Mineralogical and Geochemical Study of Zhaoping,Xifu and Hami Iron Meteorites

The mineralogy and bulk chemical compositions of three iron meteorites (Zhaoping, Xifu and Hami) recently found in China are reported here and are classified on the basis of their bulk chemical compositions. Zhaoping contains 93.4 mg/g Ni, 85.9 μg/g Ga, 418 μg/g Ge, 5.24 mg/g Co, 1.94 μg/g Ir, 0.774 μg/g W, and 1.62 μg/g Au and belongs to the low-Ni, low-Au subgroup of IAB. It is a coarse octahedrite and consists of kamacite, taenite, troilite, schreibersite and cohenite. The cohenite has entirely decomposed to graphite and low-Ni kamacite in our samples. Zhaoping contains some inclusions of Mn-free sarcopside which were rarely reported in IAB iron meteorites. Xifu has 74.1 mg/g Ni, 58.8gμg/g Ga, 150 μg/g Ge, and 0.913 μg/g W. Xifu is a member of group IIICD iron meteorite. Like most of IIICD irons, Xifu is a coarsest octahedrite with kamacite bandwidth larger than 3mm, and contains kamacite, taenite and schreibersite. Carbides and graphite are not found in the sample because of its being heterogeneous. Hami has 106 mg/g Ni, 5.36 mg/g Co and 0.922 μg/g Ir. We did not obtain the Ga and Ge contents in Hami because of their low concentrations and the limited precision of the INAA technique. Hami is an unclassified iron meteorite on the basis of the contents of other trace elements, structure and mineralogy. On mineralogy and structure, Hami resembles Rafruti, another unclassified iron meteorite.     

跨孔雷达全波形反演成像方法的研究

跨孔雷达全波形反演是一种使用全波形信息反演两钻孔之间地下信息的层析成像技术.常规的层析成像反演大部分采用射线追踪方法,其中基于初至时的射线追踪方法可以反演出速度剖面（介电常数剖面）,基于最大振幅的层析成像可以反演出衰减剖面（电导率剖面）.常规射线追踪方法有许多不足,究其原因是该方法仅使用了小部分的信号信息.为了进一步提高成像分辨率,本文全面推导了全波形跨孔雷达层析成像反演方法,该方法利用雷达波全幅度相位信息能够反演出地下高分辨率的介电常数和电导率图像.本文通过基于局域网的分布式并行算法,有效地解决了巨量数据正演计算问题.文中首先建立了基于单轴各向异性介质完全匹配层的时间域有限差分二维正演算法,进而通过应用包括时间维度在内的全波场信息与残场逆向传播的全波场信息乘积来计算梯度方向,通过求取以步长为自变量的目标函数的极值确定步长公式,并提出以第一次介电常数反演作为同步反演的初始模型,能够有效提高收敛速度.本文对多组模型进行成像实验,取得了较好的反演效果.     

Modelling of hydrodynamics and cohesive sediment transport in Tanshui River estuarine system,Taiwan

A laterally averaged two-dimensional numerical model is used to simulate hydrodynamics and cohesive sediment transport in the Tanshui River estuarine system. The model handles tributaries as well as the main stem of the estuarine system. Observed time series of salinity data and tidally averaged salinity distributions have been compared with model results to calibrate the turbulent diffusion coefficients. The overall model verification is achieved with comparisons of residual currents and salinity distribution. The model reproduces the prototype water surface elevation, currents and salinity distributions. Comparisons of the suspended cohesive sediment concentrations calculated by the numerical model and the field data at various stations show good agreement. The validated model is applied to investigate the tidally averaged salinity distributions, residual circulation and suspended sediment concentration under low flow conditions in the Tanshui River estuarine system. The model results show that the limit of salt intrusion in the mainstem estuary is located at Hsin-Hai bridge in Tahan Stream, 26 km from the River mouth under Q75 flow. The null point is located at the head of salt intrusion, using 1 ppt isohaline as an indicator. The tidally averaged sediment concentration distribution exhibits a local maximum around the null point.     

Design of a high performance variable structure position control ofROVs

An adaptive control scheme for dynamic positioning (DP) of remotely operated underwater vehicles (ROV) is proposed based on a recently developed output feedback variable structure control (VSC) algorithm named VS-MRAC. Only position measurement is required. Precise modeling of the ROV is not needed and unmodeled perturbations can be effectively rejected. A simple method for discretizing the original continuous-time VS-MRAC is proposed based on dead-beat response. Other important practical implementation issues are considered. The performance is evaluated by simulation with a realistic ROV model and by full-scale experimental pool tests with an actual ROV     

Locational Decisions and Residential Preferences of Taiwanese Immigrants in Australia

Since the 1980s, the increase of Asian migrants in large cities has contributed significantly to the cultural landscape of Australia, especially in the city suburbs. Based on the Census and in-depth interviews of 103 Taiwanese migrants, this research examines the location decisions and residential preferences of Taiwanese migrants in Sydney, Brisbane and Melbourne. The reasons for choosing the state, the particular city, and specific area of residence are probed into. The survey shows that migrants moved to Australia mainly for children’s education, lifestyle and political instability reasons. The main reasons for choosing to settle in Sydney were favourable business opportunities, and the northern part of Sydney was preferred. Those who chose Brisbane are attracted by the good climate there, and the residents preferred the Sunnybank area. Melbourne was chosen for the good education it offers, and areas on transportation lines near good schools are selected. Choice of residence was based mainly on their needs and their resources which may change over time. In general, they always choose to locate in close proximity to their family, friends and Taiwanese communities. Their locational choice depends on income and housing budget, proximity to good schools and shopping centers, and information from friends or earlier migrants. Based on such factors, this study clearly demonstrates that the Taiwanese immigrants are fundamentally different from early Chinese settlers who once aimed to settle at Chinatown locations.     

Present state and historical changes of trace metal pollution in Kaoping coastal sediments, southwestern Taiwan

Surface and gravity-cored sediments were collected from the Kaoping coastal area off southwestern Taiwan to determine particle size, organic carbon, trace metal concentration and enrichment factor (EF), 210Pb dating, and 206Pb/207Pb ratio for determining present and historical metal pollution. Surface distributions of trace metals ranged from 0.02 to 0.13 mg/kg for Cd (EF: 0.16-1.65), from 35 to 189 mg/kg for Cr (EF: 0.85-2.92), from 25 to 64 mg/kg for Ni (EF: 0.53-2.38), from 10 to 32 mg/kg for Pb (EF: 1.20-4.94), and from 29 to 129 mg/kg for Zn (EF: 1.18-3.50). Trace metal concentrations correlate closely with distributions of mud (<63 microm) and organic carbon which accumulate largely around river mouths and within the Kaoping Canyon. With the exception of Cd, Cr and Ni in certain areas with rather coarse sediments, metals were generally elevated above the baseline levels over the studied area. Metals were also relatively enriched in areas with high contents of mud and organic carbon. Sedimentation rates derived from the excess 210Pb data in core sediments sampled from the canyon illustrate metal pollution beginning around 1970 that is corresponding to the booming time of economic growth in Taiwan. Meanwhile, the status of Pb pollution in core sediments is verified by an inversed correlation between 206Pb/207Pb ratios and Pb concentrations. Anthropogenic Pb and other metals in the studied area were apparently derived primarily from the Kaoping River and accumulated around the river mouth and within the Kaoping Canyon. The Kaoping Canyon appears to act as a major sink for river borne trace metals.     

New evidence for covalent coupling of peptides to humic acids based on 2D NMR spectroscopy: A means for preservation

Nitrogen immobilization in soils and sediments involving the preservation of peptides is an important yet not well-understood process. Several hypotheses have been proposed for the preservation of peptides in these systems; however, to date, there is no direct molecular-level evidence for any one of several hypotheses. In this study, a synthesized peptide with ¹⁵N-labeled amino acid residues was utilized to examine the mechanism by which humic substances from a peat might chemically interact with peptides to induce preservation. Two-dimensional ¹⁵N-¹H HSQC NMR experiments were performed to evaluate the bonding and nonbonding interactions between ¹⁵N-labeled peptide and an Everglades peat humic acid. The observed changes in cross peaks provide the first direct spectroscopic evidence for what we believe to be covalent binding between these substances. Noncovalent interactions between the ¹⁵N-labeled peptides and humic acid molecules are also observed in the spectra. Quinone structures in humic acids are suggested to be the important reactive groups, based on reaction of the labeled peptide with a model quinone which shows similar nitrogen-proton correlated peak patterns as is observed in the HSQC NMR spectra of humic acids reacted with the peptide. The Michael reaction with quinone structures is proposed, and this type of reaction provides a mechanism that is consistent with previous observation for the chemistry of sedimentary nitrogen species.     

Establishing the Database of Inundation Potential in Taiwan

The structural measure was the major solution for flood defense in Taiwan. However, the measure is always limited to the design standard and cannot prevent the damages when floods exceed certain scale. Therefore, non-structural measures for flood mitigation are the indispensable complements to structural solutions. The study introduces the establishment of inundation potential database that provides required information for the non-structural measures in Taiwan. The database was built by numerical simulations, based on different rainfall scenarios, and has been applied by the local governments of Taiwan for land use managements, flood warning systems, emergency responses, and flood insurance programs to reduce the flood damages and impacts.     

Covalent coupling of peptides to humic acids: Structural effects investigated using 2D NMR spectroscopy

Covalent and non-covalent interaction of proteinaceous materials in soils and sediments has been suggested as an important mechanism for immobilizing nitrogen in numerous types of environments. In a previous study (Hsu P.-H., Hatcher, P.G., 2005. New evidence for covalent coupling of peptides to humic acids based on 2D NMR spectroscopy: A means for preservation. Geochimica et Cosmochimica Acta 69, 4521–4533), we provided molecular evidence for covalent, as well as non-covalent, bonding between ¹⁵N-labeled peptides and humic acid molecules using the 2D HSQC (heteronuclear single quantum coherence) NMR technique. In this report, we examine the influence of aromaticity and aliphaticity of peptides and humic materials on these covalent and non-covalent interactions. We use 2D NMR techniques to evaluate bonding interactions of ¹⁵N labeled peptides, having different aromatic and aliphatic properties, with three humic acids that vary in degree of aromaticity. The peptide containing primarily aromatic amino acid residues is observed to form covalent and non-covalent bonds with mainly aromatic-rich humic acids. The peptide composed of aliphatic amino acid residues shows, on the other hand, only bonding interactions with aliphatic-rich humic acids. These observations provide the first direct molecular evidence that aliphatic functional groups are involved in bonding with proteinaceous materials. The process may play an important role in sequestration of proteinaceous materials in sedimentary systems such as marine systems where the humic materials are mainly aliphatic in nature.