The effects of soil sand contents on characteristics of humic acids along soil profiles

It is generally accepted that the compositions and properties of soil organic matter (SOM) are influenced by many factors. In order to reveal the effects of soil texture on characteristics and dynamics of SOM and its sub-fraction, humic acid (HA), along two soil profiles, a yellow soil profile and a purplish soil profile, under the same climate and vegetation conditions were determined. Results indicate that the decomposition and humification degrees of SOM and HA of the purplish soils are higher than those of the corresponding yellow soils indicated by A/O–A ratios of HAs, TOCs and HA yields of bulk soil samples, nevertheless, the development degree of the purplish soil is lower than that of the yellow soil. The variations of E₄/E₆ ratios of HAs along the soil profiles indicate the overall molecular sizes of HAs decreased downward along the soil profiles. A/O–A ratios of HAs decreased downward along both the soil profiles indicate that humification processes decrease downward along both the soil profiles. Leaching of SOM shows significant effects on the distribution and characteristics of HAs in the yellow soil profile but the purplish soil profile, which is consistent with the higher hydrophobicity of HAs in purplish soils, shows that the distribution characteristics of SOM along the soil profiles are a complex result of the combination of soil texture and characteristics of SOM itself. The remarkably different sand contents are concluded tentatively as one of reasons to the different distributions and dynamics of HAs along the soil profiles, however, to profoundly understand the evolution and transport of SOM along soil profiles needs more researches.     

Fish,Macroinvertebrate and Epifaunal Communities in Shallow Coastal Lagoons with Varying Seagrass Cover of the Northern Gulf of Mexico

Coastal lagoons are ubiquitous along coastlines worldwide. Here, we compare the abundance of epifauna, seagrass-associated macroinvertebrates, and small fish across a gradient of seagrass cover in shallow coastal lagoons of the northern Gulf of Mexico. Two of the lagoons had little or no seagrass cover (0–18.8 %), and four had high cover (83.8–97.5 %). All of the lagoons were partially covered with fringing marsh. We hypothesized that, due to habitat redundancy between seagrass beds and fringing marshes, seagrass-associated fish and macroinvertebrates would not be largely reduced despite the large differences in seagrass cover among the lagoons. Our results support this hypothesis. For most sampling dates, we did not find significant differences in fish and macroinvertebrate abundance among the lagoons and, when we did, several highly vegetated lagoons did not have larger abundances than sparsely vegetated lagoons. The extreme shallowness of the lagoons studied (<1 m) may also provide further protection from large predatory fishes in the absence of seagrasses. Our results also suggest that marsh detritus, by providing habitat for epifauna and helping maintain prey availability, may further temper reductions in seagrass-associated fishes and macroinvertebrates following seagrass decline. The results highlight the importance of marsh-bordered, shallow lagoons as habitat for small fish and macroinvertebrates regardless of seagrass cover. This study contributes to the characterization of habitat redundancy in coastal ecosystems and pinpoints the importance of considering all habitats in concert for the proper understanding and management of coastal ecosystems.     

An evaluation of the relationship between physical/mechanical properties and mineralogy of landscape rocks as determined by hyperspectral reflectance

We investigated the relationships between mineral content and the physical and mechanical properties of landscape rock using a non-destructive remote sensing method applied in the laboratory. Using this technique, the spectral properties of the landscape rock could be collected at different wavelengths without harming the samples. Differences in spectral reflectance were compared with the physical and mechanical properties of the stone. Significant correlations were observed between reflectance values and the rocks’ mechanical and physical properties, with correlation coefficients of 95 to 99 %. However, establishing a correlation between two variables is not a sufficient condition to establish a causal relationship. Mineral densities and mineral content are characteristics used for the classification of landscape rock. We have concluded that although spectral signatures from landscape rock can be used for predicting which stones might have similar features when comparing two batches of stone, the high correlations we discovered cannot confirm a cause and effect relationship that would allow for the prediction of a rock’s physical and mechanical properties. Although this conclusion is disappointing, the mineral content and the significant correlations discovered by hyperspectral reflectance scanning can be used as supplementary information when comparing two samples of landscape rock.     

Data integration in characterizing a fracture-cavity reservoir,Tahe oilfield,Tarim basin,China

Fracture-cavity reservoirs can be described in terms of storage space, filling materials and distribution, however, characterizing these variables remains a challenge. In this study, a method was developed to characterize complex reservoirs by integrating outcrop, core, well log, and seismic data from the Tahe oilfield. Outcrop analogs were used to identify and qualitatively analyze the genesis of different reservoir spaces. Cores, well logs, and seismic data were used to identify different types of reservoir space in the subsurface, to describe the spatial distribution, and to establish the distribution pattern of fracture-cavity reservoirs. Clastic sediments, collapse breccia, and chemical fillings were described from the cores and used to assess porosity and permeability. On the basis of the results, a three-dimensional geological model was constructed incorporating a structural model, a reservoir space model, and a property model. Caves and fractures were the main storage spaces and seepage passages. The cave model was built using multi-point geostatistical simulation, while the fracture model was established using deterministic modeling combined with manual interpretations and ant-tracking technology.     

Atmospheric tracer monitoring and surface plume development at the ZERT pilot test in Bozeman,Montana, USA

A controlled release of CO₂ was conducted at a field site in Bozeman, Montana, USA in July of 2008 in a multi-laboratory study of near surface transport and detection technologies. The development of a subsurface CO₂ plume near the middle packer section of the horizontal release was studied using soil-gas and surface flux measurements of CO₂. A perfluorocarbon tracer was added to the CO₂ released from this section of the horizontal well, and the development of atmospheric plumes of the tracer was studied under various meteorological conditions using horizontal and vertical grids of monitors containing sorbent material to collect the tracer. This study demonstrated the feasibility of using remote sensing for the ultra low level detection of atmospheric plumes of tracers as means to monitor the near surface leakage of sequestered CO₂.     

Geochemistry of fluoride rich groundwater in Kolar and Tumkur Districts of Karnataka

Groundwater is a significant water resource in India for domestic, irrigation, and industrial needs. By far the most serious natural groundwater-quality problem in India, in terms of public health, derives from high fluoride, arsenic, and iron concentrations. Hydrogeochemical investigation of fluoride contaminated groundwater samples from Kolar and Tumkur Districts in Karnataka are undertaken to understand the quality and potability of groundwater from the study area, the level of fluoride contamination, the origin and geochemical mechanisms driving the fluoride enrichment. Majority of the groundwater samples did not meet the potable water criteria as they contained excess (>1.5 mg/L) fluoride, dissolved salts (>500 mg/L) and total hardness (75–924 mg/L). Hydrogeochemical facies of the groundwater samples suggest that rock weathering and evaporation–crystallization control the groundwater composition in the study area with 50–67% of samples belonging to the Ca–HCO₃ type and the remaining falling into the mixed Ca–Na–HCO₃ or Ca–Mg–Cl type. The saturation index values indicated that the groundwater in the study area is oversaturated with respect to calcite and under-saturated with respect to fluorite. The deficiency of calcium ion concentration in the groundwater from calcite precipitation favors fluorite dissolution leading to excess fluoride concentration.     

Study of petrological characteristics of coal deposits from Marki-Jhari-Jamni area,Wardha valley coalfield,Maharashtra

A detailed study of maceral composition and vitrinite reflectance of the coal deposits from Marki-Jhari-Jamni area, situated in the northwestern extremity of Wardha valley coalfield, Yeotmal district, Maharashtra has been carried out with special reference to their depositional set up. These coals have two distinct types of maceral organization, one having significantly high distribution of the vitrinite group of macerals (35–41%) and the other containing the dominance of inertinite (26–49%). Liptinite maceral group is recorded between 14 and 24%, barring a few coal bands having liptinite maceral group as high as 33–37%. The vitrinite reflectivity ranges from 0.38–0.43%. Thus, they have attained sub-bituminous C rank. Mineral matter in these coals varies between 15 and 22%. The present study suggests that the basin primarily experienced cold climate having intermittent brackish water influx with alternating dry oxidizing spells.     

New observations on Rajahmundry Traps of the Krishna-Godavari Basin

The Rajahmundry Traps of the Krishna Godavari Basin (K-G Basin) consist of three distinct basalt flows interbedded with two intertrappean sedimentary horizons, which in turn are underlain by the late Cretaceous fossiliferous limestone bed (infratrappean) and overlain by the Cenozoic Rajahmundry Formation (conglomerate/sandstone). Among the three, the lower flow is characterized by the presence of the physical volcanological features such as rootless cones, tumuli and dyke like forms along with single to multitier columnar and radial jointing. The middle and upper flows are simple, massive and vesicular and exhibit spheroidal weathering. Physical volcanological features and lithological attributes indicate that the lower flow was formed by an explosive volcanic activity in hydrous environment, followed by sub aerial eruption to form the middle and upper flows. The fossiliferous limestone bed is a representative horizon for the K-T boundary mass extinction caused due to intense volcanism. Intertrappean sediments exhibit weathered soil profiles (palaeosols) with limestone beds denoting a distinct time gap during various phases of lava eruption. Evaluation of the palaeogeographic scenario of the Krishna and Godavari Rivers does not provide any evidence for the existence of Cretaceous palaeovalley which would have provided pathway for lava transportation from the Deccan volcanic province of western India to the K-G Basin situated along the east coast. The present study opens up an alternative approach to explain the origin of basalt flows at Rajahmundry. In all probability the lavas could be intrabasinal. NW-SE and NESW faults or their intersection zones are probable pathways for lava eruption in the K-G Basin.