Triggered star formation in the LMC4/Constellation III region of the Large Magellanic Cloud

We present multicolour images of the hosts of three z  = 2 QSOs previously detected in the R band by our group. The luminosities, colours and sizes of the hosts overlap with those of actively star-forming galaxies in the nearby Universe. Surface brightness radial profiles over the outer resolved areas roughly follow either an r ^1/4 or an exponential law. These properties give support to the young host galaxy interpretation of the extended light around QSOs at high redshift. The rest-frame UV and UV–optical colours are inconsistent with the hypothesis of a scattered halo of light from the active nucleus by a simple optically thin scattering process produced by dust or hot electrons. If the UV light is indeed stellar, star formation rates of hundreds of solar masses per year are implied, an order of magnitude larger than in field galaxies at similar redshifts and above. This might indicate that the QSO phenomenon (at least the high-luminosity one) is preferentially accompanied by enhanced galactic activity at high redshifts.     

Oxidation of arsenopyrite and deposition of gold on the oxidized surfaces: A scanning probe microscopy, tunneling spectroscopy and XPS study

We have used ex situ atomic force microscopy (AFM), scanning tunneling microscopy and spectroscopy (STM/STS) and X-ray photoelectron spectroscopy (XPS) to study the surfaces of natural arsenopyrite samples that were electrochemically polarized in 1 M HCl, or leached in acidic solutions containing ferric iron salts, and then reacted with aqueous gold (III) chloride at ambient temperatures. For arsenopyrite oxidized on a positive-going potential sweep, progressively increasing amounts of surface Fe(III)-O and As-O species, and of S/Fe and S/As ratios in a non-stoichiometric sulfidic layer were found. The products formed in the sweep to a potential of 0.6 V (Ag/AgCl) of the passivity region are shaped in about 100 nm protrusions of two sorts, which are arranged in micrometer-size separate areas, while they are largely mixed at higher, “transpassive” potentials. The quantities of surface alteration substances notably decrease after leaching in ferric chloride and ferric sulfate acidic solutions. Passivation of arsenopyrite was suggested to associate with the disordered, metal-deficient surface layer having moderate excess of sulfur rather than with the products of arsenopyrite oxidation. Exposure of arsenopyrite to 10⁻⁵-10⁻³ M (pH 2) solutions results in the deposition of 8-50 nm gold particles; only a small fraction of the gold is present as Au(I)-S species. The electrochemical oxidation at 0.6 V or ageing of arsenopyrite in air promotes the subsequent gold deposition; in contrast, the amount of Au deposited on arsenopyrite that was treated by leaching in ferric chloride and sulfate solutions was about 10 times smaller than with polished arsenopyrite samples. It has been concluded that reducing agents formed as intermediates of arsenopyrite decomposition facilitate the Au⁰ cementation although other factors related to the surface state of the arsenopyrite play a role as well. A decrease in the tunneling current magnitudes with decreasing the Au⁰ particle size has been revealed using STS. This effect along with the increase by 0.2-0.5 eV in the XPS Au 4f binding energies were tentatively ascribed to retarding the electron transitions by emerging electrostatic charge on gold nanoparticles (Coulomb blockade). Possible mechanisms for the effects, and their potential role in the deposition and hydrometallurgy of “invisible” gold are discussed.     

Basin-To-Basin and Year-To-Year Variation of Temperature and Salinity Characteristics in the East Sea (Sea of Japan)

Analysis of CTD data from four CREAMS expeditions carried out in summers of 1993–1996 produces distinct T-S relationships for the western and eastern Japan Basin, the Ulleung Basin and the Yamato Basin. T-S characteristics are mainly determined by salinity as it changes its horizontal pattern in three layers, which are divided by isotherms of 5°C and 1°C; upper warm water, intermediate water and deep cold water. Upper warm water is most saline in the Ulleung Basin and the Yamato Basin. Salinity of intermediate water is the highest in the eastern Japan Basin. Deep cold water has the highest salinity in the Japan Basin. T-S curves in the western Japan Basin are characterized by a salinity jump around 1.2–1.4°C in the T-S plane, which was previously found off the east coast of Korea associated with the East Sea Intermediate Water (Cho and Kim, 1994). T-S curves for the Japan Basin undergo a large year-to-year variation for water warmer than 0.6°C, which occupies upper 400 m. It is postulated that the year-to-year variation in the Japan Basin is caused by convective overturning in winter. This revised version was published online in August 2006 with corrections to the Cover Date.     

Comparison of statistical methods and multi-time validation for the determination of the shallow landslide rainfall thresholds

Shallow landslides are unforeseeable phenomena often resulting in critical conditions in terms of people’s safety and damage. The main purpose of this paper is the comparison of different statistical methods used to determine the rainfall thresholds for the shallow landslide occurrence. Rainfall data over a 46-year period were collected for one rain gauge located in a test area of northwest Italy (Riviera Spezzina; RS). In the RS, intense rainfalls often induce shallow landslides causing damage and sometimes casualties. The rainfall events occurred in the 1967–2006 period were classified as events inducing shallow landslides (SLEs_1967–2006) and events that did not trigger shallow landslides (NSLEs_1967–2006). Thresholds for various percentiles of SLEs_1967–2006 were computed by identifying the lower limit above which shallow landslides occurred. Another set of thresholds, corresponding to different probabilities of occurrence, was determined using SLEs_1967–2006 and NSLEs_1967–2006. The least-squares linear fit (LSF) and the quantile regression (QR) techniques were employed in the former approach, while the logistic regression (LR) was applied in the latter. The thresholds were validated with the same data used for their definition and with the data recorded in the 2008–2014 period. Contingency tables were created and contingencies and skill scores were computed. The 10% probability threshold obtained using the LR method is characterized by the best values of at least two skill scores for both periods considered; therefore, it may be considered the “best” threshold for the RS. The results of this work can help the choice of the best statistical method to determine the shallow landslide rainfall thresholds.     

Post‐Younger Dryas deglaciation of the Greenland western margin as revealed by spatial analysis of lakes

Lake shapes and their spatial distribution are important geomorphological indicators in previously glaciated areas. Their shapes are influenced by the underlying geological structure and processes of glacial sediment deposition or erosion. Since these processes act on large areas, distribution of lakes can reflect the intensity of glacial erosional/depositional processes and their spatial extent. Landsat imagery was used to extract lake outlines from a selected pilot‐study area on the widest ice‐free coastal margin of the south‐western Greenland north of Kangerlussuaq. Analysis included image classification and spatial analysis of lakes with elevation data using geographic information system (GIS) tools. A morphometric index was applied to extract kettle lakes as indicators of a specific glacial process – ice stagnation. Analysis of their spatial distribution helped in the reconstruction of glacial dynamics in formerly glaciated terrain. Our results show that spatial lake distribution combined with elevation analysis can be used to identify zones of glacial erosion and deposition. The highest concentrations of lakes within the study area occupy the elevation range between 164 and 361 m above sea level (a.s.l.). This zone can be identified as an area where intensive glacial erosion took place in the past. The widespread distribution of modeled kettle lake features within the same elevation range and across the study area suggests that the last deglaciation process was accompanied by abandonment of blocks of stagnant ice. This conclusion is supported by surface exposure ages obtained in the same study area and published elsewhere. Copyright © 2009 John Wiley & Sons, Ltd.     

Spatial and vertical distributions of elements in sediments of the Colorado River delta and Upper Gulf of California

The abundance of major components (Fe, Ca, K, and organic carbon) and trace elements was analyzed in surface sediments and core samples from the Colorado River delta (CRD) and the Upper Gulf of California (UGC) using instrumental neutron activation analysis.The spatial distribution patterns of the elements studied are consistent with the model of sedimentary dynamics proposed for this area [Mar. Geol. 158 (1999) 125]: intense tidal resuspension of sediments in the delta with subsequent transport of suspended particulate matter in a southerly direction, followed by sedimentation of fine-grained material in a depocenter near the southwestern margin of the UGC. Concentrations of most of the elements are higher in the surface sediments of this depocenter. The gradual mixing of terrigenous and marine biogenic materials, normally expected for the estuarine sediments, was not detected in the CRD–UGC system because of homogenization of the sediments by tides and wind.Vertical profiles of element contents in samples of the sediment core collected in the depocenter area revealed (i) almost no anthropogenic contamination of the area by environmentally important trace elements such as Cr, Co, Sb, and As; (ii) a twofold decrease of Fe, Sc, Cr, and Co in upper core sediments; and (iii) the enrichment of the sediments at 60–62 cm depth in the core, in calcium carbonate, Ca, Sr, and the Eu_n/Sm_n shale-normalized ratio along with a depletion in this layer of Fe, Sc, Cr, Co, light rare-earth elements (REEs), and some other elements of terrigenous origin, presumably caused by the dilution of fluvial terrigenous material by biogenic carbonates, which were probably introduced at this level in the sediments by the action of a strong episodic winter storm, followed by the advective transport of shell fragments from the coastal clam banks or as a result of strong planktonic bloom.     

The U-Pb systematics of angrite Sahara 99555

Angrite Sahara 99555 (hereafter SAH), precisely dated by Baker et al. (Baker J., Bizzarro M., Wittig N., Connelly J. and Haack H. (2005) Early planetesimal melting from an age of 4.5662 Gyr for differentiated meteorites. Nature436, 1127-1131), has been proposed as a new reference point for the early Solar System timescale and for calculation of the revised minimum age of our Solar System. The Pb-Pb age of SAH of 4566.18 ± 0.14 Ma, reported by Baker et al., differs from the Pb-Pb age of D’Orbigny, another basaltic angrite, of 4564.42 ± 0.12 Ma (Amelin Y. (2008) U-Pb ages of angrites. Geochim. Cosmochim. Acta72, 221-232), despite the fact that the relative ⁵³Mn-⁵³Cr and ¹⁸²Hf-¹⁸²W ages of these meteorites are identical. Here I report U-Pb data for 21 whole rock and pyroxene fractions from SAH, analyzed using the same approach as D’Orbigny (Amelin, 2008). These fractions contain between 1.3 and 8.9 pg of total common Pb, slightly more than analytical blank. Measured ²⁰⁶Pb/²⁰⁴Pb ratios are between 625 and 2817 for D’Orbigny, blank-corrected ²⁰⁶Pb/²⁰⁴Pb ratios are between 1173 and 6675. Eight acid-washed whole rock fractions yielded an isochron age of 4564.86 ± 0.38 Ma, MSWD = 1.5. Data for pyroxene fractions plot mostly above the whole rock isochron, and do not form a linear array in ²⁰⁷Pb/²⁰⁶Pb vs. ²⁰⁴Pb/²⁰⁶Pb isochron coordinates. The ²⁰⁷Pb^∗/²⁰⁶Pb^∗ model dates of the pyroxene fractions vary from 4563.8 ± 0.3 to 4567.1 ± 0.5 Ma. The difference between whole rock and pyroxene U-Pb systematics may be a result of re-distribution of radiogenic Pb at a mineral grain scale several million years after crystallization. Complexities of Sm-Nd, Lu-Hf, and possibly ²⁶Al-²⁶Mg mineral systematics of SAH, described previously, may be related to the same process that caused the re-distribution of radiogenic Pb. Disturbance of isotopic chronometers renders SAH an imperfect anchor for the early Solar System timescale. The problems with age determination revealed by the studies of SAH call for greater attention in Pb-isotopic dating of angrites and other achondrites.     

Geochemistry of the volcano-hydrothermal system of El Chichón Volcano, Chiapas, Mexico

 The 1982 eruption of El Chichón volcano ejected more than 1 km³ of anhydrite-bearing trachyandesite pyroclastic material to form a new 1-km-wide and 300-m-deep crater and uncovered the upper 500 m of an active volcano-hydrothermal system. Instead of the weak boiling-point temperature fumaroles of the former lava dome, a vigorously boiling crater spring now discharges  / 20 kg/s of Cl-rich (∼15 000 mg/kg) and sulphur-poor ( / 200 mg/kg of SO₄), almost neutral (pH up to 6.7) water with an isotopic composition close to that of subduction-type magmatic water (δD=–15‰, δ¹⁸O=+6.5‰). This spring, as well as numerous Cl-free boiling springs discharging a mixture of meteoric water with fumarolic condensates, feed the crater lake, which, compared with values in 1983, is now much more diluted (∼3000 mg/kg of Cl vs 24 030 mg/kg), less acidic (pH=2.6 vs 0.56) and contains much lower amounts of S ( / 200 mg/kg of SO₄, vs 3550 mg/kg) with δ³⁴S=0.5–4.2‰ (+17‰ in 1983). Agua Caliente thermal waters, on the southeast slope of the volcano, have an outflow rate of approximately 100 kg/s of 71  °C Na–Ca–Cl water and are five times more concentrated than before the eruption (B. R. Molina, unpublished data). Relative N₂, Ar and He gas concentrations suggest extensional tectonics for the El Chichón volcanic centre. The ³He/⁴He and ⁴He/²⁰Ne ratios in gases from the crater fumaroles (7.3R_a, 2560) and Agua Caliente hot springs (5.3R_a, 44) indicate a strong magmatic contribution. However, relative concentrations of reactive species are typical of equilibrium in a two-phase boiling aquifer. Sulphur and C isotopic data indicate highly reducing conditions within the system, probably associated with the presence of buried vegetation resulting from the 1982 eruption. All Cl-rich waters at El Chichón have a common source. This water has the appearence of a "partially matured" magmatic fluid: condensed magmatic vapour neutralized by interaction with fresh volcaniclastic deposits and depleted in S due to anhydrite precipitation. Shallow ground waters emerging around the volcano from the thick cover of fresh pumice deposits (Red waters) are Ca–SO₄–rich and have a negative oxygen isotopic shift, probably due to ongoing formation of clay at low temperatures. Received: 21 July 1997 / Accepted: 4 December 1997     

Complex geographical analysis of the Greater Sochi region on the Black Sea coast

Results of the complex analysis of the unique natural territory of Greater Sochi from the point of view of physical geography are considered. The region of Greater Sochi is located on the S slopes of the Main Caucasus chain on the eastern coast of the Black Sea. Morphometrical analysis of the relief and analysis air surface temperature and precipitation allowed to distinguish four specific subregions within the whole territory. It is demonstrated that the period of stable snow cover in the two subregions which occupy more than half of the region's area is sufficient for successful development of winter tourism. Peculiar combination of the mild climate of the coast with stable snow cover in the mountains till the beginning of summer provide strong attractivity of the region for all-the-year-round tourists inflow to the most modern recreational centre of Russia. The work provides the methodology for similar studies.