Adsorption—desorption control of phosphate in anoxic sediment of a coastal sea,Funka Bay,Japan

Sediment core samples were taken once a month from July 1980 to September 1981 at a station in Funka Bay (92-m depth) for the determination of phosphate, silicate and alkalinity in interstitial water. A remarkable seasonal variation was found for interstitial phosphate, that is, distinct maxima appeared in spring (March—April), just after a phytoplankton bloom which brought a large amount of settling particles to the bottom, and in summer (July—August) when the water was stratified and the dissolved oxygen content of the bottom water decreased due to the decomposition of organic matter. The high interstitial phosphate concentration was always accompanied by a sharp increase in alkalinity, indicating sulfate reduction. This large seasonal variation in interstitial phosphate cannot be explained by in situ decomposition of organic matter and/or the diffusive loss of interstitial phosphate. A more likely explanation is adsorption and desorption of interstitial phosphate coincident with the depth of the active sulfate reduction layer.     

Thermal expansion of fayalite,Fe2SiO4

Thermal expansion of single-crystal fayalite has been measured by a dilatometric method at temperatures between 25 °C and 850 °C. The results show the presence of anomalous expansion in the b axis, which is correlated to the anomalous variation of elastic moduli with temperature. Grüneisen's parameter is 1.10 and the thermal Debye temperature is 565 K, which is close to the acoustic Debye temperature of 511 K.     

226Ra, 210Pb and 210Po disequilibria in the Western North Pacific

²²⁶Ra,²¹⁰Pb and²¹⁰Po were measured in oceanic profiles at two stations near the Bonin and Kurile trenches.²¹⁰Po is depleted by 50% on average relative to²¹⁰Pb in the surface water. In the deep water,²¹⁰Pb is about 25% deficient relative to²²⁶Ra. Based on the deficiency,²¹⁰Pb residence time with respect to removal by particulate matter was estimated to be less than 96 years in the deep water.²¹⁰Pb deficiency in the bottom water was significantly greater than that of the adjacent deep water, indicating more effective removal near or at the bottom interface.²¹⁰Pb,²¹⁰Po and Th appear to have similar overall rate constants of particulate removal throughout the water column.     

Direct observation of Cm(III)-fulvate species on fulvic acid-montmorillonite hybrid by laser-induced fluorescence spectroscopy

Particulate matter plays an important role in the removal of metal ions from water in natural aquifers. Some of the most important of these materials consist of associations of inorganic particles (clay minerals, oxides) with humic substances, associations that can form readily in such an environment due to the strong affinity between inorganic particles and humic substances. These associations are referred to in this paper as organic-inorganic hybrids. However, it is not clear whether the sorbed species of metal ions in such organic-inorganic hybrids are organic or inorganic species because of the complexity of such hybrids and the lack of appropriate methods for characterizing the trace metal ions incorporated in them. In this study, laser-induced fluorescence spectroscopy (LIF) was used successfully to characterize the Cm(III) species on an FA(fulvic acid)-montmorillonite hybrid, an example of such organic-inorganic hybrids. The LIF clearly showed that Cm(III) can be sorbed as Cm(III)-fulvate complex in the FA-montmorillonite hybrid. These results were consistent with those of experiments of solid-water partitioning of Cm(III) (or Eu(III) used as an analogue) and speciation calculations based on the stability constants of Cm(III)-fulvate complexes determined in this study. The results of LIF and the partitioning experiments showed that the solid-water distribution of humic substances governed that of Cm(III) under our experimental conditions. The Cm(III) preference for forming Cm(III)-fulvate complexes was also evident under a condition that would be found in a natural aquifer with a fairly low concentration of organic matter in freshwater (dissolved organic carbon: 2 mg/dm³), as determined by our speciation calculations. These findings on the importance of humic substances in the migration of Cm(III) indicate that the clarification of the environmental behavior of humic substances is necessary to understand fully the behavior of Cm(III), or actinide(III) and lanthanide(III) ions, in natural aquifers.     

Reconstruction of a climate record for the past 140 kyr based on diatom valve flux data from Lake Biwa, Japan

To reconstruct the pattern of past climate change in central Japan during the last 140 kyr, total planktonic diatom valve concentrations (valves g^–1) and fluxes (valves cm^–2 year^–1) of total planktonic diatoms flux (PVF) and individual species were examined using a 140-m core taken from Lake Biwa, Shiga Prefecture. Most records had a sample resolution between approximately 150 and 300 yr. Based on characteristics of past and modern diatom responses to possible climate variables, we interpreted changes in Stephanodiscus suzukii flux (SVF) to reflect changes in phosphorus levels, which reflect, in turn, summer precipitation levels; changes in Aulacoseiva nipponica flux (AVF) reflect winter vertical lake-water mixing induced by winter temperatures and snowfall levels. Thus, changes in total planktonic diatom flux reflect a combination of summer precipitation, winter temperature, and snowfall values. During the 140–101 ka interval, changes in S. suzukii productivity at a millennial timescale may correspond to changes in summer rainfall in central Japan. The disappearance of A. nipponica during the same period could indicate weaker vertical mixing, possibly caused by increased temperatures and decreased snowfall levels in winter. During the 101–70 ka interval, the AVF record shows levels near or above those observed in present times, indicating that winter water temperatures fell within the optimal range for A. nipponica to prosper. Generally low AVF values during the 70–7 ka interval indicate weak winter vertical mixing and cold winters. The many intervals with low PVF values during the same period suggest decreased summer precipitation levels. Between 7 and 0 ka, PVF, SVF, and AVF records show levels near or above those of the present, suggesting winter temperatures favorable for A. nipponica growth, and snowfall and summer precipitation levels probably similar to or above those currently recorded.     

Seasonal variation of atmospheric 210Pb and Al in the western North Pacific region

The atmospheric concentration of ²¹⁰Pb was determined for two years at six stations in the western North Pacific region. The following results were obtained and discussed by comparing them with those of Al. The atmospheric concentration of ²¹⁰Pb varied widely from week to week, but the degree of variation was about a half that of Al. Contrary to Al, the year-to-year variation of ²¹⁰Pb was not pronounced and its seasonal variation was well expressed by a sine curve. The ²¹⁰Pb concentration did not show a marked latitudinal variation and its base-line concentration was high in the surface air over the North Pacific. These suggest that atmospheric ²¹⁰Pb has a longer residence time, due to its transportation through higher altitudes and deposits much more evenly onto the Earth's surface and the ocean, as compared with Al in mineral dust which is larger in size in the source region.     

Simulation analysis of ground liquefaction induced by earthquake

A dynamic effective stress analysis with the finite element method has long been recommended to predict the liquefaction phenomena of sandy soil by authors and Zienkiewicz et al. as well as the similar approaches by the others. Our approach of the analysis is summarized in the first.

Until recently, however, these approaches has not commonly been used as the means of design, although its capability of prediction is appreciated by geotechnicians. This method has been neglected because of the lack of verification studies of soil models of sand and mathematical formulation for boundary problems of liquefaction phenomena. Therefore the verification of the numerical method to evaluate liquefaction potential are urgent requirement of the recent engineering practice. To respond this requirement, extensive numerical studies on the liquefation simulations are performed by DIANA program for shaking table tests which have been conducted by the authors. The test models are soil-structure type models with combination of homogenous ground and partially improved ground by compaction.

The good performance of our approach is proved by the results of numerical simulation showing good agreement with experimental data in terms of response acceleration, excess pore pressure, and deformation profile. It is also demonstrated that the numerical results can provide substantial information to understand the mechanisms of soil ground behavior which is not easily obtained by experiments.

The procedure to identify soil constants for the reflecting surface model is also reported in details.     

The characterization and distribution of aerosol and gaseous species in the winter monsoon over the western pacific ocean

During the winters of 1981 and 1982, measurements were taken on two Japanese islands of the aerosol and gaseous species which had been carried by northwesterly monsoons over the Pacific Ocean. The aerosols were characterized as sea-salt particles; soil particles, and as particles of sulfate, nitrate, organics and elemental carbon. At Chichi-jima island, which is about 800 km away from the main islands of Japan, it was found that the level of the anthropogenic components of the aerosols was considerably higher than their background level. The mean concentrations of the species on the islands are given in tabular forms. According to a survey made on board a ferry boat, the aerosol and gaseous species were fairly uniformly distributed along the southern coast of the main Japanese islands.     

Ra in the Japan Sea and the residence time of the Japan Sea water

The surface water of the Japan Sea contained²²⁶Ra of70 ± 4dpm m⁻³ which was nearly equal to that of the surface water in the North Pacific. The concentration of²²⁶Ra in the Japan Sea deep water below 500 m was151 ± 8dpm m⁻³, showing a vertically and regionally small variation. This concentration of²²⁶Ra in the deep water is unexpectedly high, because the Japan Sea deep water has a higher Δ¹⁴ C value by about 50‰ than the Atlantic deep water containing the same²²⁶Ra. One of the causes to be considered is larger contribution of²²⁶Ra from biogenic particles dissolving in the Japan Sea deep water, but the Japan Sea is not so fertile in comparison to the Bering Sea. The other more plausible cause is the internal ventilation of the Japan Sea water, which means that the residence time of the Japan Sea Proper water is considerably long although the water is vertically mixed fairly well especially in winter. The ventilation may supply some amounts of radiocarbon and oxygen but does not change the inventory of²²⁶Ra. The residence times of the Japan Sea deep water and of water within the Japan Sea are calculated by solving simultaneous equations for²²⁶Ra and¹⁴C with a three-box model to be 300–400 years and 700–1000 years, respectively.     

Iterative deconvolution of complex body waves from great earthquakes—the Tokachi-Oki earthquake of 1968

A method of body-wave inversion is developed in an attempt to extract the information about asperities or barriers in a fault zone. A sequence of point sources, each being characterized with the seismic moment, the onset time and the location, are iteratively derived from observed records at multi-stations, where the two-dimensional extent of the source location is taken into account. A modification is made of the iterative method of Kikuchi and Kanamori on the formulation of inversion procedure to facilitate the computation.Using this method, we analyse long period P waves of the Tokachi-Oki earthquake of 1968 (M_w = 8.2) and obtain several significant subevents with time durations of ～ 10 s. Their spatio-temporal distribution shows that the rupture process consists of three characteristic stages: (A) a stage of introductory rupture, (B) a stage of main rupture and (C) a stage of aftershocks. The main rupture takes place in the form of clustering around a few sites of the fault plane. The largest subevent occurs in the northwestern corner. The stress drop associated with this event is estimated to be ～ 200 bars, one order of magnitude higher than the stress drop averaged over the entire fault plane. The sum of the seismic moments of the individual subevents amounts to 2.3 × 10²⁸ dyn. cm which approximately coincides with the one estimated from the analysis of long-period surface waves. This implies that the source of the Tokachi-Oki earthquake consists of several major subevents with time durations of ～ 10 s in addition to other minor subevents.