Diverse Range of Mineralization Induced by Phase Separation of Hydrothermal Fluid: Case Study of the Yonaguni Knoll IV Hydrothermal Field in the Okinawa Trough Back-Arc Basin

The Yonaguni Knoll IV hydrothermal vent field (24°51′N, 122°42′E) is located at water depths of 1370–1385 m near the western edge of the southern Okinawa Trough. During the YK03–05 and YK04–05 expeditions using the submersible Shinkai 6500, both hydrothermal precipitates (sulfide/sulfate/carbonate) and high temperature fluids (Tmax = 328°C) presently venting from chimney‐mound structures were extensively sampled. The collected venting fluids had a wide range of chemistry (Cl concentration 376–635 mmol kg^?1), which is considered as evidence for sub‐seafloor phase separation. While the Cl‐enriched smoky black fluids were venting from two adjacent chimney‐mound structures in the hydrothermal center, the clear transparent fluids sometimes containing CO₂ droplet were found in the peripheral area of the field. This distribution pattern could be explained by migration of the vapor‐rich hydrothermal fluid within a porous sediment layer after the sub‐seafloor phase separation. The collected hydrothermal precipitates demonstrated a diverse range of mineralization, which can be classified into five groups: (i) anhydrite‐rich chimneys, immature precipitates including sulfide disseminations in anhydrite; (ii) massive Zn‐Pb‐Cu sulfides, consisting of sphalerite, wurtzite, galena, chalcopyrite, pyrite, and marcasite; (iii) Ba‐As chimneys, composed of barite with sulfide disseminations, sometimes associated with realgar and orpiment overgrowth; (iv) Mn‐rich chimneys, consisting of carbonates (calcite and magnesite) and sulfides (sphalerite, galena, chalcopyrite, alabandite, and minor amount of tennantite and enargite); and (v) pavement, silicified sediment including abundant native sulfur or barite. Sulfide/sulfate mineralization (groups i–iii) was found in the chimney–mound structure associated with vapor‐loss (Cl‐enriched) fluid venting. In contrast, the sulfide/carbonate mineralization (group iv) was specifically found in the chimneys where vapor‐rich (Cl‐depleted) fluid venting is expected, and the pavement (group v) was associated with diffusive venting from the seafloor sediment. This correspondence strongly suggests that the subseafloor phase separation plays an important role in the diverse range of mineralization in the Yonaguni IV field. The observed sulfide mineral assemblage was consistent with the sulfur fugacity calculated from the FeS content in sphalerite/wurtzite and the fluid temperature for each site, which suggests that the shift of the sulfur fugacity due to participation of volatile species during phase separation is an important factor to induce diverse mineralization. In contrast, carbonate mineralization is attributed to the significant mixing of vapor‐rich hydrothermal fluid and seawater. A submarine hydrothermal system within a back‐arc basin in the continental margin may be considered as developed in a geologic setting favorable to a diverse range of mineralization, where relatively shallow water depth induces sub‐seafloor phase separation of hydrothermal fluid, and sediment accumulation could enhance migration of the vapor‐rich hydrothermal fluid.     

A methodology for estimating business interruption loss caused by flood disasters: insights from business surveys after Tokai Heavy Rain in Japan

This study proposes a probabilistic methodology for estimating the business interruption loss of industrial sectors as an extension of current methodology. The functional forms and parameters are selected and calibrated based on survey data obtained from businesses located in the inundated area at the time of the 2000 Tokai Heavy Rain in Japan. The Tokai Heavy Rain was a rare event that hit a densely populated and industrialized area. In the estimation of business interruption losses, functional fragility curves and accelerated failure time models are selected to estimate the extent of damage to production capacity and production recovery time. Significant explanatory variables, such as inundation depth, distinct vulnerability, and the resilience characteristics of each sector, as well as the accuracy of fit of the model, are analyzed in the study. The function obtained and the estimated parameters can be utilized as benchmarks in estimating the probabilistic distribution of business interruption losses, especially in the case of urban flood disasters.

     

Nitrogen, Oxygen and Argon Dissolved in the Northern North Pacific in Early Summer

Major gases dissolved in seawater were accurately determined with a shipboard gas chromatographic method. The standard deviations were 0.28, 0.34 and 0.36% for N₂, O₂ and Ar, respectively. The method was applied to water from the northwestern North Pacific Ocean collected in May to June 2000. We got 127 duplicate seawater samples from the surface 200 m layer at 11 stations. The O₂ concentrations obtained by this method agreed with those given by the Winkler method. All the seawater samples from the surface 200 m, especially those from the upper 30 m, were supersaturated with respect to atmospheric N₂ and Ar concentrations. In the topmost 30 m layer, the degrees of supersaturation in the inventory were 2.7–4.3% for N₂ (ΔN₂) and 1.7–2.6% for Ar (ΔAr), and their ratios, ΔN₂/ΔAr, ranged from 1.53 to 1.81. This supersaturation seems to be chiefly due to air bubbles injected into the water and dissolved due to the water pressure, because the N₂/Ar ratio of the air is around 2. The amounts of air bubbles dissolved in the upper 30 m water were relatively large, with mean value of 0.41 ml/kg or 18.4 μmol/kg. The ΔN₂, ΔAr and ΔN₂/ΔAr values were all positively well correlated with the wind velocities averaged for the last 24 hours prior to sampling, allowing the conclusion to be drawn that the weaker the wind velocity, the dissolved gas composition approaches in equilibrium with the air; while the stronger the wind velocity, it approaches in the air composition. This revised version was published online in July 2006 with corrections to the Cover Date.     

Factors regulating the distribution of elements in marine sediments predicted by a simulation model

The contents of oxyanionic elements (V, Se and Mo) and cationic transition metals (Mn, Fe, Co, Ni, Cu and Zn) in sediments from near-shore to deep-sea environments were measured to clarify factors regulating the distribution of these elements in marine sediments. For cationic transition metals of which contents increase from near-shore to deep-sea environments, the chemical composition of pelagic clays is modeled by a mixture of aluminosilicates having the chemical composition of average shale and Fe–Mn oxides having the chemical composition of associated manganese nodules. The content of V is fairly constant in sediments from near-shore to deep-sea areas. The mixture model of average shale and manganese nodules holds also for V, although most of the V is located in the aluminosilicate lattices. The content of Se in the near-shore sediments is higher and that in the deep-sea sediments is lower than that in average shale. The high content in the near-shore sediments is interpreted as the addition of biogenic materials to aluminosilicates with average shale composition and the low content in deep-sea sediments is explained by oxidative release of Se from aluminosilicates. The content of Mo in sediments increases from near-shore to deep-sea environments. The general distribution of Mo in marine sediments is expressed by the mixture model. An anomalously high content of Mo in a near-shore sediment is attributed to adsorption of molybdate on manganese oxides.     

Sedimentary records of multidecadal-scale variability of diatom productivity in the Bungo Channel, Japan, associated with the Pacific Decadal Oscillation

In order to examine the responses of primary productivity in the southern coastal sea of Japan to the Pacific Decadal Oscillation (PDO) in the 20th century, sedimentary records of diatom productivity (diatom valve fluxes) were reconstructed using core samples from the Bungo Channel (BC) in southwest Japan. The record of the Thalassionema spp. flux—the best index of fall primary productivity in the BC—indicated a multidecadal-scale duration with a low flux (1943–1982) and those with a high flux (1913–1943 and 1982–2001); apparent shifts were recognized in 1943 and 1982. The shift in 1982 was also recognized in the flux records of other early summer to fall predominant genera in the BC and, previously, in the biogenic silica records from a broad region of the southeast BC. This indicates that in our records, this shift reflects a general trend in the primary production in the southeast BC. A comparison among the Thalassionema spp. flux records, meteorological data from an observatory adjacent to the core site, and the PDO index showed that the flux records were more similar to the PDO index than the other meteorological records, which suggests that the multidecadal-scale variability of the BC primary productivity may be associated with some marine-derived forcing. The bottom intrusions of nutrient-rich water that upwelled from the shelf slope into the BC, the axis movement or the transport of the Kuroshio Current off the BC, and a basin-scale wind stress in the North Pacific might play an important role in this forcing and mediate between the BC primary productivity and the PDO.     

2-D and 3-D modelling of wide-angle seismic data: an example from the Vøring volcanic passive margin

This study presents the modelling of 2-D and 3-D wide-angle seismic data acquired on the complex, volcanic passive margin of the Vøring Plateau, off Norway. Three wide-angle seismic profiles were shot and recorded simultaneously by 21 Ocean Bottom Seismometers, yielding a comprehensive 3-D data set, in addition to the three in-line profiles. Coincident multi-channel seismic profiles are used to better constrain the modelling, but the Mesozoic and deeper structures are poorly imaged due to the presence of flood basalts and sills. Velocity modelling reveals an unexpectedly large 30 km basement high hidden below the flood basalt. When interpreted as a 2-D structure, this basement high produces a modelled gravity anomaly in disagreement with the observed gravity. However, both the gravity and the seismic data suggest that the structure varies in all three directions. The modelling of the entire 3-D set of travel times leads to a coherent velocity structure that confirms the basement high; it also shows that the abrupt transition to the slower Cretaceous basin coincides in position and orientation with the fault system forming the Rån Ridge. The positive gravity anomaly over the Rån Ridge originates from the focussed and coincident elevation of the high velocity lower crust and pre-Cretaceous basement. Although the Moho is not constrained by the seismic data, the gravity modelled from the 3-D velocity model shows a better fit along the profiles. This study illustrates the interest of a 3-D acquisition of wide-angle seismic over complex structures and the benefit of the subsequent integrated interpretation of the seismic and gravity data.     

Current structure and volume transport of the Soya Warm Current in summer

ADCP, CTD and XBT observations were conducted to investigate the current structure and temperature, salinity and density distributions in the Soya Warm Current (SWC) in August, 1998 and July, 2000. The ADCP observations clearly revealed the SWC along the Hokkaido coast, with a width of 30–35 km and an axis of maximum speed of 1.0 to 1.3 ms⁻¹, located at 20–25 km from the coast. The current speed gradually increased from the coast to a maximum and steeply decreased in the offshore direction. The SWC consisted of both barotropic and baroclinic components, and the existence of the baroclinic component was confirmed by both the density front near the current axis and vertical shear of the alongshore current. The baroclinic component strengthened the barotropic component in the upper layer near the axis of the SWC. The volume transport of the SWC was 1.2–1.3 SV in August, 1998 and about 1.5 SV and July, 2000, respectively. Of the total transport, 13 to 15% was taken up by the baroclinic component. A weak southeastward current was found off the SWC. It had barotropic characteristics, and is surmised to be a part of the East Sakhalin Current.     

Large but variable particulate flux in the Antarctic Ocean and its significance for the chemistry of Antarctic water

Settling particles were collected at 1,460 m and 3,760 m depth in the Antarctic Ocean with sediment traps of time series type. The total deployment period of 40 days was divided into four terms of 10 days each. Seawater samples were collected both at deployment and retrieval of the traps at each site. During the 42 days the concentration of silicate in the surface water decreased by 32%, whereas those of nitrate and phosphate decreased by only 4–5%. The total particulate flux in the Antarctic Ocean is the largest among those hitherto observed in the world ocean. The time variation of the particulate flux at 1,460 m depth almost coincided with that at 3,760 m. The settling particles were comprised roughly of 80% biogenic silica, 15% organic matter and 5% other substances including sea salt. The clay fraction was only 0.05% at 1,460 m depth. The settling flux of biogenic silica agrees fairly well with the calculated rate of change in the concentration of silicate in the surface 100 m. Thus it is concluded that preferential propagation of diatoms reduces the concentration of silicate prior to other nutrients in the Antarctic Ocean.