Detection of C2HD and the D/H ratio on Titan

We report here the first detection of mono-deuterated acetylene (acetylene-d1, C₂HD) in Titan's atmosphere from the presence of two of its emission bands at 678 and 519 cm⁻¹ as observed in CIRS spectral averages of nadir and limb observations taken between July 2004 and mid-2007. By using new laboratory spectra for this molecule, we were able to derive its abundance at different locations over Titan's disk. We find the C₂HD value () to be roughly constant with latitude from the South to about 45° N and then to increase slightly in the North, as is the case for C₂H₂. Fitting the 678 cm⁻¹ν₅ band simultaneously with the nearby C₂H₂ 729 cm⁻¹ν₅ band, allows us to infer a D/H ratio in acetylene on Titan with an average of the modal values of 2.09±0.45×¹⁰⁻⁴ from the nadir observations, the uncertainties being mainly due to the vertical profile used for the fit of the acetylene band. Although still subject to significant uncertainty, this D/H ratio appears to be significantly larger than the one derived in methane from the CH₃D band (upper limit of 1.5×¹⁰⁻⁴; Bézard, B., Nixon, C.A., Kleiner, I., Jennings, D.E., 2007. Icarus, 191, 397-400; Coustenis, A., Achterberg, R., Conrath, B., Jennings, D., Marten, A., Gautier, D., Bjoraker, G., Nixon, C., Romani, P., Carlson, R., Flasar, M., Samuelson, R.E., Teanby, N., Irwin, P., Bézard, B., Orton, G., Kunde, V., Abbas, M., Courtin, R., Fouchet, Th., Hubert, A., Lellouch, E., Mondellini, J., Taylor, F.W., Vinatier, S., 2007. Icarus 189, 35-62). From the analysis of limb data we infer D/H values of (at 54° S), (at 15° S), (at 54° N) and (at 80° N), which average to a mean value of 1.63±0.27×¹⁰⁻⁴.     

Dense collection areas and terrestrial alteration of meteorites in the Atacama Desert

In the last 15 years, more than 2700 meteorites have been recovered and officially classified from the Atacama Desert. Although the number of meteorites collected in the Atacama has risen, the physical and climatic properties of the dense collection areas (DCAs) have not been fully characterized. In this article, we compiled the published data of all classified meteorites found in the Atacama Desert to (i) describe the distribution by meteorite groups, (ii) compare the weathering degree of chondrites among different Atacama DCAs and other hot and cold deserts, and (iii) determine the preservation conditions of chondrites in the main Atacama DCAs in relation with the local climatic conditions. The 35 DCAs so far identified in the Atacama Desert are located in three main morphotectonic units: The Coastal Range (CR), Central Depression (CD), and Pre-Andean Range/Basement. A comparison with reported weathering data from other cold and hot deserts indicates that the mean terrestrial weathering of Atacama chondrites (W1–2), displays less alteration than other hot deserts (W2–3) and resembles the weathering distribution of the Antarctic meteorites (W1–2). The highest abundance of Atacama chondrites with low weathering (≤W2) is localized in the CD (78.8%, N = 1435), which is protected from the coastal fog influence and seasonal rainfalls and displays the oldest surfaces in the Atacama Desert. The morphogenetic classification based on present-day temperatures and precipitations of the main Atacama DCAs reveals similar regional/subregional climatic conditions in the most productive areas and a truly productive surface for meteorite recovery between 5% and 58% of the quadrangles formally defined for each Atacama DCA. Our morphogenetic classification lacks consideration of some meteorological parameters such as the coastal fog, so it cannot fully explain the differences in weathering patterns among CR chondrites. Future studies of chondrite preservation in the Atacama DCAs should consider other meteorological variables such as relative humidity, specific humidity, or dew point, in combination with exposure ages of meteorites and its surfaces.     

Grain-size-sensitive flow and shear-stress enhancement at the brittle–ductile transition of the continental crust

Localized shear zones along low-angle normal faults have been identified in regions of extension at the brittle-ductile transition of the continental crust. The possibility of the strain localizing at a depth of 10 km is interpreted here as a consequence of an increase in the equivalent shear stress applied to the flow of the lower crust. This enhancement of the flow stress is seen as a prerequisite for the triggering of brittle deformation mechanisms leading to strain localization. The lower crust rheology used to examine this stress increase is strain-rate, temperature and grain-size dependent, due to the coupling of dislocation and diffusion creep. The model structure proposed consists of a top layer, the upper crust, gliding rigidly above a bottom layer, the lower crust, which deforms in simple shear. During a short time interval (1400 years), the equivalent shear stress is found to increase by a factor of up to 3 (67 MPa for anorthite and 17 MPa for quartz). For anorthite, this stress could explain the activation of a Mohr-Coulomb failure with a friction coefficient of 0.2, which is reasonable at the depth of 10 km. Dislocation creep is activated during a rapid change in the prescribed velocity, whereas diffusion creep dominates if the velocity is held constant, highlighting the importance of grain-size sensitivity for lower crustal rheology.     

A Discussion of IGS Solutions and Their Impact on Geodetic and Geophysical Applications

The International Association of Geodesy officially established the International GPS Service (IGS) on Janaury 1, 1994. Its prime objective is to provide support and a rerefence system for a wide variety of scientific and practical applications involving GPS. To fulfill its role the IGS also generates, in addition to its fundamental products (orbital/staion positions and consistent Earth orientation parameters), additional reference-system products providing the necessary infrastructure, standards, and means of calibrations for timing and various atmospheric applications of GPS. The generation and efficient application of IGS products and their impact on a number of positioning and atmospheric applications, including low earth orbit satellites, is reviewed and discussed. @ 1998 John Wiley & Sons, Inc.     

Field characterization and data integration to define the hydraulic heterogeneity of a shallow granular aquifer at a sub-watershed scale

Providing a sound basis for aquifer management or remediation requires that hydrogeological investigations carried out to understand groundwater flow and contaminant transport be based on representative data that capture the heterogeneous spatial distribution of aquifer hydraulic properties. This paper describes a general workflow allowing the characterization of the heterogeneity of the hydraulic properties of granular aquifers at an intermediate scale of a few km². The workflow involves characterization and data integration steps that were applied on a 12-km² study area encompassing a decommissioned landfill emitting a leachate plume and its main surface water receptors. The sediments composing the aquifer were deposited in a littoral–sublittoral environment and show evidence of small-scale transitional heterogeneities. Cone penetrometer tests (CPT) combined with soil moisture and electrical resistivity (SMR) measurements were thus used to identify and characterize spatial heterogeneities in hydraulic properties over the study area. Site-specific statistical relationships were needed to infer hydrofacies units and to estimate hydraulic properties from high-resolution CPT/SMR soundings distributed all over the study area. A learning machine approach was used due to the complex statistical relationships between colocated hydraulic and CPT/SMR data covering the full range of aquifer materials. Application of this workflow allowed the identification of hydrofacies units and the estimation of horizontal hydraulic conductivity, vertical hydraulic conductivity and porosity over the study area. The paper describes and discusses data acquisition and integration methodologies that can be adapted to different field situations, while making the aquifer characterization process more time-efficient and less labor-intensive.     

Fluvial incisions in the North‐Western Pyrenees (Aspe Valley): Dissection of a former planation surface and some tectonic implications

Dissected remnants of a high elevation low relief surface (HELRS) are encountered all along the Pyrenean range. All authors agree that the HELRS was shaped during the post‐shortening evolution of the belt, but doubt remains on its original elevation. Notably, whether a post‐shortening uplift event occurred after the generation of the Pyrenean planation surface is still debated. Based on a geomorphological study of the entrenchment of the Aspe River in the North‐Western Pyrenees, we describe a post‐Oligocene multi‐stage dissection of the HELRS linked to a regional post‐shortening uplift. Each incision stage is recorded by erosional triangular facets and associated stepped remnants of former smooth topographies. Compared analysis of patterns of incision in the Axial Zone and its northern border allows to evidence differential vertical motions. We discuss the forcing mechanism(s) that controlled this morphological evolution.     

Low-pressure adsorption of Ar, Kr, and Xe on carbonaceous materials (kerogen and carbon blacks), ferrihydrite, and montmorillonite: Implications for the trapping of noble gases onto meteoritic matter

Noble gases trapped in meteorites are tightly bound in a carbonaceous carrier labeled “phase Q.” Mechanisms having led to their retention in this phase or in its precursors are poorly understood. To test physical adsorption as a way of retaining noble gases into precursors of meteoritic materials, we have performed adsorption experiments for Ar, Kr, and Xe at low pressures (10⁻⁴ mbar to 500 mbar) encompassing pressures proposed for the evolving solar nebula. Low-pressure adsorption isotherms were obtained for ferrihydrite and montmorillonite, both phases being present in Orgueil (CI), for terrestrial type III kerogen, the best chemical analog of phase Q studied so far, and for carbon blacks, which are present in phase Q and can be considered as possible precursors.Based on adsorption data obtained at low pressures relevant to the protosolar nebula, we propose that the amount of noble gases that can be adsorbed onto primitive materials is much higher than previously inferred from experiments carried out at higher pressures. The adsorption capacity increases from kerogen, carbon blacks, montmorillonite to ferrihydrite. Because of its low specific surface area, kerogen can hardly account for the noble gas inventory of Q. Carbon blacks in the temperature range 75 K-100 K can adsorb up to two orders of magnitude more noble gases than those found in Q. Irreversible trapping of a few percent of noble gases adsorbed on such materials could represent a viable process for incorporating noble gases in phase Q precursors. This temperature range cannot be ruled out for the zone of accretion of the meteorite precursors according to recent astrophysical models and observations, although it is near the lower end of the temperatures proposed for the evolving solar nebula.     

Les failles récentes des Grands-Moulins (Savoie) : un Sackung (tassement gravitaire) majeur dans les Alpes françaises

In Savoy, the Grands-Moulins recent fault scarps, previously interpreted as seismic fault ruptures, are in fact part of a major Sackung (deep seated gravitational spreading) of the French Alps (9 km long). We mapped more than 60 sackung scarps, some of them reaching 1330 m long and 30 m high. These antislope scarps stop the active screes and offset relict Dryassic rock glaciers by 16 m. We present geomorphologic observations attesting for their gravitational origin. This Sackung is primarily due to glacial debuttressing, while seismic shaking could be a triggering mechanism. To cite this article: J.-C. Hippolyte et al., C. R. Geoscience 338 (2006).     

Ab initio quantum mechanical study of γ-AlOOH boehmite: structure and vibrational spectrum

The structure and vibrational spectrum of boehmite have been investigated at the quantum-mechanical level with the CRYSTAL code, using a Gaussian-type basis set and the B3LYP Hamiltonian. Three space groups are considered in this study: Cmcm, Cmc2₁, P2₁/c. Cmcm turns out to correspond to a transition state, whereas Cmc2₁ and P2₁/c are minimum energy structures. The difference among them is the position of H atoms only, the Al-O frame being essentially the same. Harmonic frequencies at the Γ point have been computed. The comparison between calculated and experimental frequencies shows a good agreement for the Al-O part of the spectrum (under 790 cm⁻¹). For the Al-OH bending modes (800–1,300 cm⁻¹) an absolute differences of 50–100 cm⁻¹ is observed; for the OH stretching modes (3,200–3,500 cm⁻¹) it increases to 120–200 cm⁻¹: anharmonicity is large because OH groups are involved in strong hydrogen bonds.