Simultaneous vertical measurements of in situ pH and CO2 in the sea using spectrophotometric profilers

We have developed new systems capable of profiling to >1000 m for measuring in situ pH and fugacity of CO₂ (fCO₂) in the ocean using spectrophotometric analysis (pH and CO₂ profilers). The in situ pH is determined by detecting the color change of the pH indicator (m-cresol purple). It can withstand ambient pressure to 1000 m depth. The CO₂ profiler analyzed in situ fCO₂ by detecting the change of pH in an inner solution, equilibrated with the seawater through a gas permeable membrane. It can be operated to 2500 m depth. We used an amorphous fluoropolymer tubing form of AF-2400 for the gas permeable membrane due to its high gas permeability coefficients. The inner solution was a mixture of 2 μM bromocresol purple (BCP) and 5 μM sodium hydroxide. This system gave us a response time of 1 minute, which is twice as fast as previous systems. The precisions of pH and CO₂ profilers were within 0.002 and 2.5% respectively. We have used these profilers to study the North Pacific, obtaining good agreement with the difference between the data from profilers and a discrete bottle of 0.002 ± 0.005 pH (SE, n = 25) and −0.4 ± 3 μatm (SE, n = 31).     

Magnetic field and current sheets in the corona above active regions

A new method for the calculation of coronal magnetic field is proposed and it is shown to reproduce the EUV features in the corona as observed by Skylab experiments satisfactorily well. One of the remarkable points is that it reproduces the loopy threads in the active region corona and also the large scale field lines connecting active regions. The existence of coronal current is expected wherever the present coronal-current-free model fails to represent the feature. A method of calculating the coronal sheet-current is also developed with the purpose of knowing the shape of the current sheet and the amount of magnetic stress energy stored due the the presence of it by comparing the calculated field configuration with the observed local distortion of the EUV threads. This may be used in pinning down the possible site of the flare and in discussing the flare occurrence in terms of the energy stored there.During the preparation of this work, Poletto et al. (1975) calculated the magnetic field shape in Schmidt's method to compare with the soft X-ray feature obtained by Skylab.     

Determination of Uranium in Thirty-six Geological Reference Samples by Fluorimetry and Extractive Spectrophotometry

The uranium contents of 36 geological reference samples have been determined by fluorimetry after ion-exchange separation, and spectrophotometry using Arsenazo III after solvent extraction with tri-n-octylphosphine oxide. The agreement between present results and published data is generally good. The methods of fluorimetry and spectrophotometry proved very convenient in the determination of uranium in geological materials.     

The Structure of Young Stellar Jets and Winds Revealed by High Resolution [Fe II] λ1.644μm Line Observations

We present high angular resolution spectra taken along the jets from L1551 IRS 5 and DG Tau obtained with the Subaru Telescope. The position-velocity diagrams of the [Fe II] λ 1.644 μmemission line revealed remarkably similar characteristics for the two sources, showing two distinct velocity components separated from each other in both velocity and space with the entire emission range blueshifted with respect to the stellar velocity. The high velocity component (HVC) has a velocity of –200 ––300 km s^-1 with a narrow line width, while the low velocity component (LVC) is around –100 km s^-1 exhibitinig a broad line width. The HVC is located farther away from the origin and is more extended than the LVC. Our results suggest that the HVC is a well-collimated jet originating from the region close to the star, while the LVC is a widely-opened wind accelerated in the region near the inner edge of the accretion disk.     

Potential of Oil Palm Trunk Sap as a Novel Inexpensive Renewable Carbon Feedstock for Polyhydroxyalkanoate Biosynthesis and as a Bacterial Growth Medium

Utilization of cheap renewable carbon feedstock for polyhydroxyalkanoate (PHA) production not only brings down its production cost but also ensures sustainability. The scope of this study was to evaluate the potential of sap extracted from felled oil palm trunk (OPT) as a novel inexpensive renewable carbon source for PHA production. OPT sap was found to be nutritionally rich and contained various fermentable sugars (5.5% w/v) as its major constituent. Termite gut isolate, Bacillus megaterium MC1 grew profoundly in mineral medium with OPT sap as carbon source and a cell density of 10.9 g/L was attained after 16 h of cultivation in shake flask cultures. A maximum poly‐3‐hydroxybutyrate [P(3HB)] content (% cell dry weight; CDW) of 30 wt% and a P(3HB) concentration of 3.28 g/L was recorded. Additionally, OPT sap extracted from younger tree trunks with prolonged storage had higher sugar content (10.8% w/v) and, when used as a growth medium without the addition of any nutrients, supported bacterial growth comparable to commercially available media.     

Rapid decrease of mass balance observed in the Xiao (Lesser) Dongkemadi Glacier,in the central Tibetan Plateau

The mass balance of the Xiao (Lesser) Dongkemadi Glacier located in the Tanggula Mountains, of the central Qinghai‐Tibetan Plateau has been monitored since 1989. The results show that the mass balance of the glacier has recently shown a deficit trend, and that the glacial terminus was also retreating. Positive mass balance of the glacier was dominant during the period 1989–1993, and the accumulated mass balance reached 970 mm. However, negative mass balance of the glacier has occurred since 1994, except for the large positive mass balance year 1997. The mass balance was ? 701 mm in 1998, an extremely negative glacier mass balance year. The equilibrium line altitude showed a significant increasing trend. The mass balance of the glacier has changed from a significantly positive mass balance to a strongly negative mass balance since 1994. Meteorological data suggest that the rapid decrease in the mass balance is related to summer season warming. Copyright © 2007 John Wiley & Sons, Ltd.     

Strontium concentrations and strontium-chlorinity ratios in sea water of the North Pacific and the adjacent seas of Japan

Strontium contents of 232 sea water samples collected at various stations in the North Pacific and adjacent seas of Japan were measured by the atomic absorption spectrophotometry and strontium-chlorinity ratios were determined. Mean Sr concentration is 8.08 mg/kg and mean Sr/Cl ratio is 0.425 mg/kg/Contrary to some recent reports, regional and vertical variations of Sr/Cl ratios were statistically insignificant, and presence of particulate strontium was not confirmed.     

Changes in the lower limit of mountain permafrost between 1973 and 2004 in the Khumbu Himal, the Nepal Himalayas

Because the Khumbu Himal of the Nepal Himalayas lacks long-term climate records from weather stations, mountain permafrost degradation serves as an important indicator of climate warming. In 1973, the permafrost lower limit was estimated to be 5200–5300 m above sea level (ASL) on southern-aspect slopes in this region. Using ground-temperature measurements, we examined the mountain permafrost lower limit on slopes with the same aspect in 2004. The results indicate that the permafrost lower limit was 5400–5500 m ASL in 2004. The permafrost lower limit was estimated to be 5400 to 5500 m on slopes with a southern aspect in the Khumbu Himal in 1991 using seismic reflection soundings. Thus, it is possible that the permafrost lower limit has risen 100–300 m between 1973 and 1991, followed by a stable limit of 5400 to 5500 m over the last decade. An increase in mean annual air temperature of approximately 0.2 to 0.4 °C from the 1970s to the 1990s has indicated a rise in the permafrost lower limit of 40 to 80 m at the Tibetan Plateau. The rise in the mountain permafrost lower limit in the Khumbu Himal exceeds that of the Tibetan Plateau, suggesting the possibility of greater climate warming in the Khumbu Himal.