Melting experiments on a high-magnesian andesite

Melting experiments were conducted on a high-magnesian bronzite olivine andesite (Teraga-Ike andesite) which is considered to be a primary andesite. The high-magnesian andesite magma is in equilibrium with both olivine and orthopyroxene at about 15.5 kbar and 1080°C under H₂O-saturated conditions and at lower pressure and higher temperature under H₂O-undersaturated conditions. This suggests that high-magnesian andesites could be generated by the partial melting of upper mantle peridotite containing a small amount of H₂O.     

Anomalously large seismic amplifications in the seafloor area off the Kii peninsula

Seismic wave amplifications were investigated using strong-motion data obtained from the ground’s surface (K-net) on the Kii peninsula (southwestern Japan) and from the network of twenty seismic stations on the seafloor (DONET) located off the peninsula near the Nankai trough. Observed seismograms show that seismic signals at DONET stations are significantly larger than those at K-net stations, independent of epicentral distances. In order to investigate the cause of such amplifications, seismic wavefields for local events were simulated using the finite-difference method, in which a realistic 3D velocity structure in and around the peninsula was incorporated. Our simulation results demonstrate that seismic waves are significantly amplified at DONET stations in relation to the presence of underlying low-velocity sediment layers with a total thickness of up to 10 km. Our simulations also show considerable variations in the degree of amplification among DONET stations, which is attributed to differences in the thickness of the sediment layers. The degree of amplification is relatively low at stations above thin sediment layers near the trough axis, but seismic signals are much more amplified at stations closer to the Kii peninsula, where sediment layers are thicker than those at the trough axis. Simulation results are consistent with observations. This study, based on seafloor observations and simulations, indicates that because seismic signals are amplified due to the ocean-specific structures, the magnitude of earthquakes would be overestimated if procedures applied to data observed at land stations are used without corrections.     

Partitioning Eddy-Covariance Methane Fluxes from a Shallow Lake into Diffusive and Ebullitive Fluxes

Methane (\(\mathrm {CH}_{4}\)) is known to be emitted from lakes to the atmosphere via processes such as diffusion and ebullition (i.e., bubble emission). We developed a practical method for partitioning eddy-covariance \(\mathrm {CH}_{4}\) fluxes from a shallow lake into diffusive and ebullitive fluxes using a wavelet analysis based on local scalar similarity between the \(\mathrm {CH}_{4}\) concentration and other reference scalars, such as the air temperature or water vapour concentration, in the wavelet time-scale domain, with the hypothesis that similar and dissimilar fluctuation components are related to diffusive and ebullitive \(\mathrm {CH}_{4}\) fluxes, respectively. Our method is applied to approximately two weeks of data obtained at a shallow mid-latitude lake. The partitioned diffusive flux has a physically sound relationship with wind speed, supporting the validity of the method. The ratio of the diffusive flux to the total flux is typically 0.11 with flow from an area of steady bubble emission, but otherwise 0.36. Further validation is required using a larger dataset and data from other lakes. The proposed method can be easily applied to historical data because it requires only 10-Hz data of \(\mathrm {CH}_{4}\) concentration and other reference scalars, along with an empirical parameter.     

Bimodal representation of the tropical intraseasonal oscillation

The tropical intraseasonal oscillation (ISO) shows distinct variability centers and propagation patterns between boreal winter and summer. To accurately represent the state of the ISO at any particular time of a year, a bimodal ISO index was developed. It consists of Madden-Julian Oscillation (MJO) mode with predominant eastward propagation along the equator and Boreal Summer ISO (BSISO) mode with prominent northward propagation and large variability in off-equatorial monsoon trough regions. The spatial–temporal patterns of the MJO and BSISO modes are identified with the extended empirical orthogonal function analysis of 31?years (1979–2009) OLR data for the December–February and June–August period, respectively. The dominant mode of the ISO at any given time can be judged by the proportions of the OLR anomalies projected onto the two modes. The bimodal ISO index provides objective and quantitative measures on the annual and interannual variations of the predominant ISO modes. It is shown that from December to April the MJO mode dominates while from June to October the BSISO mode dominates. May and November are transitional months when the predominant mode changes from one to the other. It is also shown that the fractional variance reconstructed based on the bimodal index is significantly higher than the counterpart reconstructed based on the Wheeler and Hendon’s index. The bimodal ISO index provides a reliable real time monitoring skill, too. The method and results provide critical information in assessing models’ performance to reproduce the ISO and developing further research on predictability of the ISO and are also useful for a variety of scientific and practical purposes.     

Weathering of apatite under extreme conditions of leaching

Apatites occurring in lateritic residues derived from high-grade metamorphic rocks from Sri Lanka are hydroxy-apatite as indicated by EPMA and XRD. Weathered phosphates and weathered crystalline products are composed of carbonate fluorapatite, crandallite, wardite, fluellite, kaolinite, goethite and gibbsite. EDAX, DTA and SIMS show the presence of amorphous materials, such as oxides of Fe, Al, Si, Al+Si, and S, on the surface of weathered phosphate. Using SEM, TEM, EDAX and electron diffraction techniques, the presence of these amorphous and crystalline materials with several transitions has been clearly identified in weathered phosphate. Recrystallization of phosphate occurred during weathering by dissolution, nucleation and precipitation. The lattice images of hydroxyapatite are gradually increased from 8.3-A basal spacings by weathering, and form mosaic bound fragments. Chondrite-, shale- and phosphorite concretion-normalized REE patterns of these apatites, known to have sedimentary origins, suggest enrichment and remobilisation during post-depositional reworking.