Spatial variability of chemical tracers in surface snow along the traverse route from the coast to 1000 km inland at east Dronning Maud Land, Antarctica

1　IntroductionAntarcticicesheetisaburialgroundforatmosphericdeposition .Sincethereiscon tinuousinteractionbetweentheicesheetandtheatmosphere,variousatmosphericsub stancesareinjectedtotheicesheetsequentiallyintimeandspace.Therefore,verticalanalysesoftheicesheetprovideuswithinformationaboutpastclimaticchange (Delmas1 992 ;LegrandandMayewski 1 997)andhorizontalanalysesoftheicesheetprovideuswithknowledgeregardinglong rangetransportofairbornematerials (Kamiyamaetal.1 989;KreutzandMayewski 1 999)…     

Simulations of an isotopic fractionation by freezing in an open system

1　IntroductionBasaliceofglaciersandicesheetshasbeenwidelystudiedtounderstandtheinacces sibleice bedinterface (e.g.,Lawson 1 979;Gowetal.1 979;Knight 1 994;HubbardandSharp 1 995 ,Souchez1 988) .Useofstableisotopesofbasaliceisasuperiormethodtodeterminewhetherthebasalicewasformedbymelt refreezingornon meltingattheinlandbaseofglaciersandicesheets.Inatheoreticalstudyofstableisotopes,JouzelandSouchez ( 1 982 )showedthatforaclosedsystem ,wherenowaterisinputoroutput,theslopegradientdefinedbyδ18O…     

Semi-brittle behavior of wet olivine aggregates: the role of aqueous fluid in faulting at upper mantle pressures

The role of aqueous fluid in fracturing in subducting slabs was investigated through a series of deformation experiments on dunite that was undersaturated (i.e., fluid-free) or saturated with water (i.e., aqueous-fluid bearing) at pressures of 1.0–1.8 GPa and temperatures of 670–1250 K, corresponding to the conditions of the shallower regions of the double seismic zone in slabs. In situ X-ray diffraction, radiography, and acoustic emissions (AEs) monitoring demonstrated that semi-brittle flow associated with AEs was dominant and the creep/failure strength of dunite was insensitive to the dissolved water content in olivine. In contrast, aqueous fluid drastically decreased the creep/failure strength of dunite (up to ~?1 GPa of weakening) over a wide range of temperatures in the semi-brittle regime. Weakening of the dunite by the aqueous fluid resulted in the reduction of the number of AE events (i.e., suppression of microcracking) and shortening of time to failure. The AE hypocenters were located at the margin of the deforming sample while the interior of the faulted sample was aseismic (i.e., aseismic semi-brittle flow) under water-saturated conditions. A faulting (slip rate of ~?10^?3 to 10^?4 s^?1) associated with a large drop of stress (Δσ?~?0.5 to 1 GPa) and/or pressure (ΔP?~?0.5 GPa) was dominant in fluid-free dunite, while a slow faulting (slip rate?<?8?×?10^?5 s^?1) without any stress/pressure drop was common in water-saturated dunite. Aseismic semi-brittle flow may mimic silent ductile flow under water-saturated conditions in subducting slabs.     

Multi-decadal changes in the relationships between rainfall characteristics and debris-flow occurrences in response to gully evolution after the 1990–1995 Mount Unzen eruptions

Explosive volcanic eruptions can cause long-term landscape change, leading to increased sediment discharge that continues after the cessation of the eruptions. During the period 1990–1995, eruptions of Mount Unzen, Japan, generated large amounts of pyroclastic material, resulting in 57 debris-flow events during 1991–2018. To investigate changes in the relationships between rainfall characteristics and debris-flow occurrence, we conducted the following: geometric analysis of two gullies (i.e., debris-flow initiation zones) using LiDAR (light detection and ranging)-generated 1 m DEMs (digital elevation models); rainfall analysis, based on the relationship between rainfall duration and mean intensity (i.e., considering the intensity–duration, or ID, threshold); and debris-flow monitoring during 2016–2018. Since 1991, rainfall runoff has caused erosion of the supplied pyroclastic material, generating a channel network consisting of incised gullies. With sufficient rainfall, debris flows formed, accompanied by further gully erosion; this resulted in both vertical and lateral adjustments of the cross-sectional geometry. In the two decades since the eruptions ceased, readily mobilized pyroclastic material has become scarce as the gullies have adjusted to local hydrographic conditions. At the same time, the infiltration capacity of the volcanic flank has increased, reducing the capacity for overland flow. As a result, since 2000, rainfall events with intensities above the ID threshold have occurred; however, the lack of sediment supplied by the gullies appears to have hindered the occurrence and development of debris flows. This suggests that debris flows in volcanically perturbed landscapes may occur at lower rainfall thresholds as long as the corresponding upland channels are evolving as a result of intense overland flow. However, as such channels evolve towards equilibrium geometries, the frequency of debris flows decreases in response to the reduction in sediment availability.     

Wave Dispersion Study in the Indian Ocean-Tsunami of December 26, 2004

A numerical study which takes into account wave dispersion effects has been carried out in the Indian Ocean to reproduce the initial stage of wave propagation of the tsunami event that occurred on December 26, 2004. Three different numerical models have been used: the nonlinear shallow water (nondispersive), the nonlinear Boussinesq, and the full Navier-Stokes aided by the volume of fluid method to track the free surface. Numerical model results are compared against each other. General features of the wave propagation agreed very well in all numerical studies. However some important differences are observed in the wave patterns, i.e., the development in time of the wave front is shown to be strongly connected to the dispersion effects. Discussions and conclusions are made about the spatial and temporal distribution of the free surface reaffirming that the dispersion mechanism is important for tsunami hazard mitigation.     

Three-dimensional finite strain analysis in the high-grade part of the Sanbagawa Belt using deformed meta-conglomerate

Abstract   Regional ductile deformation of the Sanbagawa belt is generally thought to be characterized by constrictional strain, based on strain analysis using deformed radiolarians in the low-grade regions. Similar strain analysis could not be carried out in the medium- to high-grade zones, because it is very difficult to identify individual radiolarians after strong recrystallization. However, discovery of the first known meta-conglomerate in the high-grade region of the Sanbagawa Belt allows quantitative 3-D strain to be estimated in this region. Using a development of the Rf-φ method, an evaluation of appropriate errors for this estimate can be determined. The principal strain ratios and estimated errors are X/Y = 5.4–6.6 and Y/Z = 3.8–3.9 implying deformation in the flattening field and refuting the idea of uniform constrictional strain. Semi-quantitative markers of the shape of the strain ellipse throughout the high-grade regions suggest that the deformation of the Sanbagawa Belt is dominantly in the flattening field. The difference with the earlier results may be due to late-stage overprinting by upright folding of the main ductile fabric in the low-grade region of western Shikoku.     

Laboratory Experiment of Plasma Flow Around Magnetic Sail

To propel a spacecraft in the direction leaving the Sun, a magnetic sail (MagSail) blocks the hypersonic solar wind plasma flow by an artificial magnetic field. In order to simulate the interaction between the solar wind and the artificially deployed magnetic field produced around a magnetic sail spacecraft, a laboratory simulator was designed and constructed inside a space chamber. As a solar wind simulator, a high-power magnetoplasmadynamic arcjet is operated in a quasisteady mode of 0.8 ms duration. It can generate a simulated solar wind that is a high-speed (above 20 km/s), high-density (10¹⁸ m⁻³) hydrogen plasma plume of ∼0.7 m in diameter. A small coil (2 cm in diameter), which is to simulate a magnetic sail spacecraft and can obtain 1.9-T magnetic field strength at its center, was immersed inside the simulated solar wind. Using these devices, the formation of a magnetic cavity (∼8 cm in radius) was observed around the coil, which indicates successful simulation of the plasma flow of a MagSail in the laboratory.     

Seismic response estimation method for earthquake‐damaged RC buildings

This study proposes a procedure for identifying spectral response curves for earthquake‐damaged areas in developing countries without seismic records. An earthquake‐damaged reinforced concrete building located in Padang, Indonesia was selected to illustrate the identification of the maximum seismic response during the 2009 West Sumatra earthquake. This paper summarizes the damage incurred by the building; the majority of the damage was observed in the third story in the span direction. The damage was quantitatively evaluated using the damage index R according to the Japanese guidelines for post‐earthquake damage evaluation. The damage index was also applied to the proposed spectral response identification method. The seismic performance of the building was evaluated by a nonlinear static analysis. The analytical results reproduced a drift concentration in the third story. The R‐index decreased with an increase in the story drift, which provided an estimation of the maximum response of the building during the earthquake. The estimation was verified via an earthquake response analysis of the building using ground acceleration data, which were simulated based on acceleration records of engineering bedrock that considered site amplification. The maximum response estimated by the R‐index was consistent with the maximum response obtained from the earthquake response analysis. Therefore, the proposed method enables the construction of spectral response curves by integrating the identification results for the maximum responses in a number of earthquake‐damaged buildings despite a lack of seismic records. Copyright © 2016 The Authors. Earthquake Engineering & Structural Dynamics published by John Wiley & Sons Ltd.     

Simultaneous Analysis of Natural Free Estrogens and Their Conjugates in Wastewater by GC‐MS

A solid‐phase extraction (SPE)‐gas chromatography (GC)‐mass spectrometry (MS) analytical method was developed for the simultaneous analysis of natural free estrogens and their conjugates in wastewater samples. Natural free estrogens and their conjugates in wastewater were successfully separated by the oasis hydrophilic‐lipophilic balance solid phase extraction (Oasis HLB SPE) method, and the conjugates were initially enzyme hydrolyzed by β‐glucuronidase or arylsulfatase from Helix pomatia prior to derivatization. N‐methyl‐N‐(tert‐butyldimethylsilyl)trifluoroacetamide (MTBSTFA) plus 1% tert‐butyldimetheylchlorosilane (TBDMCS) was chosen as the derivatization reagent, and the most appropriate conditions of derivatization were determined to be at 95°C for 90 min. The recovery ratios of nine target chemicals were determined by spiking them in 1 L of ultra‐purified water or the influent of a wastewater treatment plant (WWTP). The recovery ratios of six out of nine for the analytes ranged from 73.3–114.9% with relative standard deviations (RSD) from 1.6–19.9%. The established method was successfully applied to environmental wastewater samples which were collected from one municipal wastewater treatment plant (WWTP) in Osaka, Japan, for the determination of natural free estrogens and their conjugates. In the influent sample, E1, E2, E1‐3S, E3‐3S, and E1‐3G were detected at concentrations of 16.6, 9.6, 8.2, 21.9, and 3.2 ng L^–1, respectively. However, only E1 was detected at a high concentration of 44 ng L^–1 in the effluent sample, suggesting that it is the dominant natural free estrogen in the effluent.     

Simultaneous Analysis of Natural Free Estrogens and Their Sulfate Conjugates in Wastewater

Natural estrogens from humans increasingly attract attention because of their strong endocrine disrupting potency. The discharge of sewage water is considered as the most important source of these endocrine disrupting chemicals (EDCs) in the environment. Therefore, a GC‐MS method was developed for the simultaneous analysis of six natural free estrogens and their sulfate conjugates in municipal wastewater, in which natural free estrogens and sulfate conjugates were successfully separated from an Oasis HLB solid phase extraction (SPE) cartridge with two different eluents, and the sulfate conjugates were then transformed to their corresponding free estrogens by acid solvolysis. Before the analysis with GC‐MS, samples were derivatized by N,O‐bis (trimethylsilyl) trifluoroacetamide (BSTFA) plus 1% trimethylchlorosilane (TMCS) at 80°C for 40 min. Satisfactory recoveries ranging from 64 to 112.3% were obtained by spiking ultra‐purified water, raw, and treated municipal wastewater with the six estrogens at 50, 100, and 50 ng/L, respectively. The method was successfully applied to wastewater samples from one WWTP, which suggested that E1 was the dominant natural estrogens in effluent and E3‐3S was one of the conjugates possibly occurring in the effluent.