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71.
碳酸铷、硼酸化学计量比混合,蒸发溶液,直至五硼酸铷RbB5O8·4H2O晶体析出。经粉末X射线衍射(XRD)、拉曼光谱(Raman spectroscopy)、热重/微商热重/差示扫描量热(TG/DTG/DSC)、原子吸收光谱等实验方法,确定其化学组成及结构。298.15、333.15K时测量溶液的物理化学性质(密度、电导、pH),并与经验方程进行拟合,研究五硼酸铷溶液的物化性质随浓度、温度的变化规律。根据文献报道的平衡常数,实验测量的pH数据,采用牛顿迭代法进一步研究五硼酸铷溶液中主要存在的硼酸根离子对类型、含量以及物种的形成。 相似文献
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73.
Yajie Zhang Yao Li Jing Ge Gaopeng Li Zhisheng Yu Haishan Niu 《Environmental Earth Sciences》2018,77(12):462
Drought monitoring is a key topic in environmental monitoring and assessment although there is still a need to determine the correlation between drought monitoring indices and remote sensing products. We analyzed the correlation between the self-calibrating Palmer Drought Severity Index (sc_PDSI), the Standardized Precipitation Index and the Standardized Precipitation Evapotranspiration Index (SPEI) and terrestrial water storage monitored through the Gravity Recovery and Climate Experiment (GRACE) on a monthly timescale from 2002 to 2015 in China. As a consequence of anomalies in the soil water budget, the highly significant correlation between the sc_PDSI and the GRACE satellite-observed terrestrial water storage suggested that these two datasets are the most suitable for use in monitoring droughts. In comparing the three drought indices, the sc_PDSI was introduced as a means of drought monitoring in the Yangtze, Pearl, Huaihe, Southeast and Songhua River Basins, whereas the SPEI was found to be more applicable to other major river basins, such as the Inland River Basin. These diverse spatial behaviors are caused by the differences between the hydrological droughts characterized by these three drought indices. 相似文献
74.
Juanle Wang Eryang Chen Ge Li Lu Zhang Xiaoming Cao Yongjie Zhang Yujie Wang 《Environmental Earth Sciences》2018,77(16):590
Concentrations of suspended solids in lakes can affect the latter’s primary productivity and reflect changes in sediment deposition. Determining the temporal and spatial distribution of suspended solid concentrations has important significance in lake water environmental management; this is particularly urgent for Poyang Lake, the largest freshwater lake in China. In this study, suspended solid concentration inversion models for Poyang Lake were created using a semi-empirical method with regression analysis between continuously measured suspended solid concentration data and multi-band moderate-resolution imaging spectroradiometer images for spring, summer, autumn, and winter from 2009 to 2012. The coefficient of determination (R2) is from 0.6 to 0.9 and the average relative error for the accuracy verification was between 10 and 30%. The seasonal distributions of suspended solid concentrations in Poyang Lake from 2000 to 2013 were then obtained using optimal reversal models. The results showed that the seasonal variation in suspended solid concentrations had a “W” shape in which high spring and autumn and low summer and winter values. The suspended solid concentrations increased annually from 2000 to 2013 and were mainly distributed in the northern and central portions of the lake, with lower values along the shorelines. Further analysis indicated that the large difference in water level between the wet and dry seasons is an important factor in explaining these seasonal variations. Moreover, the suspended solid concentrations were poorly correlated with water temperature and chlorophyll-a concentration but more highly correlated with the deferred chlorophyll-a concentration. 相似文献
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76.
Acta Geotechnica - Complex geological conditions and/or inappropriate shield tunnel boring machine (TBM) operation can significantly degrade both the excavation and safety of tunnel construction.... 相似文献
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78.
Geochemistry of pore waters from the Xisha Trough, northern South China Sea and their implications for gas hydrates 总被引:2,自引:0,他引:2
Shao-Yong Jiang Tao Yang Lu Ge Jing-Hong Yang Hong-Fei Ling Neng-You Wu Jian Liu Dao-Hua Chen 《Journal of Oceanography》2008,64(3):459-470
This paper reports all available geochemical data on sediments and pore waters from the Xisha Trough on the northern continental
margin of the South China Sea. The methane concentrations in marine sediments display a downhole increasing trend and their
carbon isotopic compositions (δ
13C = −25 to −51‰) indicate a thermogenic origin. Pore water Cl− concentrations show a range from 537 to 730 mM, and the high Cl− samples also have higher concentrations of Br−, Na+, K+, and Mg2+, implying mixing between normal seawater and brine in the basin. The SO4
2− concentrations of pore waters vary from 19.9 to 36.8 mM, and show a downhole decreasing trend. Calculated SMI (sulfate-methane
interfaces) depths and sulfate gradients are between 21 and 47 mbsf, and between −0.7 and −1.7 mM/m, respectively, which are
similar to values in gas hydrate locations worldwide and suggest a high methane flux in the basin. Overall, the geochemical
data, together with geological and geophysical evidence, such as the high sedimentation rates, high organic carbon contents,
thick sediment piles, salt and mud diapirs, active faulting, abundant thermogenic gases, and occurrence of huge bottom simulating
reflector (BSR), are suggestive of a favorable condition for occurrence of gas hydrates in this region. 相似文献
79.
提出一种基于卷积神经网络和图割法的自动提取高分影像建筑物的方法。首先,通过卷积神经网络定位与检测建筑物的位置,逐一提取单个建筑物轮廓,利用检测结果分别建立建筑物和非建筑物的高斯混合模型(GMM),然后结合最大流最小割的图像分割方式实现全局优化,完成建筑物初步提取,最后用形态学进行优化。通过试验证明了该方法的可行性。 相似文献
80.
江汉叠合盆地及邻区中生代以来盆山耦合数值模拟研究 总被引:9,自引:9,他引:0
江汉叠合盆地位于扬子地台中部,夹持于秦岭-大别及江南造山带中段之间。中生代以来,先后经历了北部陆陆碰撞、南部陆内挤压造山与断陷、裂陷成盆的演化历程,区域构造体制在中生代发生了重大转换,其中复合、联合了众多的地质现象;盆地历经的海盆、煤盆、盐盆、陆相广盆四个盆地世代详细记录有中国南北大陆联合及东北亚大陆构造体制转换的运动学过程,是认识欧亚大陆东部深层动力地质作用过程的关键地区之一。盆地沉积充填过程可简要概括为前陆、裂陷、坳陷三种基本样式。系统的盆山构造样式及运动学分析结果表明:叠合盆地前陆期发育于同碰撞-造山后作用阶段早期,断、坳陷期发育于造山后作用阶段晚期-非造山裂解阶段。本文运用大陆动力学数值模拟(FLAC软件)方法,从挤压和伸展两方面效验了山-盆演化分别受控于印支-早燕山期的华南与华北陆块的旋转碰撞造山,以及随后的晚燕山-喜山早期碰后陆内俯冲作用所产生的板片断离引起的地幔物质上升与对流作用,晚喜山期太平洋板块俯冲作用以及由此产生的地幔调整等三期动力学系统。为南方中小型叠合盆地动力学解析提供了一种新的思路与研究方法。 相似文献