Determination of Uranium in Thirty-six Geological Reference Samples by Fluorimetry and Extractive Spectrophotometry

The uranium contents of 36 geological reference samples have been determined by fluorimetry after ion-exchange separation, and spectrophotometry using Arsenazo III after solvent extraction with tri-n-octylphosphine oxide. The agreement between present results and published data is generally good. The methods of fluorimetry and spectrophotometry proved very convenient in the determination of uranium in geological materials.     

Strontium concentrations and strontium-chlorinity ratios in sea water of the North Pacific and the adjacent seas of Japan

Strontium contents of 232 sea water samples collected at various stations in the North Pacific and adjacent seas of Japan were measured by the atomic absorption spectrophotometry and strontium-chlorinity ratios were determined. Mean Sr concentration is 8.08 mg/kg and mean Sr/Cl ratio is 0.425 mg/kg/Contrary to some recent reports, regional and vertical variations of Sr/Cl ratios were statistically insignificant, and presence of particulate strontium was not confirmed.     

Changes in the lower limit of mountain permafrost between 1973 and 2004 in the Khumbu Himal, the Nepal Himalayas

Because the Khumbu Himal of the Nepal Himalayas lacks long-term climate records from weather stations, mountain permafrost degradation serves as an important indicator of climate warming. In 1973, the permafrost lower limit was estimated to be 5200–5300 m above sea level (ASL) on southern-aspect slopes in this region. Using ground-temperature measurements, we examined the mountain permafrost lower limit on slopes with the same aspect in 2004. The results indicate that the permafrost lower limit was 5400–5500 m ASL in 2004. The permafrost lower limit was estimated to be 5400 to 5500 m on slopes with a southern aspect in the Khumbu Himal in 1991 using seismic reflection soundings. Thus, it is possible that the permafrost lower limit has risen 100–300 m between 1973 and 1991, followed by a stable limit of 5400 to 5500 m over the last decade. An increase in mean annual air temperature of approximately 0.2 to 0.4 °C from the 1970s to the 1990s has indicated a rise in the permafrost lower limit of 40 to 80 m at the Tibetan Plateau. The rise in the mountain permafrost lower limit in the Khumbu Himal exceeds that of the Tibetan Plateau, suggesting the possibility of greater climate warming in the Khumbu Himal.     

Estimates of the turbulent kinetic energy budget in the oceanic convective boundary layer

The terms of the steady-state turbulent kinetic energy (TKE) budget in the oceanic convective boundary layer (CBL) are estimated by use of microstructure data obtained over the continental shelf of the East China Sea. The dissipation term is calculated from the micro-scale vertical shear of horizontal velocity measured directly using a freely-falling microstructure profiler, whereas the buoyancy flux and shear production terms are estimated indirectly by integrating vertically the one-dimensional conservation equation of density and by applying similarity theory, respectively. The transport term, calculated as the residual of the other three terms, vertically redistributes the TKE from the upper half of the CBL to the lower half, consistent with the TKE budgets in the atmospheric CBL and in shear-free and slightly-sheared CBLs simulated by large eddy-simulation models. The relatively large contribution of the transport term to the TKE budget shows that a local equilibrium form of the TKE equation is not appropriate for the TKE budget in the oceanic CBL.     

Zircon U–Pb ages of plutonic rocks in the southern Abukuma Mountains: Implications for Cretaceous geotectonic evolution of the Abukuma Belt

Plutonic rocks in the southern Abukuma Mountains include gabbro and diorite, fine‐grained diorite, hornblende–biotite granodiorite (Ishikawa, Samegawa, main part of Miyamoto and Tabito, Kamikimita and Irishiken Plutons), biotite granodiorite (the main part of Hanawa Pluton and the Torisone Pluton), medium‐ to coarse‐grained biotite granodiorite and leucogranite, based on the lithologies and geological relations. Zircon U–Pb ages of gabbroic rocks are 112.4 ±1.0 Ma (hornblende gabbro, Miyamoto Pluton), 109.0 ±1.1 Ma (hornblende gabbro, the Hanawa Pluton), 102.7 ±0.8 Ma (gabbronorite, Tabito Pluton) and 101.0 ±0.6 Ma (fine‐grained diorite). As for the hornblende–biotite granodiorite, zircon U–Pb ages are 104.2 ±0.7 Ma (Ishikawa Pluton), 112.6 ±1.0 Ma (Tabito Pluton), 105.2 ±0.8 Ma (Kamikimita Pluton) and 105.3±0.8 Ma (Irishiken Pluton). Also for the medium‐ to fine‐grained biotite granodiorite, zircon U–Pb ages are 106.5±0.9 Ma (Miyamoto Pluton), 105.1 ±1.0 Ma (Hanawa Pluton) and the medium‐ to coarse‐grained biotite granodiorite has zircon U–Pb age of 104.5 ±0.8 Ma. In the case of the leucogranite, U–Pb age of zircon is 100.6 ±0.9 Ma. These data indicate that the intrusion ages of gabbroic rocks and surrounding granitic rocks ranges from 113 to 101 Ma. Furthermore, K–Ar ages of biotite and or hornblende in the same rock samples were dated. Accordingly, it is clear that these rocks cooled down rapidly to 300 °C (Ar blocking temperature of biotite for K–Ar system) after their intrusion. These chronological data suggest that the Abukuma plutonic rocks in the southern Abukuma Mountains region uplifted rapidly around 107 to 100 Ma after their intrusion.     

Relationship between sinking organic matter and minerals in the shallow zone of the western Subarctic Pacific

We used time-series sediment trap data for four major components, organic matter and ballast minerals (CaCO₃, opal, and lithogenic matter) from 150, 540, and 1000 m in the western subarctic Pacific (WSAP), where opal is the predominant mineral in sinking particles, to develop four simple models for settling particles, including the “ballast model”. The ballast model is based on the concept that most of the organic matter “rain” in the deep sea is carried by the minerals. These four models are designed to simultaneously reproduce the flux of each major component of settling particles at 540 and 1000 m by using the data for each component at 150 m as initial values. Among the four models, the ballast model, which considers the sinking velocity increase with depth, was identified as the best using the Akaike information criterion as a measure of the model fit to data. This model successfully reproduced the flux of organic matter at 540 and 1000 m, indicating that the ballast model concept works well in the shallow zone of the WSAP on a seasonal timescale. This also suggests that ballast minerals not only physically protect the organic matter from degradation during the settling process but also enhance the sinking velocity and reduce the degree of decomposition.     

Audio frequency magneto-telluric survey of Norikura Volcano in central Japan

Norikura Volcano has not been active during the last 10,000 years in spite of the activity of the surrounding volcanic mountains. To study past volcanic activities, geological studies were carried out extensively. However, quite a few geophysical investigations were conducted to contribute to volcanology. Our objective is to detect the present subsurface structure of Norikura Volcano and to define volcanic stratifications. In the vicinity of Norikura Volcano, geothermal fields are still active. Subsurface volcanic rocks in this area have been exposed to geothermal activity and altered. To comprehend volcanic stratifications of Norikura and geothermal activity, we conducted audio frequency magneto-telluric (AMT) surveys around Norikura Volcano. AMT survey is useful in clearly defining the resistivity structure related to volcanic regions. The AMT data were acquired over a frequency range 10 Hz–10 kHz. Decomposition analysis was applied to the tensor impedance data. Subsequently, apparent resistivity and phase data were inverted using a two-dimensional magneto-telluric (MT) inversion and a model of Norikura was derived. The final model manifests that the surface resistors are in agreement with andesite lava or dacite lava. As for the deeper structure, a horizontal conductor is situated above resistive basements. The alteration of the conductor was weak, while basement rocks were strongly altered and/or heated through the thermal activity. The existence of these layers seems to indicate the degree of thermal activity of Norikura Volcano.     

Geology of the summit limestone of Mount Qomolangma (Everest) and cooling history of the Yellow Band under the Qomolangma detachment

Abstract   Newly discovered peloidal limestone from the summit of Mount Qomolangma (Mount Everest) contains skeletal fragments of trilobites, ostracods and crinoids. They are small pebble-sized debris interbedded in micritic bedded limestone of the Qomolangma Formation, and are interpreted to have been derived from a bank margin and redeposited in peri-platform environments. An exposure of the Qomolangma detachment at the base of the first step (8520 m), on the northern slope of Mount Qomolangma was also found. Non-metamorphosed, strongly fractured Ordovician limestone is separated from underlying metamorphosed Yellow Band by a sharp fault with a breccia zone. The ⁴⁰Ar–³⁹Ar ages of muscovite from the Yellow Band show two-phase metamorphic events of approximately 33.3 and 24.5 Ma. The older age represents the peak of a Barrovian-type Eo-Himalayan metamorphic event and the younger age records a decompressional high-temperature Neo-Himalayan metamorphic event. A muscovite whole-rock ⁸⁷Rb–⁸⁶Sr isochron of the Yellow Band yielded 40.06 ± 0.81 Ma, which suggests a Pre-Himalayan metamorphism, probably caused by tectonic stacking of the Tibetan Tethys sediments in the leading margin of the Indian subcontinent. Zircon and apatite grains, separated from the Yellow Band, gave pooled fission-track ages of 14.4 ± 0.9 and 14.4 ± 1.4 Ma, respectively. These new chronologic data indicate rapid cooling of the hanging wall of the Qomolangma detachment from approximately 350°C to 130°C during a short period (15.5–14.4 Ma).