内蒙古别鲁乌图铜多金属矿床锆石U-Pb年龄和S、Pb同位素特征及其地质意义

为了明确内蒙古别鲁乌图铜多金属矿床的成矿年龄与矿床成因,对该矿床中与成矿关系密切的流纹岩进行了锆石U-Pb年龄以及主要金属硫化物的S、Pb同位素测试。其中流纹岩的锆石²⁰⁶Pb/²³⁸U加权平均年龄为(271.7±1.6) Ma(MSWD=1.02),显示成矿作用发生于二叠纪。金属硫化物的S同位素分析结果显示δ³⁴S_V-CDT值分布在-0.6‰～1.0‰之间,平均为0.49‰,变化范围较窄,显示S的来源单一;Pb同位素组成比较集中,²⁰⁶Pb/²⁰⁴Pb为18.207～18.674,²⁰⁷Pb/²⁰⁴Pb为15.620～15.699,²⁰⁸Pb/²⁰⁴Pb为38.144～38.790,具有壳幔混源的特征。S、Pb同位素特征均指示成矿物质主要来源于岩浆热液。结合区域地质、矿床地质、空间分带等特征以及S、Pb同位素组成可知,别鲁乌图铜多金属矿床为VHMS型矿床,形成于二叠纪...     

Asymptotic regimes in unstable miscible displacements in random porous media

We study two asymptotic regimes of unstable miscible displacements in porous media, in the two limits, where a permeability-modified aspect ratio, R_L=L/H(k_v/k_h)^1/2, becomes large or small, respectively. The first limit is known as transverse (or vertical) equilibrium, the second leads to the problem of non-communicating layers (the Dykstra–Parsons problem). In either case, the problem reduces to the solution of a single integro-differential equation. Although at opposite limits of the parameter R_L, the two regimes coincide in the case of equal viscosities, M=1. By comparison with high-resolution simulation we investigate the validity of these two approximations. The evolution of transverse averages, particularly under viscous fingering conditions, depends on R_L. We investigate the development of a model to describe viscous fingering in weakly heterogeneous porous media under transverse equilibrium conditions, and compare with the various existing empirical models (such as the Koval, Todd–Longstaff and Fayers models).     

从岩相古地理论中国南方石炭系油气潜景

石炭系是中国南方重要的海相含油气地层之一。下石炭统的油气生成条件比上石炭统的好,这和早石炭世的盆地面积较大有关。石炭系下伏的志留系和上覆的二叠系的油气生成条件比石炭系还要好。上石炭统的油气储集条件比下石炭统的好,这和上石炭统的白云岩和滩相石灰岩分布较广有关。石炭系油气藏的直接盖层是下二叠统下部的梁山组,区域盖层是中新生代的泥岩为主的地层。南方石炭系油气生储盖条件的配置关系相当好。但是,南方石炭系以及整个古生代和三叠纪海相地层均经历了多次大的构造变动,其油气藏形成条件遭受相当大的破坏。在有利的生储配置关系的基础上,在区域盖层和保存条件较好的及面积较大的中新生代沉积盆地中,尤其是在邻近石炭系本身或其下伏志留系油气源岩的地区,是寻找和发现石炭系新的油气藏的有利地区。     

黄陵矿区地质灾害的现状与评价预测

在论述黄陵矿区地质环境的基础上,分析了矿区地质灾害的类型、现状与特点,采用模糊判别等数学方法对矿区的地质灾害进行了评价与预测,并据此确定了黄陵矿区有4个地质灾害区段,即黄陵城区灾害段、黄陵店头镇灾害段、苍村井田灾害段和车村井田灾害段。      

2008年5月12日汶川MW 7.9地震的震源位置与发震时刻

综合运用四川省地震台网与紫坪铺水库地震台网的观测资料,精确地测定了2008年5月12日汶川MW7.9地震的震源位置与发震时刻．指出,对汶川地震这样的大地震精准定位,必须克服或尽量减少远台观测对地震精确定位的局限性、地壳介质模型的不完善性以及识别与检测初至波震相的不一致性等因素的影响．通过分析对比、反复试验,从上述台网中精心选取了方位分布均匀、具有近震源台站约束、直达P波震相确系由初始破裂辐射出的15个地震台的直达P波到时数据,反演得出精确度比区域性地震台网常规测定的精确度高一个数量级的汶川大地震的定位结果,即:发震时刻（北京时间）:2008年5月12日14:27:57.59plusmn;0.03 s;震中位置:31.018deg;Nplusmn;0.3 km,103.365deg;Eplusmn;0.3 km;震源深度:15.5 kmplusmn;0.3 km．      

日照市土壤重金属来源解析及环境风险评价

选择日照市的东港区和岚山区为研究区,采集了445个0～20 cm表层土壤样品,并测定了10种重金属元素的含量;采用多元统计和地统计分析,揭示了研究区土壤重金属污染的主要来源以及与土地利用、成土母质之间的关系,绘制了重金属的环境风险概率的空间分布图.结果表明:①As、Co、Cr和Cu的平均值低于山东省东部地区土壤背景值,Cd、Hg、Mn、Ni、Pb和Zn的平均值高于背景值,尤其是Cd、Hg的含量分别为背景值的1.85和1.38倍,土壤中重金属累积较为明显.②10种元素可被辩识出4个主成分(PCs),PC1 (Co、Cr、Mn、Ni和Zn)和PC3 (As、Cu)为自然源因子,PC2 (Cd、Pb)为工农业及交通源因子,PC4(Hg)为工业源因子;其中Pb、Zn在PC1和PC3上均有较大载荷,受地质背景和人类活动的共同控制.③Cd、Hg含量在不同的覆被类型有显著差异,在城镇建设用地的含量最高;Co、Cr、Cu、Mn和Ni在花岗岩和变质岩母质的含量高,与冲积与海积物母质有较大差异.④来自于同一主成分的元素及元素组合的环境风险空间格局与相应主成分插值结果基本一致,所有重金属综合环境风险的高值区在西部和东部呈点状分布,主要是由西部的高地质背景和东部的强烈人为干扰的综合作用造成的.     

Numerical simulation of three-dimensional tidal current in the Bobal Sea

Ｎｕｍｅｒｉｃａｌｓｉｍｕｌａｔｉｏｎｏｆｔｈｒｅｅ－ｄｉｍｅｎｓｉｏｎａｌｔｉｄａｌｃｕｒｒｅｎｔｉｎｔｈｅＢｏｂａｌＳｅａ￥ＤｅｎＺｈｅｎｘｉｎｇ;ＹａｎｇＬｉａｎｗｕ;ａｎｄＪｏｓｅＯｚｅｒ（ＲｅｃｅｉｖｅｄＭａｙ１,１９９３;ａｃｃｅｐｔｅｄ...     

北塘口近岸海域水环境质量时空变化分析及预测

通过分析2005年-2010年北塘口及其邻近海域水环境现场调查资料,同时结合历史数据进行对比,结果表明:(1)北塘口河口水体中COD和BOD5超标严重,整体污染态势以2008年为界呈现先降低后升高的趋势;邻近海域水体中无机氮为最主要污染物,其中硝酸盐是无机氮中最主要组成部分,但丰水期时亚硝酸盐氮和枯水期时铵盐氮所占比例逐年升高,说明区域水体氧化还原环境的潜在变化;N/P比值远高于正常的Redfield 16比值表明,区域水体已处于潜在严重P限制状态,同时,区域严重富营养化状态也极易诱导区域赤潮爆发;(2)丰水期陆源无机氮大量输入,使区域水体大部分时间超该区域功能区划要求的Ⅳ类海水水质标准,但底质沉积物环境相对比较稳定,各监测项目全部符合一类海洋沉积物质量标准要求;(3)丰水期和枯水期时,活性磷酸盐含量1983年-1998年分别增加了16.6倍和17.2倍,1998年-2010年由于监控措施的加强,极大地降低了P排放,丰水期和枯水期时活性磷酸盐含量最大增幅分别降到了5.84倍和2.33倍,无机氮含量增幅也呈现明显减小趋势,1983年-1998年丰水期和枯水期分别增加了8.37倍和13.7倍,而1998年-2010年丰水期和枯水期最大增幅也仅为3.52倍和3.28倍;整体看来水质和底质环境有缓和趋势,但潜在威胁仍然严重.     

Monitoring severe aquifer-system compaction and land subsidence in Taiwan using multiple sensors: Yunlin,the southern Choushui River Alluvial Fan

During 1992–2007, excessive pumping of groundwater caused large-scale aquifer-system compaction and land subsidence in the Choshui River Alluvial Fan, especially in the area of Yunlin county. The subsidence impedes surface-water runoff and endangers the operation of Taiwan High Speed Rail. Leveling, Global Positioning System (GPS), multi-level compaction monitoring well, and Differential Interferometric Synthetic Aperture Radar (DInSAR) are used to study the extent of subsidence in Yunlin and its mechanism. These sensors complement each other in spatial and temporal resolutions. A leveling network totaling 434 km in length was deployed to derive subsidence at every 1.5 km along the routes, and the result is accurate to few mm and shows a basin-like subsidence pattern centering at Tuku Township. Four multi-level compaction monitoring wells, co-located with GPS pillars, detect compactions at different depths, showing that the aquifer-system compaction (the cause of subsidence) occurs mostly below depths >200 m, where reduction of groundwater pumping is most needed. The vertical displacements from GPS and leveling agree to within 1 cm, and are larger than the cumulative compaction detected by the compaction-monitoring wells, suggesting that compaction also occurs below 300 m (the depth of the wells). The vertical displacements derived using DInSAR and 8 ENVISAT SAR images agree with the leveling result to 1–2 cm.     

Effects of natural and calcined oyster shells on Cd and Pb immobilization in contaminated soils

In Korea, soils adjacent to abandoned mines are commonly contaminated by heavy metals present in mine tailings. Further, the disposal of oyster shell waste by oyster farm industries has been associated with serious environmental problems. In this study, we attempted to remediate cadmium (Cd)- and lead (Pb)-contaminated soils typical of those commonly found adjacent to abandoned mines using oyster shell waste as a soil stabilizer. Natural oyster shell powder (NOSP) and calcined oyster shell powder (COSP) were applied as soil amendments to immobilize Cd and Pb. The primary components of NOSP and COSP are calcium carbonate (CaCO₃) and calcium oxide (CaO), respectively. X-ray diffraction, X-ray fluorescence and scanning electron microscope analyses conducted in this study revealed that the calcination of NOSP at 770°C converted the less reactive CaCO₃ to the more reactive CaO. The calcination process also decreased the sodium content in COSP, indicating that it was advantageous to use COSP as a liming material in agricultural soil. After 30 days of incubation, we found that the 0.1 N HCl-extractable Cd and Pb contents in soil decreased significantly as a result of an increase in the soil pH and the formation of metal hydroxides. COSP was more effective in immobilizing Cd and Pb in the contaminated soil than NOSP. Overall, the results of this study suggest that oyster shell waste can be recycled into an effective soil ameliorant.