赣南晚侏罗世九龙脑钨锡铅锌矿集区不同成矿类型花岗岩年龄、地球化学特征对比及其地质意义

九龙脑花岗岩体位于南岭东部,它周围分布着众多钨、锡和铅锌矿床(点).本文选择岩体北侧淘锡坑石英脉型钨矿、东侧宝山矽卡岩型铅锌矿底部的隐伏花岗岩,对比九龙脑岩体开展了成岩年代学、地球化学、Sr- Nd同位素研究.上述岩体的SHRIMP锆石U-Pb年龄分别是158.7±3.9Ma、157.7±2.7Ma、154.9±2.2...     

西藏多龙矿集区地堡Cu(Au)矿床含矿斑岩锆石U-Pb测年、Hf同位素组成及其地质意义

西藏多龙矿集区地堡铜(金)矿位于班公湖—怒江缝合带北侧,羌塘地块南缘,是多龙矿集区中具有较好找矿前景的斑岩—浅成低温热液矿床。本文首次对地堡含矿斑岩进行LA-ICP-MS锆石U-Pb测年、微量元素和Hf同位素分析。含矿斑岩23个锆石点测试,获得锆石~(206)Pb/~(238)U加权平均值年龄为122.0±2.5Ma(MSWD=0.34),与多龙矿集区成矿岩浆活动时限一致,是多龙矿集区的重要组成部分。锆石微量元素特征揭示地堡含矿斑岩中锆石为岩浆锆石,锆石Ti温度计计算出其结晶温度为663~850℃,平均为765℃,其岩浆源区可能经历了水饱和条件下的部分熔融作用。Hf同位素分析结果表明,地堡含矿斑岩锆石n(~(176)Hf)/n(~(177)Hf)值相对较高,为0.282726~0.283054,ε_(Hf)(t)为1.1~12.6,均为正值,其物质来源有幔源组分的加入,可能为壳幔混源的新生下地壳。     

Sources and transports of polycyclic aromatic hydrocarbons in the Nanshan Underground River,China

Karst areas have much higher ecological vulnerability and are easy to be contaminated by polycyclic aromatic hydrocarbons (PAHs), which are introduced as health risk pollutants. PAHs ratios were used to understand the sources and transport behavior of PAHs conducted in the karst Nanshan Underground River, China. Water, sediments from the underground river and water, sediments, soil from the surface were collected monthly in 2011 and 2012. Abundant PAHs were found both in the underground river and in the surface system. The detected ΣPAHs concentrations varied from 353 to 13,203 ng L^?1 in the groundwaters and content from 169 to 12,038 ng g^?1 in the sediments of the underground river. The ratios of anthracene to anthracene, plus phenanthrene and fluoranthene to fluoranthene, plus pyrene indicated that PAHs were delivered in the groundwaters from combusted grass, wood, and coal, while in the sediments were a mixture of non-combusted petroleum, grass, wood, coal and combusted grass, wood, coal. The similarities in sources between an underground river and surface system indicated that farmlands play a major role for the transport of PAHs and contamination in the underground river. Karst features are liable for the transport behavior.     

Mineralization episode of porphyry copper deposits in the Jinshajiang-Red River mineralization belt: Re-Os dating

Re-Os isotopic dating for the molybdenites from the porphyry copper deposits of the Jinshajiang-Red River mineralization belt in Yunnan Province yields isochron ages of 33.9±1.1 Ma for the Machangqing deposit and 34.4±0.5 Ma for the Tongchang deposit. This result shows that both the Machangqing and the Tongchang porphyry Cu-Mo deposits from two different ore-fields formed simultaneously. This new data and the published Re-Os model ages of molybdenite (35.4 Ma, 35.9 Ma, 36.2 Ma) of the Yulong porphyry copper deposit in Tibet, which is located in the same Jinshajiang-Red River mineralization belt as the Machangqing deposit and the Tongchang deposit, suggest that these three Cenozoic porphyry copper deposits in the Jinshajiang-Red River mineralization belt were contemporary for their mineralization episode. That is to say, even their present locality is far away and nearly iso-distantly distributed, these three porphyry Cu(Mo) deposits belong to the same mineralization episode at the end of Eocene.     

滇黔交界地区玄武岩铜矿有机质的组成、结构及成因

滇黔交界地区玄武岩型铜矿有两种产出状态 ,一类产于玄武岩中 ,另一类产于玄武岩喷发旋回之间的沉积夹层中。两类铜矿石中均发育有机质。本文通过反射率测定、元素分析、红外光谱和碳同位素组成测定等方法对该区玄武岩铜矿有机质的成熟度、组成、结构及成因进行了研究。结果表明 :1铜矿石有机质的反射率为1.0 4 %～ 2 .172 % ;除个别样品外 ,n H/ n C值平均 0 .4 9,n O/ n C 值平均 0 .0 6 2 ,表明其有机质的成熟度均较高 ,有机质的物理性质及红外光谱特征也显示了这一点。 2有机质的组成以 C为主 ,其次为 H、O、N,两种铜矿石中有机质的 C、H、O元素含量类似 ,仅 N元素含量有一定差异。 3有机质的结构中以羟基、烷烃、芳烃官能团为主 ,有时有 C=O官能团 ;羟基红外吸收峰强度大 ,表明有机质经历了强烈的热液流体交代作用。 4玄武岩中铜矿石沥青的δ1 3CV- PDB为- 2 7.3‰～ - 33.2‰ ,平均 - 31.97‰ ,沉积岩中铜矿石碳质的 δ1 3CV- PDB为 - 2 0 .2‰～ - 2 3.2‰ ,平均 - 2 2 .11‰ ,表明二者无明显成因联系 ,前者属腐泥型 ,为石油的遗迹 ,来自下部地层 ;后者为腐植型 ,来自原地沉积的陆生高等植物。两种铜矿石中不同来源有机质成熟度、组成及结构上的相似性是其经历了相同的成矿作用的反映     

南岭东段赣南地区天门山花岗岩体及花岗斑岩脉的SHRIMP定年及其意义

赣南地区岩浆岩分布广泛,其中燕山期岩浆活动最为强烈,与W、Sn、Nb、Ta成矿的关系尤为密切。选择天门山岩体及附近的花岗斑岩脉为研究对象,应用SHRIMP锆石微区U-Pb测年技术,对天门山岩体的主体、补体和花岗斑岩脉进行了精确测年:天门山岩体的主体——中细粒斑状黑云母花岗岩锆石的9个点SHRIMP谐和年龄为152±2Ma(MSWD=1.09);补体——细粒斑状黑云母花岗岩锆石的5个点SHRIMP谐和年龄为152±2.6Ma(MSWD=0.16);花岗斑岩(墙)脉锆石10个点的SHRIMP谐和年龄为150.8±1.8Ma(MSWD=1.6)。结合区域资料,研究表明:①天门山岩体的主体形成于中侏罗世,补体是主体进一步分异演化的产物;②在赣南西部的崇余犹矿集区内成岩与成矿的年龄基本上是协调一致的,成矿集中期为150~155Ma;③岩浆活动由中深成相花岗岩侵入体演化到浅成相花岗斑岩脉仅相差1~5Ma,表明存在成矿集中期。     

南岭成矿带铀矿地质特征、成矿规律与全位成矿模式

南岭成矿带是中国重要的铀矿基地,产出的铀矿床以花岗岩型为主,其次为碳硅泥岩型和少量砂岩型。本文通过搜集整理前人找矿勘查和科研成果,认为南岭成矿带多期多阶段构造演化为铀成矿作用提供了初始铀源、产铀花岗岩、断裂网络和含铀热液等有利的成矿条件。产铀花岗岩大多是由高硅、过铝、偏钾高碱的S型花岗岩,沿断裂分布的构造碎裂岩、蚀变岩和还原性地质体是有利的赋矿围岩。矿化与蚀变中心带发育沥青铀矿、黑色微晶玉髓、紫黑色萤石、胶状黄铁矿、赤铁矿、绿泥石等矿物组合。铀矿体形态多样,以中小规模、中低工业品位为主。南岭成矿带中新生代多阶段区域性拉张过程中形成了多阶段铀矿化。花岗岩型铀矿床分布于加里东隆起区花岗岩内部构造结和岩体接触带附近,矿体沿断裂与蚀变体一起赋存于氧化-还原界面和脆韧性构造转换面之间的"成矿壳层"内。南岭成矿带中新生代"空间全位"铀成矿模式显示,不同的构造层、不同的建造、不同的岩性及不同的部位均有铀成矿潜力,但由于具体成矿条件的不同组合而产出不同类型、不同规模、不同时间和不同强度的铀矿化。也就是说,难以排除某一空间部位不成矿的可能性。根据这一"全位"成矿的认识,从不同的角度对南岭成矿带中新生代铀...     

矿床成矿系列组——六论矿床的成矿系列问题

矿床的成矿系列(简称成矿系列)是矿床学领域的一个理论性概念,由五级序次组成。矿床成矿系列组属第一序次,是指在一定的地质历史时期、在一定的地壳运动过程中形成的一组相互关联的矿床成矿系列。理想情况下,一个完整的矿床成矿系列组(G),可包括与岩浆作用有关的(I)、与沉积作用有关的(S)、与变质作用有关的(M)、与区域性构造事件-流体作用有关的(F)及与表生作用有关的(H)5类矿床成矿系列。从地球构造演化角度来看,矿床成矿系列组的形成与大陆成矿体系形成的阶段性与旋回性存在内在成因联系,是地壳构造演化的不同阶段的客观记录和必然产物,可与地壳尺度构造运动相对应。深入研究矿床成矿系列组,对于探索地球演化规律,深化理解不同尺度、不同时期成矿构造环境及其成矿过程,揭示地壳运动的基本规律具有重要意义。同时,应用成矿系列组内矿床成矿系列"全位成矿、缺位找矿"的理念和"成矿序列"(有序性)的原则,不仅可以解释矿产资源分布的不均衡性,还可以有效指导区域成矿预测。因涉及面广,矿床成矿系列组的研究尚属起步阶段,有待于进一步深化研究。     

Response spectrum-oriented pulse identification and magnitude scaling of forward directivity pulses in near-fault ground motions

This paper presents a novel approach to identify the pulse-like motions in earthquake recordings that dominate the maximum structural responses over a wide period range. The identification method is based on the congruence relationship between the response spectrum and the dimensionless П-response spectrum established in this study through straightforward dimensional arguments of linear and bilinear SDOF oscillators subject to pulse-like ground motions. By evaluating the geometric match and dislocations of the П-response spectrum of a given waveform with the dimensional response spectrum in bi-logarithm plotting, one can identify the simple pulses and their parameters that match simultaneously the kinematic characteristics and the response spectrum of earthquake recordings that exhibit pulse-like features. The developed pulse identification method has been implemented in a computer program and applied successfully to detect the pulse-like motions in the PEER NGA strong motion database. Both velocity and acceleration pulses potentially due to forward directivity effects in near fault regions are identified. The identified velocity pulses show strong correlation with the seismological parameters. They are subsequently used in regression analysis to derive the empirical scaling laws that relate the directivity pulse parameters to the earthquake magnitude and rupture distance. The study confirms some magnitude scaling laws in literature and demonstrates the accuracy and efficiency of the proposed pulse identification method.