Optical variability of the NLS1 galaxy Ark 564 in 1987–2004

We present the results of our U BV R _c I _c photoelectric and CCD photometry of the NLS1 galaxy Ark 564 in 1987–2004. Between late 1997 and 2002, a slight increase in brightness was observed followed by a small but systematic decline until 2004. Ark 564 has a low variability amplitude, within 0.2^m in the U BV R _c I _c bands. The galaxy’s spectral energy distribution at 3600–9000 Å is unlike those for Seyfert 1 (Syl) galaxies. A delay of the Ic flux relative to the B flux of about three days was found, which is in agreement with the standard disk model. This delay probably reflects the geometric size of the region that emits the observed continuum.     

Ge-bearing coals of the Luzanovka Graben, Pavlovka brown coal deposit, southern Primorye

Results of the study of a new Ge-bearing area of the Pavlovka brown coal deposit are presented. Ge is accumulated in bed III₂ lying at the bottom of the Late Paleogene-Early Neogene coal-bearing sequence adjacent to the Middle Paleozoic granite basement. The Ge content in coals and coal-bearing rocks varies in different sections from 10 to 200–250 ppm, reaching up to 500–600 ppm in the highest-grade lower part of the bed. The metalliferous area reveals a geochemical zoning: complex Ge-Mo-W anomalies subsequently grades along the depth and strike into Mo-W and W anomalies. Orebodies, like those at many Ge-bearing coal deposits, are concentric in plan and dome-shaped in cross-section. Coals in their central parts, in addition to Ge, W, and Mo, are enriched in U, As, Be, Ag, and Au. Distribution of Ge and other trace elements in the metalliferous sequence and products of gravity separation of Ge-bearing coals is studied. These data indicate that most elements (W, Mo, U, As, Be) concentrated like Ge in the Ge-bearing bed relative to background values are restricted to the organic matter of coals. The electron microscopic study shows that Ge-bearing coals contain native metals and intermetallic compounds in association with carbonates, sulfides, and halogenides. Coal inclusions in the metalliferous and barren areas of the molasse section strongly differ in contents of Ge and associated trace elements. Ge was accumulated in the coals in the course of the interaction of ascending metalliferous solutions with organic matter of the buried peat bogs in Late Miocene. The solutions were presumably represented by N₂-bearing thermal waters (contaminated by volcanogenic CO₂) that are typical of granite terranes.     

The Kyrgyz-Ata Synform in the South Tien Shan: Structural and kinematic aspects of its evolution

The complexes of metamorphic rocks that take part in the tectonic structure of the South Tien Shan are mostly confined to the cores of large synforms and occupy high structural position therein. Problems of their age, origin, metamorphic conditions, and relationships with the adjacent unmetamorphosed Paleozoic sequences have remained debatable throughout the history of geological investigations. The results of detailed studies of the Kyrgyz-Ata Synform, a typical structure of the Turkestan-Alay Zone in the South Tien Shan, are reported in this paper. The metamorphic rocks of the Kan Group participate in the structure of this synform. On the basis of the study of structural assemblages and the kinematic analysis, it is concluded that the multistage evolution of this tectonic unit proceeded under transpressive conditions of volcanic trough “crushing.” The detailed study of rock alteration in the contact zone between the Kan Group and the Middle Devonian basic volcanic rocks allowed us to suggest that the metamorphic Kan Group is not a self-dependent stratigraphic unit but represents an infrastructure (a metamorphosed analogue of the volcanic sequence and underlying rocks) displaced tectonically over its own suprastructure.     

On two types of metalliferous carbonaceous rocks

Two types of metalliferous carbonaceous rocks that differ in associated metals are considered. One of them is characterized by gold occurring in finely dispersed arsenopyrite and arsenic-bearing pyrite, and the other, by finely impregnated native metals in carbonaceous matter. Rocks of the first type also contain elements of the platinum group, while those of the second type bear rhenium, silver, iron, molybdenum, and other metals. Graphitic mineralization is usually localized in the shear zone associated with alkaline basalts.     

Computer microtomography of zircon: A new approach to the selection of targets for U-Pb geochronologic studies

The paper reports results obtained by the complex studying of zircon crystals from rocks of various genesis. Zircon is one of the minerals most often used as geochronometers. It also provides genetic information on superimposed processes that is “recorded” in the external and internal morphology of its crystals. This mineral is thoroughly examined to select its unaltered crystals for U-Pb dating by the single-grain method. Zircon grains are selected with the use of optical and electron microscopy and cathodoluminescence. This publication presents the first results obtained by examining zircon by computer microtomography (μCT) and the results of the studying of the external and internal structure by conventional techniques ([optical microscopy and SEM (SE and CL)]. The paper demonstrates the advantages of the application of the μCT techniques to the selection of targets for U-Pb zircon dating: there is no need for the special preparation of the samples and no material is destructed. However, this technique may be not informative enough if the zircon contains inherited core whose density does not differ from the density of the surrounding mineral.     

Vertical distribution and water solubility of phosphorus and heavy metals in sediments of the St. Lucie Estuary, South Florida, USA

Accumulation and distribution of heavy metals and phosphorus in sediments impact water quality. There has been an increasing concern regarding fish health in the St. Lucie Estuary, which is related to increased inputs of nutrients and metals in recent decades. To investigate vertical changes of contaminants (P, Cd, Cr, Co, Cu, Ni, Pb, Zn, and Mn) in sediments of the St. Lucie Estuary in South Florida, 117 layer samples from six of the 210 to 420 cm depth cores were analyzed for their total and water-soluble P and heavy metals, clay, total Fe, Al, K, Ca, Mg, Na, and pH. Principal component analysis (PCA) was used in two sets of analytical data (total and water-soluble contaminant concentrations) to document changes of contaminants in each core of sediments. The PCA of total contaminants and minerals resulted in two factors (principal components). The first and second factors accounted for 61.7 and 17.2 % of the total variation in all variables, and contrast indicators associated with contaminants of P, Cd, Co, Cr, Ni, Pb, Zn, and Mn and accumulation of Fe and Al oxides, respectively. The first factor could be used for overall assessment of P and heavy metal contamination, and was higher in the upper 45–90 cm than the lower depths of each core. The concentrations of P and heavy metals in the surface layers of sediments significantly increased, as compared with those in the sediments deeper than 45–90 cm. The PCA of water-soluble contaminants developed two factors. The second factor (Cu–P) was higher in the upper than the lower depths of the sediment, whereas the highest score of the first factor (Cd–Co–Cr–Ni–Pb–Zn–Mn) occurred below 100 cm. The water-soluble Cu and P concentrations were mainly dependent on their total concentrations in the sediments, whereas the water-soluble Cd, Co, Cr, Ni, Pb, Zn, and Mn concentrations were mainly controlled by pH.     

吉林伊通盆地莫里青断陷古近系双阳组储集层成岩作用研究

古近系双阳组是在吉林省伊通盆地莫里青断陷中，油气赋存的主要层位,储层主要为湖底扇和扇三角洲的砂体。依据双阳组储层的大量薄片、扫描电镜、粘土矿物分析的资料研究了该储集层的成岩作用。研究结果表明双阳组储集层：成岩作用经历了压实、压溶、胶结、交代和溶解6方面的作用。双储集层中的自生粘土矿物蒙皂石向伊利石转化具有明显的特征：主要演化过程经历了蒙皂石渐变带，第一迅速转化带和第二迅速转化带，相应的成岩作用阶段可划分为早成岩阶段B期、晚成岩阶段A1期和晚成岩阶段A2期。依据在垂向上的成岩变化,建立了莫里青断陷双阳组储集层的成岩作用演化序列。在垂向上成岩作用的类型和强度均存在明显的差异，造成了储层物性的垂向分带。     

塔里木盆地东河砂岩沉积和储层特征及综合分析

东河砂岩是一套海侵初期的沉积产物，东河砂岩不是一个等时沉积体，相当于晚泥盆世晚期至早石炭世早期沉积，具体沉积时间各地有差异。由于东河砂岩是覆盖广泛的海侵初期沉积，因此具有海侵初期填平补齐的特征，其沉积相决定于海侵的速度、沉积物的供给和海侵前的古地貌。塔北地区受塔北古隆起的阻挡，海水在古隆起周围滞留时间较长，又有较粗粒的物源供给，其沉积产物主要是滨岸海滩沉积；塔中地区由于地形复杂，沉积类型也比较复杂，底部砾岩段有河流相沉积，而块状砂岩段和砂砾岩段有河口湾和滨岸海滩沉积，不同段在成分、分选性和粒级上有较大的差异；而其它低平地区主要是海侵期快速的滨岸和陆架沉积。受沉积因素影响，东河砂岩有效储层的分布具有地域性；除沉积因素外，低的地温梯度和短期的深埋藏是优质储层发育的重要控制因素。