Application of Column Chromatography for Accurate Determination of the Carbon Isotopic Compositions of n-alkanes in Diverse Environmental Samples

Ocean Science Journal - The carbon isotopic compositions (δ13C) of n-alkanes in various environmental samples have been previously proposed as suitable fingerprints for assessing the origin of...     

Reduction of future disaster damages by learning from disaster experiences

This paper examines the effect of a country’s own past disaster experiences and nearby countries’ past experiences on subsequent disaster damage. We use global disaster data from 1990 to 2010, which include disaster-related death tolls for both natural and technological disasters that are further divided into sub-categories. Overall, we find evidence of a reduction effect of past disaster damage on future disaster damage. More detailed analyses show that an adaptation effect seems to be present for certain combinations of disaster types and levels of economic development. The results show that a country’s own experiences reduce future damage for natural disasters but that the marginal effect is larger for lower-income countries. On the other hand, for technological disasters, a robust impact of experiences was found only in higher-income countries. In terms of the disaster experiences of nearby countries, the adaptation effect was found only for natural disasters, and the marginal impact was relatively higher for higher-income countries.     

Structural similarity and variety at the tips in a wide range of strike–slip faults: a review

Strike–slip faults are often accompanied by a variety of structures, particularly at their tips. The zones of additional fracturing are classified as tip‐damage zones. These zones can be subdivided into several different damage patterns based on the nature and orientation of faults and fractures developed. Damage zones at the ends of small strike–slip faults (mode II tips) develop wing cracks, horsetail splays, antithetic faults, synthetic branch faults and solution surfaces. Similar tip‐damage patterns are also commonly observed at larger (regional) scales, but with a dominance of faulting over tensile cracks and solution surfaces. Wing cracks and horsetail splays developed at small‐scale faults are replaced by normal faults in large‐scale faults. Antithetic faults and synthetic branch faults are observed at small and large scales. Thrust faults are developed at large scales, in a similar pattern to solution surfaces at a small scale. All these structures may show slightly different angular relationships to the master fault at small and large scale, but develop in response similar stress distribution and mechanics around the fault. Thus, mode II tip‐damage zones show similar patterns over a wide range of fault scales.     

Impact of adsorbed petroleum hydrocarbons on marine organisms

Adsorptions of south Louisiana crude oil from seawater by clays, non-clay minerals and sediments were conducted in the laboratory. Effect of sediment-adsorbed and water dispersed crude oil on adult oysters were investigated in aquaria. Hydrocarbons in oyster tissues and surrounding water were identified by gas chromatography. Field specimens from an area of a new oil spill and an area five months after an oil spill were also analysed. Evidence of secondary chemical effect of aged oil in sediments on oyster mortality is presented. Oil coated asbestos surfaces severely reduced recruitment of sedentary larval organisms.     

Growth of the ice phase in strong cumulonimbus updrafts

A numerical model of ice phase growth in an ascending parcel is used to delineate seeding requirements under the competing embryo and glaciation hypotheses. The strong updraft core is found to remain virtually all liquid until homogeneous freezing occurs, AgI or dry ice seeding having negligible effects with achievable seeding rates. This suggests that the glaciation hypothesis is untenable. Natural hail embryo formation is noted to be limited to updrafts less than 3 to 4 m sec^?1 at cloud base. AgI seeding of such updraft regions at rates currently used is found to produce concentrations of hail embryos sufficient to enhance competition in multi-cell hailstorms, although super-cell storms may require significantly greater seeding rates.     

Mercury in tissues of mussel off southern California

Total mercury content has been determined in three tissues of the intertidal mussel Mytilus californianus collected at locations along the southern California coast and at island control stations. The apparent influence of certain harbours and municipal wastewater outfalls was reflected by the relatively higher levels of mercury in all tissues of mussels from these areas. In general, the concentrations reported here are lower than those in mussels on west European coasts.     

Comparison of waveform inversion, part 1: conventional wavefield vs logarithmic wavefield

This is the first in a series of three papers focused on using variants of a logarithmic objective function approach to full waveform inversion. In this article, we investigate waveform inversion using full logarithmic principles and compare the results with the conventional least squares approach. We demonstrate theoretically that logarithmic inversion is computational similar to the conventional method in the sense that it uses exactly the same back‐propagation technology as used in least‐squares inversion. In the sense that it produces better results for each of three numerical examples, we conclude that logarithmic inversion is also more robust. We argue that a major reason for the inherent robustness is the fact that the logarithmic approach produces a natural scaling of the amplitude of the residual wavefield by the amplitude of the modelled wavefield that tends to stabilize the computations and consequently improve the final result. We claim that any superiority of the logarithmic inversion is based on the fact that it tends to be tomographic in the early stage of the inversion and more dependent on amplitude differences in the latter stages.     

Organohalogen compounds in deep-sea fishes from the western North Pacific, off-Tohoku, Japan: Contamination status and bioaccumulation profiles

Twelve species of deep-sea fishes collected in 2005 from the western North Pacific, off-Tohoku, Japan were analyzed for organohalogen compounds. Among the compounds analyzed, concentrations of DDTs and PCBs (up to 23,000 and 12,400 ng/g lipid wt, respectively) were the highest. The present study is the foremost to report the occurrence of brominated flame retardants such as PBDEs and HBCDs in deep-sea organisms from the North Pacific region. Significant positive correlations found between δ¹⁵N (‰) and PCBs, DDTs and PBDEs suggest the high biomagnification potential of these contaminants in food web. The large variation in δ¹³C (‰) values observed between the species indicate multiple sources of carbon in the food web and specific accumulation of hydrophobic organohalogen compounds in benthic dwelling carnivore species like snubnosed eel. The results obtained in this study highlight the usefulness of deep-sea fishes as sentinel species to monitor the deep-sea environment.     

Fatty acid profiles of benthic environment associated with artificial reefs in subtropical Hong Kong

Artificial reefs can enhance habitat heterogeneity, especially in seabed degraded by bottom-dredging and trawling. However, the trophodynamics of such reef systems are not well understood. This study provided baseline data on trophic relationships in the benthic environment associated with artificial reefs in late spring and mid summer of subtropical Hong Kong, using fatty acid profiles as an indicator. Data from sediments collected at the reef base, materials from sediment traps deployed on top and bottom of the reefs, total particulate matter from the water column and oyster tissues from reef surface were subjected to principal component analysis. Results showed variations of fatty acid profiles in the total particulate matter, upper sediment trap and oyster tissue samples collected in the two samplings, indicating seasonal, trophodynamic changes within the reef system. The wastes produced by fish aggregating at the reefs can also contribute a source of biodeposits to the nearby benthic environment.     

On Evaluating Characteristics of the Solute Transport in the Arid Vadose Zone

The transport of bromide (Br) under matric heads of 0, ?2, ?5, and ?10 cm using undisturbed soil columns was investigated for understanding the solute transport in arid soils. Undisturbed soil cores were collected at ground surface, directly below where tension infiltrometer measurements were made in the Amargosa Desert, Nevada, United States. Laboratory experiments were conducted by introducing water containing Br tracer into a soil column maintained at steady‐state conditions. The observed data of breakthrough curves (BTC) were well fitted to an one‐region model, except for the cores at saturation, and a core at the matric head of ?5 cm, from which the observed data were better fitted to a two‐region model. Fitted pore water velocities with the one‐region model ranged from 1.2 to 56.6 cm/h, and fitted dispersion coefficients (D) ranged from 2.2 to 100 cm²/h. Results for the core analyzed with the two‐region model indicated that D ranged from 27.6 to 70.9 cm²/h at saturation, and 25.7 cm²/h at the matric head of ?5 cm; fraction of mobile water (β) ranged from 0.18 to 0.65, and mass transfer coefficient (ω) ranged from 0.006 to 0.03. In summary, the water fluxes and Br dispersion coefficients at investigated matric heads were very high due to the coarseness of the soils and possibly due to preferential flow pathways. These high water fluxes and Br dispersion coefficients would lead to a higher risk of deeper leaching accumulating nitrate nitrogen to the groundwater, and have significant effects on the desert ecosystem.