. They generally lie above the sorption isotherms. The degree of hysteresis, i.e. deviation of sorption and desorption isotherms, varies and shows no dependence on coal rank.Adsorption tests with CH₄/CO₂ mixtures were conducted to study the degree of preferential sorption of these two gases on coals of different rank. These experiments were performed on dry coals at 45 °C and pressures up to 180 bar (18 MPa). For the highest rank samples of this sequence preferential sorption behaviour was “as expected”, i.e. preferential adsorption of CO₂ and preferential desorption of CH₄ were observed. For the low rank samples, however, preferential adsorption of CH₄ was found in the low pressure range and preferential desorption of CO₂ over the entire pressure range.Follow-up tests for single gas CO₂ sorption measurements consistently showed a significant increase in sorption capacity for re-runs on the same sample. This phenomenon could be due to extraction of volatile coal components by CO₂ in the first experiment. Reproducibility tests with methane and CO₂ using fresh sample material in each experiment did not show this effect.