A possible Caledonide arm through the Barents Sea imaged by OBS data

The assembly of the crystalline basement of the western Barents Sea is related to the Caledonian orogeny during the Silurian. However, the development southeast of Svalbard is not well understood, as conventional seismic reflection data does not provide reliable mapping below the Permian sequence. A wide-angle seismic survey from 1998, conducted with ocean bottom seismometers in the northwestern Barents Sea, provides data that enables the identification and mapping of the depths to crystalline basement and Moho by ray tracing and inversion. The four profiles modeled show pre-Permian basins and highs with a configuration distinct from later Mesozoic structural elements. Several strong reflections from within the crystalline crust indicate an inhomogeneous basement terrain. Refractions from the top of the basement together with reflections from the Moho constrain the basement velocity to increase from 6.3 km s⁻¹ at the top to 6.6 km s⁻¹ at the base of the crust. On two profiles, the Moho deepens locally into root structures, which are associated with high top mantle velocities of 8.5 km s⁻¹. Combined P- and S-wave data indicate a mixed sand/clay/carbonate lithology for the sedimentary section, and a predominantly felsic to intermediate crystalline crust. In general, the top basement and Moho surfaces exhibit poor correlation with the observed gravity field, and the gravity models required high-density bodies in the basement and upper mantle to account for the positive gravity anomalies in the area. Comparisons with the Ural suture zone suggest that the Barents Sea data may be interpreted in terms of a proto-Caledonian subduction zone dipping to the southeast, with a crustal root representing remnant of the continental collision, and high mantle velocities and densities representing eclogitized oceanic crust. High-density bodies within the crystalline crust may be accreted island arc or oceanic terrain. The mapped trend of the suture resembles a previously published model of the Caledonian orogeny. This model postulates a separate branch extending into central parts of the Barents Sea coupled with the northerly trending Svalbard Caledonides, and a microcontinent consisting of Svalbard and northern parts of the Barents Sea independent of Laurentia and Baltica at the time. Later, compressional faulting within the suture zone apparently formed the Sentralbanken High.     

Organizations and the interior characteristics of winter monsoon clouds by dual-polarization Doppler radar observation in Hokuriku, Japan

To understand the characteristics of winter monsoon clouds, dual-polarization Doppler radar observations were carried out at Mihama, Hokuriku, Japan. A series of organized disturbances associated with the passage of a cyclonic circulation was analyzed. The following scenario was proposed. Environmental circumstances, for example, temperature and wind profiles, surface heat and moisture fluxes, etc., determine the organizational style of mesoscale convections. This organization regulates the convection interior flow pattern including the location and intensity of updrafts. Subsequently, it influences interior microphysical properties, for example, the types of precipitation particles, their growth and distributions, their electrification, etc. In this paper, an observational example following this scenario is presented.     

Ba, Si, U, Al, Sc, La, Th, C and C/C in a sediment core in the western subarctic Pacific as proxies of past biological production

A sediment core covering the last 145 kyrs was collected in the western subarctic Pacific (WSAP), and analyzed for Ba, U, Al, Sc, La, Yb, Th, biogenic opal (Opal) and organic carbon (C_org) as well as its isotopic ratio (δ¹³C). This study examined the change of past biological production in WSAP with multiple proxies, together with understanding the relation between Loess from the Asian continent and the biological production. The Loess content was estimated from the metal components, Al, Sc, La, Yb and Th. In this high latitude core (50°N), the Loess content was generally high during the glacial periods, but it was also high even in some interglacial periods. The excess amount of Ba relative to the detrital material composition, Ba_ex, showed the best correlation with the Vostok δD (r = 0.72, p < 0.001), indicating that the biological production was lower in the glacial periods than in the interglacials. This corroborates the pervasive correlation between Ba_ex in the polar region, WSAP and the Antarctic Sea, and Antarctic temperature, combined with previous research. This correlation might be explained by the stratification caused by cooling. In addition, the time variations of Ba_ex in WSAP were similar to those of Ba_ex in the Okhotsk Sea and of other proxies (C_org and Opal) in both the Okhotsk and the Bering Sea, indicating the spatial homogeneity of Ba_ex in WSAP including proximal marginal seas. The Opal content was more weakly correlated with the Vostok δD (r = 0.46, p < 0.001) than Ba_ex, reflecting that Opal in WSAP including proximal marginal seas was spatially heterogeneous compared to Ba_ex. While both the C_org content and U_ex, the excess amount of U relative to the detritus composition, were not positively correlated with the Vostok δD, they behaved similarly in the sediments. The positive correlation between δ¹³C and the Vostok δD (r = 0.42, p < 0.001), between δ¹³C and Ba_ex (r = 0.60, p < 0.001) and between δ¹³C and Opal (r = 0.36, p < 0.01) indicates that δ¹³C in WSAP may give some information on the phytoplankton growth rate. There was not a significant correlation between the spatially homogeneous Ba_ex in WSAP and Loess (r = − 0.16, p > 0.01), suggesting that the increase of biological production with the increase of Loess supply during the glacial periods did not occur.     

Temporal Change of Dissolved Inorganic Carbon in the Subsurface Water at Station KNOT (44°N, 155°E) in the Western North Pacific Subpolar Region

The dissolved inorganic carbon (DIC) and related chemical species have been measured from 1992 to 2001 at Station KNOT (44°N, 155°E) in the western North Pacific subpolar region. DIC (1.3∼2.3 µ mol/kg/yr) and apparent oxygen utilization (AOU, 0.7∼1.8 µmol/kg/yr) have increased while total alkalinity remained constant in the intermediate water (26.9∼27.3σ_θ). The increases of DIC in the upper intermediate water (26.9∼27.1σ_θ) were higher than those in the lower one (27.2∼ 27.3σ_θ). The temporal change of DIC would be controlled by the increase of anthropogenic CO₂, the decomposition of organic matter and the non-anthropogenic CO₂ absorbed at the region of intermediate water formation. We estimated the increase of anthropogenic CO₂ to be only 0.5∼0.7 µmol/kg/yr under equilibrium with the atmospheric CO₂ content. The effect of decomposition was estimated to be 0.8 ± 0.7 µmol/kg/yr from AOU increase. The remainder of non-anthropogenic CO₂ had increased by 0.6 ± 1.1 µmol/kg/yr. We suggest that the non-anthropogenic CO₂ increase is controlled by the accumulation of CO₂ liberated back to atmosphere at the region of intermediate water formation due to the decrease of difference between DIC in the winter mixed layer and DIC under equilibrium with the atmospheric CO₂ content, and the reduction of diapycnal vertical water exchange between mixed layer and pycnocline waters. In future, more accurate and longer time series data will be required to confirm our results.     

Photographic monitoring system for observing heavy free-falling objects: Multi-stage design packages of radioactive waste

In the consideration of safety it is required that packages containing radioactive wastes when dumped at sea should keep their integrity and retain their contents until they reach the seabed. Packages containing simulated radioactive wastes (non-radioactive) were tested by a free-fall method at depthsca. 4,300 m in an area for dumping industrial waste off Shikoku Island. Since the weight of the largest package was 4,300 kg, special attention was paid to the connection of a buoyancy system with mooring rope. Descent and ascent velocities of the free-fall system were calculated prior to the experiment. A free-fall experiment with an extremely heavy object, heavier than ever previously reported, was accomplished without trouble by using the free-fall system. Recovery of a camera, flash-light, and other components was successful in each of the three experiments. Successive photographing of the package during descent was made and its integrity was observed using the photographs taken by the recovered camera. The packages remained intact during descent and at least for a short time after arrival on the seabed.     

Tritium in the northwestern North Pacific

Vertical profiles of tritium in seawater were determined for samples collected during the period from 1988 to 1990 at fourteen stations in the northwestern North Pacific (the Oyashio region) including the Okhotsk Sea and the Bering Sea. The profiles usually had a maximum in the surface layer and decreased gradually with depth down to 1,000 m. The water column inventory of tritium averaged 63% of the total atmospheric input in this region.The horizontal distribution of tritium showed a maximum in the region facing the Okhotsk Sea near 45°N for every isopycnal surface of ₀ ranging from 26.60 to 27.40. The ages of the intermediate water were calculated for the respective isopycnal surfaces in the maximum region. This calculation assumed that the intermediate water was formed by the isopycnal mixing of two water masses—the Okhotsk Sea and the Bering Sea Component Waters, which had been produced in wintertime by the diapycnal mixing of the surface and the deep waters in the respective marginal seas. The results show that the intermediate water in this region was formed in the late 1980's for the water which has ₀ of 26.60 to 26.80 and about 1970 for the water which has ₀ of 27.00 to 27.40. Although we have estimated the mean ages of the intermediate water, the horizontal profile of dissolved oxygen suggests that the Okhotsk Sea Component Water is younger than the mean age.     

Different partitioning among thorium isotopes in seawater of the Northern North pacific

Each about 400 l of seawater sample was collected in the northern North Pacific and filtered through a membrane filter. Four radioisotopes of thorium,²³²Th,²³⁰Th,²²⁸Th and²³⁴Th, were determined for the two FractionsF (filtrate) andP (particles on the filter). In the percentages of FractionP in the subsurface water,²³⁰Th was significantly larger than other 3 isotopes, and²³²Th was significantly smaller than other 3 isotopes. The former finding can be explained by the slower rates in the reversible change between the FractionsF andP. The latter one, however, cannot be explained if thorium isotopes in the FractionF are truly dissolved with the same chemical form. This suggests that major part of the FractionF of²³²Th is not identical with those of other radiogenic thorium isotopes, and it should not be composed of simple dissolved ions. The removal of radiogenic²³⁴Th was related to the biological activity, but there was a deviation, between the FractionP and radioactivity deficiency of²³⁴Th in their vertical profiles. The deviation was similar to that between the chlorophylla and phaeo-pigments contents including their maximum depths.     

Observation of the Kyucho in the Bungo Channel by HF radar

Observations of sea surface currents by HF radar were carried out in the Bungo Channel in summer 1992. The current ellipses of M₂ constituent obtained by the observational results agree quite well with those obtained by the ADCP observations, showing that the accuracy of the HF radar measurements is of the same level as ADCP. The results revealed the current structures and their change with the Kyucho in detail. The Kyucho is influenced by the complicated coastal geometry and does not propagate straightly into the Bungo Channel. It propagates further inward after charging the coastal bays with warm water. The current directions change largely, since the currents turn around the stagnant region in the bay filled with the warm water. The northward intrusion begins to be weakened in the southern part of the channel, while it still persists in the northern part. The northward current speeds of the observed Kyucho are about 50 cm/s and sometimes attain 60 to 70 cm/s.     

Uranium in coastal sediments of Tokyo Bay and Funka Bay

The sediment cores from Tokyo Bay and Funka Bay were analyzed for U and its isotopic ratio,²³⁴U/²³⁸U, after dissolving them in 0.1 M HCl, and 30% H₂O₂ in 0.05 M HCl. A small fraction of U in the anoxic sediments was dissolved in 0.1M HCl and even the added yield tracer,²³²U, was lost. The isotopic ratio of H₂O₂ soluble U in the sediments was equal to that of seawater, suggesting that the H₂O₂ soluble U in the sediments is authigenic. The 6M HCl solution dissolved part of the lithogenic U besides the authigenic U. The depth profiles of U from the two bays resembled each other. The authigenic U comprised more than half of the total U even at the surface and increased with depth down to 70 cm, showing small maxima at about 20 cm. The concentration of refractory U was nearly constant with depth and similar to that of the pelagic sediments. The highest U concentration, 6 µg g^–1 which was about 5 times that of the pelagic sediments, was observed in the layer between 70 and 160 cm depth in Tokyo Bay. The annual sedimentation rates of U in the Tokyo Bay sediments were 2.6 tons at the surface and 7.0 tons at the 70–160 cm depth. The increase in U with depth should be due to the deposition of interstitial U either diffusing downward from the surface indicating the trapping of seawater U, or otherwise diffusing upward from the deeper layer indicating the internal cycling of U within the sediments.     

A practical method for the simultaneous determination of234Th,226Ra,210Pb and210Po in seawater

A practical method has been developed for the simultaneous determination of²²⁶Ra,²³⁴Th,²¹⁰Pb and²¹⁰Po in seawater. In the method, the samples are spiked with²²⁸Ra,²³⁰Th,²⁰⁸Po and common lead to determine chemical yield. These nuclides are coprecipitated with calcium carbonate and ferric hydroxide from 20 to 50 l of seawater and separated from one another by using coprecipitation and ion exchange techniques. Counting sources of Ra and the other nuclides are prepared by electrodeposition onto silver discs. Their radioactivities are counted with an-spectrometer and a low background-counter. This method gives a standard deviation of about 5% for replicate determination of²²⁶Ra and the other nuclides.