Improved Method for Calculating Anthropogenic CO2 in the Upper Layer of the North Pacific Subtropical Gyre along 175°E

Seawater samples were collected in the North Pacific along 175°E during a cruise of the Northwest Pacific Carbon Cycle Study (NOPACCS) program in 1994. Many properties related to the carbonate system were analyzed. By using well-known ratios to correct for chemical changes in seawater, the CO₂ concentration at a given depth was back calculated to its initial concentration at the time when the water left the surface in winter. We estimated sea-surface CO₂ and titration alkalinity (TA) in present-day winter, from which we evaluated the degree of air-sea CO₂ disequilibrium in winter was. Using a correction factor for air-sea CO₂ disequilibrium in winter, we reconstructed sea-surface CO₂ in pre-industrial times. The difference between the back-calculated initial CO₂ and sea-surface CO₂ in pre-industrial times should correspond to anthropgenic CO₂ input. Although the mixing of different water masses may cause systematic error in the calculation, we found that the nonlinear effect induced by the mixing of different water masses was negligible in the upper layer of the North Pacific subtropical gyre along 175°E. The results of our improved method of assessing the distribution of anthropogenic CO₂ in that region show marked differences from those obtained using the previous back-calculation method.     

The paleobiogeographical significance of the Silurian and Devonian trilobites of Japan

Six major groups of trilobites from the Silurian and Devonian of Japan are evaluated for their paleobiogeographical signature. Silurian illaenids and scutelluids show four generic‐level and at least two species‐level links with the Australian segment of the Gondwana paleocontinent; encrinurids also indicate two generic‐level links with Australia and also the South China paleocontinent; whilst Devonian phacopids, and possibly proetids, suggest at least two generic‐level links with the North China paleocontinent. These different patterns may reflect the fragmentary biostratigraphical record of Japanese trilobites, but they also appear to reflect paleoenvironmental parameters associated with lithofacies, and paleoecology. Thus, Japanese assemblages of proetids and phacopids occurring in deep‐water clastic lithofacies have counterparts in similar settings in North China, and Japanese scutelluids and illaenids are strongly associated with shallow marine carbonate lithofacies that are similar to those of their occurrences in Australia. Japanese encrinurids occur in carbonate rocks indicative of shallow marine settings in the Kurosegawa Terrane, and they demonstrate a consistent paleobiogeographical affinity with Australia and South China. Larval ecology cannot be directly assessed for Japanese trilobite groups. However, proetids have consistently been shown to have planktonic protaspides, whereas illaenids, scutelluids, and encrinurids have benthic protaspides. Planktonic protaspides would have a greater propensity for distribution in ocean currents than benthic ones, and therefore may be of more limited paleobiogeographical utility. The combined data from the six different groups indicates that the complex paleobiogeographical patterns of the Japanese trilobite assemblages need to be interpreted with caution, and similarity of taxa does not necessarily denote paleogeographical proximity to other regions.     

The Kellwasser events in the Upper Devonian Frasnian to Famennian transition in the Toc Tat Formation,northern Vietnam

Upper Devonian carbonates of the Toc Tat Formation in the Si Phai Pass area of Dong Van District, northern Vietnam were deposited in carbonate platform, slope, and basin environments. These carbonates yield abundant conodonts indicative of the Palmatolepis nasuta, Pa. linguiformis and Pa. triangularis zones, the Frasnian–Famennian stage boundary being identified by the first occurrence of Pa. triangularis. Two positive carbon isotope excursions are recognized, the lower excursion peaking in the interval of the lower to middle Pa. nasuta Zone, whilst the upper excursion peaks just above the local Frasnian–Famennian boundary. Based on the biostratigraphy, these excursions equate to the Lower and Upper Kellwasser events. Locally, tentaculitoid taxa (Nowakia, Styliolina, Homoctenus, and Metastyliolina?) are abundant in the interval of the Pa. nasuta Zone, but show a drastic decline in abundance before the Lower Kellwasser Event, and only two taxa survived into the Famennian.     

Numerical simulation of Pacific water intrusions into Otsuchi Bay,northeast of Japan,with a nested-grid OGCM

A numerical simulation of Otsuchi Bay located on the northeast coast of the Honshu, the largest island of Japan, is conducted, using an ocean general circulation model (OGCM) with a nested-grid system in order to illustrate seasonal variability of the circulation in the bay. Through a year, an anticlockwise circulation is dominant in the bay, as observational studies have implied, although it is modified in the bay-mouth-half of the bay in winter. In addition, there is an intense outflow at the surface layer during spring to autumn, influenced by river water discharge. Intrusion of the Pacific water into the bay is influened by mean circulations, but it is also influenced by baroclinic tides from spring to autumn. Pacific water intrusions affected by baroclinic tides may have an impact on the environment in Otsuchi Bay.     

Distributions of polycyclic aromatic hydrocarbons and alkylated polycyclic aromatic hydrocarbons in Osaka Bay,Japan

Contaminations in sediments by polycyclic aromatic hydrocarbons (PAHs) and alkylated PAHs were investigated at 44 sites in Osaka Bay, Japan. Concentrations of total PAHs and alkylated PAHs were in the range 6.40–7800 ng/g dry weights and 13.7–1700 ng/g dry weights, respectively. The PAH concentrations tended to be higher along the shoreline in the vicinities of big ports, industrialized areas, and densely populated regions such as the cities of Osaka and Kobe. The major sources appeared to be pyrogenic or both pyrogenic and petrogenic at most of the sites. PAH concentrations were remarkably high at a site near Kobe, where the concentrations of dibenzo(a,h)anthracene and benzo(g,h,i)perylene exceeded the effects-range-medium concentration and eight PAHs were above the corresponding effects-range-low concentrations. Those PAHs may have been derived from the great fire associated with the large earthquake in 1995.     

Scoria cone formation through a violent Strombolian eruption: Irao Volcano, SW Japan

Scoria cones are common volcanic features and are thought to most commonly develop through the deposition of ballistics produced by gentle Strombolian eruptions and the outward sliding of talus. However, some historic scoria cones have been observed to form with phases of more energetic violent Strombolian eruptions (e.g., the 1943–1952 eruption of Parícutin, central Mexico; the 1975 eruption of Tolbachik, Kamchatka), maintaining volcanic plumes several kilometers in height, sometimes simultaneous with active effusive lava flows. Geologic evidence shows that violent Strombolian eruptions during cone formation may be more common than is generally perceived, and therefore it is important to obtain additional insights about such eruptions to better assess volcanic hazards. We studied Irao Volcano, the largest basaltic monogenetic volcano in the Abu Monogenetic Volcano Group, SW Japan. The geologic features of this volcano are consistent with a violent Strombolian eruption, including voluminous ash and fine lapilli beds (on order of 10^?1 km³ DRE) with simultaneous scoria cone formation and lava effusion from the base of the cone. The characteristics of the volcanic products suggest that the rate of magma ascent decreased gradually throughout the eruption and that less explosive Strombolian eruptions increased in frequency during the later stages of activity. During the eruption sequence, the chemical composition of the magma became more differentiated. A new K–Ar age determination for phlogopite crystallized within basalt dates the formation of Irao Volcano at 0.4?±?0.05 Ma.     

Global distributions of storm-time ionospheric currents as seen in geomagnetic field variations

To investigate temporal and spatial evolution of global geomagnetic field variations from high-latitude to the equator during geomagnetic storms, we analyzed ground geomagnetic field disturbances from high latitudes to the magnetic equator. The daytime ionospheric equivalent current during the storm main phase showed that twin-vortex ionospheric currents driven by the Region 1 field-aligned currents （R1 FACs） are intensified significantly and expand to the low-latitude region of-30~ magnetic latitude. Centers of the currents were located around 70~ and 65~ in the morning and afternoon, respectively. Corresponding to intensification of the R1 FACs, an enhancement of the eastward/westward equatorial electrojet occurred at the daytime/nighttime dip equator. This signature suggests that the enhanced convection electric field penetrates to both the daytime and nighttime equa- tor. During the recovery phase, the daytime equivalent current showed that two new pairs of twin vortices, which are different from two-cell ionospheric currents driven by the R1 FACs, appear in the polar cap and mid latitude. The former led to enhanced north- ward Bz （NBZ） FACs driven by lobe reconnection tailward of the cusps, owing to the northward interplanetary magnetic field （IMF）. The latter was generated by enhanced Region 2 field-aligned currents （R2 FACs）. Associated with these magnetic field variations in the mid-latitudes and polar cap, the equatorial magnetic field variation showed a strongly negative signature, produced by the westward equatorial electrojet current caused by the dusk-to-dawn electric field.     

Year-round accumulation of particulate organic matter in the estuarine turbidity maximum: comparative observations in three macrotidal estuaries (Chikugo, Midori, and Kuma Rivers), southwestern Japan

The inner part of the Ariake Sea is one of the most productive estuarine systems in Japan. To examine potential food items for estuarine organisms, we conducted monthly observations of the dynamics of particulate organic matter along the macrotidal Chikugo River estuary in 2005 and 2006. In the neighboring macrotidal Midori and Kuma River estuaries, comparative observations were made. High turbidity and strong vertical mixing were observed only at low salinities (<10) in the Chikugo River estuary. In contrast, the Midori and Kuma River estuaries were characterized by less turbid and less mixed waters. Concentrations of particulate organic carbon often exceeded 5?mg?l^?1 in or close to the estuarine turbidity maximum (ETM) of the Chikugo River estuary. However, such high concentrations were rarely observed in the other two estuaries. The observed differences could be attributable to different hydrodynamic processes related to the different lengths of tidal reaches: 23, 8, and 6?km in the Chikugo, Midori, and Kuma Rivers, respectively. In the Chikugo River estuary, spatiotemporal changes of chlorophyll a suggested that phytoplankton occurred abundantly up- and/or downstream from the ETM especially during the warm season. In contrast, pheophytin (i.e., plant detritus) always accumulated in or close to the ETM. Carbon stable isotope ratios and carbon to nitrogen ratios indicated that the plant detritus was derived from phytoplankton and terrestrial plants. The Chikugo River estuary has a high potential to support the production of estuarine organisms through abundant plant detritus in the well-developed ETM all the year round.     

Relationships between volcano distribution, crustal structure, and P-wave tomography: an example from the Abu Monogenetic Volcano Group, SW Japan

Achieving an understanding of the nature of monogenetic volcanic fields depends on identification of the spatial and temporal patterns of volcanism in these fields, and their relationships to structures mapped in the shallow crust and inferred in the deep crust and mantle through interpretation of geophysical data. We investigate the spatial and temporal distributions of volcanism in the Abu Monogenetic Volcano Group, Southwest Japan, and compare these distributions to fault and seismic data in the brittle crust, and P-wave tomography of the crust and upper mantle. Essential characteristics of the volcano distribution are extracted by a nonparametric kernel method using an algorithm to estimate anisotropic bandwidth. Overall, E-W elongate smooth modes in spatial density are identified that are consistent with the spatial extent of P-wave velocity anomalies in the lower crust and upper mantle, supporting the idea that the spatial density map of volcanic vents reflects the geometry of a mantle diapir. While the number of basalt eruptions decreased after 0.2 Ma, andesite eruptions increased and overall volume eruption rate is approximately steady-state. Estimated basalt supply to the lower crust is also constant. This observation and the spatial distribution of volcanic vents suggest stability of magma productivity and essentially constant two-dimensional size of the source mantle diapir since 0.46 Ma.