长江经济带岩盐矿特征与盐穴储库适宜性评价

长江经济带包括上海、江苏、浙江、安徽、江西、湖北、湖南、四川、重庆、云南和贵州11个省(直辖市),是我国重要的经济发展区域,油气资源长期安全可靠的储存对于该区经济可持续发展至关重要。基于长江经济带战略油气储库基地建设规划布局的需求,在充分收集利用前人地质调查和研究成果的基础上,对区内岩盐矿床进行了综合研究和分析,建立了层次结构模型,评价了盐穴油气储库建设的可行性。长江经济带除上海和贵州外,其余9省(直辖市)均发现了大量的岩盐矿床,主要成盐时代为震旦纪、三叠纪、白垩纪和古近纪; 成盐盆地范围0.29~10 000 km²,盐层累计厚度3~1 050 m,矿体埋藏深度40~3 400 m; 矿石中NaCl含量20%~99.86%; 矿体顶底板及夹层岩石主要为泥岩、粉砂质泥岩及泥质粉砂岩。地质调查揭示出区内大部分地下盐穴远离地震活动带,构造稳定,因此可以改造为石油储库。考虑储气库的密闭性及安全性,江苏金坛盆地等6个盐矿埋深适中,建穴地质条件较好,适合建造储气盐穴库; 江苏淮安等14个盆地的局部地区适合建造天然气储库; 重庆垫江等11个盐矿埋深较大,可以建造储气盐穴库,但建造成本较高; 湖南澧县等21个盐矿埋藏偏浅,应选择更深部的盐层空间建造油气储库。建议在江苏金坛、淮安、赵集和丰县,江西清江和会昌,湖北云应、天门小板和潜江等盐矿地区优先开发利用盐穴。     

塔里木盆地满西地区海相油气成藏规律

满西地区是塔里木盆地海相油气藏的主要富集区之一,侧向运移是该区油气成藏的一个重要特征。该区油气藏的形成和分布主要受控干古隆起背景、东河砂岩优质输导层的展布以及中一新生代(尤其是晚喜马拉雅期)构造变动等三大因素。古隆起背景的存在是该区油气藏形成和富集的关键。研究表明,哈得逊古隆起及其斜坡上倾部位是满西地区油气聚集成藏的最有利地区,石炭系东河砂岩是油气富集的主要层位,东河砂岩地层圈闭和地层一构造复合型圈闭是油气藏形成的主要类型。认为满西地区大中型油气田的勘探应以哈得逊古隆起及其西斜坡为重点。     

长江经济带土壤质量评价及产地适宜性初步研究

开展土壤质量评价对科学划定永久基本农田及统筹优化农业生产布局具有重要指导意义。本文采用内梅罗综合污染指数法、分级法、累积频率法和综合判定法,参照《土壤环境质量农用地土壤污染风险管控标准》(试行)(GB 15618—2018)和《绿色食品产地环境质量》(NY/T 391—2013),对长江经济带土壤重金属污染、酸碱度、有益元素丰缺和绿色农产品产地适宜性进行评价。研究区土壤质量总体良好,清洁土壤面积34.84万km²,其重金属含量继承了自然背景特征; 三级及以下土壤面积6.94万km²,呈斑块及星点状分布于赣东北、赣南、湖南长沙—郴州一带、沿江及贵阳、昆明等地,其重金属为自然富集或受矿业开发、煤炭和石油的燃烧及工业“三废”排放的影响。酸性土壤面积33.56万km²,分布于江西、湖南、宁波—台州沿海和金华衢州盆地,碱性土壤面积15.69万km²,分布于苏北平原、环洞庭湖、成都平原以及沿长江一线,其土壤酸碱度与土壤类型有关。土壤有益元素丰缺与第四系沉积物成土母质有关,土壤有益元素适量及以上区域面积34.44万km²,分布于四川阿坝、成都盆地、环洞庭湖、环鄱阳湖、安徽沿江、苏北沿海和杭嘉湖平原; 土壤有益元素缺乏区面积13.89万km²,分布于赣南、江淮、鄂东北以及云南玉溪等地。绿色农产品产地最适宜区、适宜区和不适宜区面积分别为22.49万km²、18.78万km²和18.28万km²。依据区内绿色农产品产地适宜性、土壤环境质量和立地条件划分出7片永久农田保护建议区。     

库姆塔格沙漠的“羽毛状沙丘”形态的观测

参照卫星照片和地形图,实地观测了库姆塔格沙漠“羽毛状沙丘”分布区域的地貌。新月型“沙垄”是该区域的主导性地貌类型,垄间地形波状起伏。如果将“沙垄”喻为“羽轴”,垄间的波状起伏地形为“羽枝”,则可构成卫星照片所显示的“羽毛状沙丘”。新月型“沙垄”的走向为NE-SW,由新月形沙丘前一沙丘的迎风坡与后一沙丘的东翼相连而成,高3~19m,宽约50m,长15~22km。“垄”间起伏地形的波长为100~300m,振幅为40~100cm,与“沙垄”成60~105°夹角。在波状起伏地形的波峰与波谷过渡区堆积颜色较浅的细沙,厚2~7cm,构成了“大沙波”。实地观测的“羽毛状沙丘”的形态与卫星照片显示的形态有一定差异。     

应用逐步判别法预测岩溶塌陷探讨——以桂林岩溶区为例

本文着重论述在岩溶塌陷评价和预测中采用多元统计——逐步判别分析法,并以桂林岩溶区的实际资料为例进行电算,说明该方法的具体效果,以便在类似的岩溶区,类似的塌陷形成条件下建立判别函数式,从而预测或区划未知塌陷区与相对稳定区。     

高表面活性矿物对Zn~(2+)的吸附机理及其环境意义

本文利用高表面活性矿物蒙脱石、蛭石、沸石在一定的介质条件下对Zn2 +进行吸附实验研究。蒙脱石和蛭石对Zn2 +的等温吸附线呈双“S”型 ,而沸石对Zn2 +的等温吸附线则呈“Langmuir”型。三种矿物对Zn2 +的吸附容量大小顺序为 :蒙脱石 >蛭石 >沸石。运用粉晶X射线衍射、红外光谱、差热及热重分析等技术对矿物及矿物吸附Zn2 +后的结构特征进行了研究。结果表明 ,蒙脱石吸附锌后其层间域中吸附锌大量水解形成新的物相 ,而蛭石与沸石吸附锌后水解很少。这为利用高表面活性矿物控制和治理环境污染及其可循环利用提供了理论依据。     

Petrochronology of oxidized granulites from southern Peru

Sapphirine–quartz granulites from the Cocachacra region of the Arequipa Massif in southern Peru record early Neoproterozoic ultrahigh‐temperature metamorphism. Phase equilibrium modelling and zircon petrochronology are used to quantify timing and pressure–temperature (P–T) conditions of metamorphism. Modelling of three magnetite‐bearing sapphirine–quartz samples indicates peak temperatures of >950°C at ~0.7 GPa and a clockwise P–T evolution. Elevated concentrations of Al in orthopyroxene are also consistent with ultrahigh‐temperature conditions. Neoblastic zircon records ages of c. 1.0–0.9 Ga that are interpreted to record protracted ultrahigh‐temperature metamorphism. Th/U ratios of zircon of up to 100 reflect U‐depleted whole‐rock compositions. Concentrations of heavy rare earth elements in zircon do not show systematic trends with U–Pb age but do correlate with variable whole‐rock compositions. Very large positive Ce anomalies in zircon from two samples probably relate to strongly oxidizing conditions during neoblastic zircon crystallization. Low concentrations of Ti‐in‐zircon (<10 ppm) are interpreted to result from reduced titania activities due to the strongly oxidized nature of the granulites and the sequestration of titanium‐rich minerals away from the reaction volume. Whole‐rock compositions and oxidation state have a strong influence on the trace element composition of metamorphic zircon, which has implications for interpreting the geological significance of ages retrieved from zircon in oxidized metamorphic rocks.     

Elastic solutions for a transversely isotropic half-space subjected to buried asymmetric-loads

Elastic closed-form solutions for the displacements and stresses in a transversely isotropic half-space subjected to various buried loading types are presented. The loading types include finite line loads and asymmetric loads (such as uniform and linearly varying rectangular loads, or trapezoidal loads). The planes of transverse isotropy are assumed to be parallel to its horizontal surface. These solutions are directly obtained from integrating the point load solutions in a transversely isotropic half-space, which were derived using the principle of superposition, Fourier and Hankel transformation techniques. The solutions for the displacements and stresses in transversely isotropic half-spaces subjected to linearly variable loads on a rectangular region are never mentioned in literature. These exact solutions indicate that the displacements and stresses are influenced by several factors, such as the buried depth, the loading types, and the degree and type of rock anisotropy. Two illustrative examples, a vertical uniform and a vertical linearly varying rectangular load acting on the surface of transversely isotropic rock masses, are presented to show the effect of various parameters on the vertical surface displacement and vertical stress. The results indicate that the displacement and stress distributions accounted for rock anisotropy are quite different for those calculated from isotropic solutions. Copyright © 1999 John Wiley & Sons, Ltd.