Comparison between VES and 2D imaging techniques for delineating subsurface plume of hydrocarbon contaminated water southeast of Karbala City,Iraq

Shallow vertical electrical sounding (VES) technique with Schlumberger electrode array (maximum distance between current electrodes was 50 m) through 25 VES points distributed on five traverses. Two 2D imaging lines with Wenner electrode array 30 m each corresponding to two VES traverses were conducted near well water contaminated with hydrocarbon materials at Karbala Governorate, Iraq. It is found that these techniques can give good results in delineating contaminated and clear zones but the 2D imaging technique was better in delineating the boundaries of the contaminated water plume and gave clear image of the subsurface distribution of the contaminated water vertically and horizontally.     

Estimation of the methane flux from mud volcanoes along Chishan Fault,southwestern Taiwan

Because of the increasing public awareness of the greenhouse effect, geological emissions of methane (GEM) have gained more attention. The Intergovernmental Panel on Climate Change included GEM in the natural sources of methane category in the Fourth Assessment Report in 2007. The methane flux from mud volcanoes (MVs) is the second leading source within GEM. However, given that gas flux from MVs has been measured directly only in Sicily and Azerbaijan, the global methane estimation is still a conservative assumption based on limited data. The behavior of MV activities is seldom reported. This study attempts to estimate annual methane emissions through MVs by using a video recorder to record MV activities along the Chishan Fault and determining the bubble size and flux rate of each MV. Observation results, after a 1 year observation period, indicate that the annual emissions of the 19 MVs along the Chishan Fault are 0.1–0.2% of the global methane flux from MVs, highlighting that the methane emission from these MVs should not be neglected. In addition, the continuous monitoring of a particular MV disclosed periodic characteristics of MV activities. These results manifest the spatial and temporal variations of MV activities along the Chishan Fault. The spatial variations are related to the extensional kinematics of the Chishan fault, while the temporal variation relates to the earth-tide-related MV activities. The estimated annual methane emissions from the study are far more than those of previous studies and are still considered conservative. Results of this study may provide valuable information for researchers attempting to estimate the quantity of GEM.     

Changing roles controlling alternating marine and aeolian deposition and formation of Quaternary sequences in Hergla coastal escarpment (north-eastern Tunisia)

This work is meant to set a new stratigraphic framework of the Quaternary Hergla Sea Cliff deposits in eastern Tunisia including vital precisions concerning depositional environments and climatic conditions. Infrared stimulated luminescence (IRSL) data previously obtained at the Hergla region show that the Khniss unit is Tyrrhenian in age (MIS 5.5), while the Rejiche unit dates to the MIS 5.3/5.1 undifferentiated by the IRSL for the marine deposits and attributed to the MIS 4 for the dunes continental deposits. The sedimentological studies showed that the whole of the marine units of the Upper Pleistocene of Hergla were deposited in a shallow marine environment and also highlighted at least two major transgressive cycles interrupted by drops of the sea level leading to emergence. The first cycle corresponds to the Khniss unit deposit. The second cycle corresponds to the transgression of the Rejiche unit. The end of the MIS 5.5 is marked by a lagoonal sedimentation with a regressive tendency followed by an emergence period materialized by the presence of a paleosol. During the MIS 5.3/5.1, the marine deposits of the Rejiche unit correspond to infratidal carbonate sediments subjected to storms currents. They are characterized by the reworking of lithoclasts, due to the action of the storm currents. Eventually, the study of cements in the continental deposits of the Rejiche unit indicates a late evolution in a continental vadose environment, subjected to the action of meteoric waters. In terms of climatic conditions, the MIS 5.5 was hotter and wetter than the subsequent MIS 5.3/5.1.     

Determination of the thicknesses of oil films in micro- and nano-pores in tight oil sands: an example from the southern Songliao Basin,NE China

An experimental method of field-emission environmental scanning electron microscope (ESEM) coupled with the energy dispersive spectrum (EDS) to determine the thickness of oil films in the micro- and nano-pores of tight oil sands was proposed to overcome the limitations of current methods. First, we got the data of the detection range volumes, elemental mass percentages, and elemental atomic percentages using the EDS, and then calculated the volumes of oil films in the detection range according to the elemental mass percentages and the elemental atomic percentages of carbon. After that, we calculated the surface areas of oil films using the pore size data (lengths, widths, and depths) detected by ESEM. The thicknesses of oil films in the pores equaled the volumes divided by the surface areas. An analysis of tight oil samples from the Quan 4 Segment of in the southern Songliao Basin, NE China confirmed that the oil in the micro- and nano-pores had two main forms: oil films and oil droplets. The thicknesses of the oil films ranged from about 400 nm to 2 μm, while the thicknesses of the oil droplets ranged from about 200 to 700 nm.     

Characterization of the mechanical properties of a claystone by nano-indentation and homogenization

Based on the analyses of mineralogical compositions by X-ray diffraction and microstructure by optical microscopy, the Young’ modulus and hardness of a claystone were characterized by the nano-indentation technique and homogenization method. Three distinct microstructural zones are identified in the claystone: clay matrix, a composite matrix of clay and small mineral grains and imbedded quartz grains. The elastic modulus and hardness of different zones were determined by nano-indentation testing. Based on the statistical analysis of nano-indentation results, the spatial mappings and frequency distributions of elastic modulus and hardness of the different zones were obtained. The elastic moduli of main constituent phases of the claystone are then estimated from the nano-indentation tests. These values were further used for the determination of the macroscopic elastic modulus of the claystone using two different homogenization schemes: the dilute scheme and Mori–Tanaka scheme. The predicted values by the homogenization schemes are compared with experimental data obtained from conventional uniaxial compression tests.     

Periodical mixing of MORB magmas near East Pacific Rise 13°N: Evidence from modeling and zoned plagioclase phenocrysts

Thirty-six basalt samples from near East Pacific Rise 13°N are analyzed for major and trace elements. Different types of zoned plagioclase phenocrysts in basalts are also backscatter imaged, and major element profiles scanned and analyzed for microprobe. Basalts dredged from a restricted area have evolved to different extents (MgO=9.38wt%—6.76wt%). High MgO basalts are modeled for crystalliza-tion to MgO of about 7wt%, and resulted in the Ni contents (≈28 ppm) that are generally lower than that in observed basalts (>60 ppm). It suggests that low MgO basalts may have experienced more intensive magma mixing. High MgO (9.38wt%) basalt is modeled for self-"mixing-crystallization", and the high Ni contents in low MgO basalts can be generated in small scale and periodical self-mixing of new magma (high MgO). "Mixing-crystallization" processes that low MgO magmas experienced accord with recent 226Ra/230Th disequilibria studies for magma residence time, in which low MgO magmas have experi-enced more circles of "mixing-crystallization" in relatively longer residence time. Magma mixing is not homogeneous in magma chamber, however, low MgO magmas are closer to stable composition pro-duced by periodical "mixing-crystallization", which is also an important reason for magma diversity in East Pacific Rise. Zoned plagioclase phenocrysts can be divided into two types: with and without high An# cores, both of which have multiple reversed An# zones, suggesting periodical mixing of their host magmas. Cores of zoned plagioclase in low MgO (7.45wt%) basalt differ significantly with their mantle in An#, but are similar in An# with microlite cores (products of equilibrium crystallization) in high MgO (9.38wt%) basalt, which further shows that plagioclase phenocryst cores in low MgO basalts may have formed in their parental magmas before entering into the magma chamber.     

Sedimentary Deposits from the 17 July 2006 Western Java Tsunami,Indonesia: Use of Grain Size Analyses to Assess Tsunami Flow Depth,Speed, and Traction Carpet Characteristics

The 2006 western Java tsunami deposited a discontinuous sheet of sand up to 20 cm thick, flooded coastal southern Java to a depth of at least 8 m and inundated up to 1 km inland. In most places the primarily heavy mineral sand sheet is normally graded, and in some it contains complex internal stratigraphy. Structures within the sand sheet probably record the passage of up to two individual waves, a point noted in eyewitness accounts. We studied the 2006 tsunami deposits in detail along a flow parallel transect about 750 m long, 15 km east of Cilacap. The tsunami deposit first becomes discernable from the underlying sediment 70 m from the shoreline. From 75 to 300 m inland the deposit has been laid down in rice paddies, and maintains a thickness of 10–20 cm. Landward of 300 m the deposit thins dramatically, reaching 1 mm by 450 m inland. From 450 m to the edge of deposition (around 700 m inland) the deposit remains <1 mm thick. Deposition generally attended inundation—along the transect, the tsunami deposited sand to within about 40 m of the inundation limit. The thicker part of the deposit contains primarily sand indistinguishable from that found on the beach 3 weeks after the event, but after about 450 m (and roughly coinciding with the decrease in thickness) the tsunami sediment shifts to become more like the underlying paddy soil than the beach sand. Grain sizes within the deposit tend to fine upward and landward, although overall upward fining takes place in two discrete pulses, with an initial section of inverse grading followed by a section of normal grading. The two inversely graded sections are also density graded, with denser grains at the base, and less dense grains at the top. The two normally graded sections show no trends in density. The inversely graded sections show high density sediment to the base and become less dense upward and represents traction carpet flows at the base of the tsunami. These are suggestive of high shear rates in the flow. Because of the grain sorting in the traction carpet, the landward-fining trends usually seen in tsunami deposits are masked, although lateral changes of mean sediment grain size along the transect do show overall landward fining, with more variation as the deposit tapers off. The deposit is also thicker in the more seaward portions than would be produced by tsunamis lacking traction carpets.     

A general weighted total Kalman filter algorithm with numerical evaluation

An applicable algorithm for Total Kalman Filter (TKF) approach is proposed. Meanwhile, we extend it to the case in which we can consider arbitrary weight matrixes for the observation vector, the random design matrix and possible correlation between them. Also the updated dispersion matrix of the predicted unknown is given. This approach makes use of condition equations and straightforward variance propagation rules. It is applicable to data fusion within a dynamic errors-in-variables (DEIV) model, which usually appears in the determination of the position and attitude of mobile sensors. Then, we apply for the first time the TKF algorithm and its extended version named WTKF to a DEIV model and compare the results. The results show the efficiency of the proposed WTKF algorithm. In particular in the case of large weights, WTKF shows approximately 25% improvement in contrast to TKF approach.     

Seismic evaluation of an existing complex RC building

The seismic evaluation of existing buildings is a more difficult task than the seismic design of new buildings. Non-linear methods are needed if realistic results are to be obtained. However, the application to real complex structures of various evaluation procedures, which have usually been tested on highly idealized structural models, is by no means straightforward. In the paper, a practice-oriented procedure for the seismic evaluation of building structures, based on the N2 method, is presented, together with the application of this method to an existing multi-storey reinforced concrete building. This building, which is asymmetric in plan and irregular in elevation, consists of structural walls and frames. It was designed in 1962 for gravity loads and a minimum horizontal loading (2% of the total weight). The main results presented in terms of the global and local seismic demands are compared with the results of non-linear dynamic response-history analyses. As expected, the structure would fail if subjected to the design seismic action according to Eurocode 8. The shear capacity of the structural walls is the most critical. If the shear capacity of these elements was adequate, the structure would be able to survive the design ground motion according to Eurocode 8, in spite of the very low level of design horizontal forces. The applied approach proved to be a feasible tool for the seismic evaluation of complex structures. However, due to the large randomness and uncertainty which are involved in the determination of both the seismic demand and the seismic capacity, only rough estimates of the seismic behaviour of such structures can be obtained.