Chemical and Isotopic Characteristics of the Kuroko‐Forming Volcanism

The Miocene northeast Honshu magmatic arc, Japan, formed at a terrestrial continental margin via a stage of spreading in a back‐arc basin (23–17 Ma) followed by multiple stages of submarine rifting (19–13 Ma). The Kuroko deposits formed during this period, with most forming during the youngest rifting stage. The mode of magma eruption changed from submarine basalt lava flows during back‐arc basin spreading to submarine bimodal basalt lava flows and abundant rhyolitic effusive rocks during the rifting stage. The basalts produced during the stage of back‐arc basin spreading are geochemically similar to mid‐ocean ridge basalt, with a depleted Sr–Nd mantle source, whereas those produced during the rifting stage possess arc signatures with an enriched mantle source. The Nb/Zr ratios of the volcanic rocks show an increase over time, indicating a temporal increase in the fertility of the source. The Nb/Zr ratios are similar in basalts and rhyolites from a given rift zone, whereas the Nd isotopic compositions of the rhyolites are less radiogenic than those of the basalts. These data suggest that the rhyolites were derived from a basaltic magma via crystal fractionation and crustal assimilation. The rhyolites associated with the Kuroko deposits are aphyric and have higher concentrations of incompatible elements than do post‐Kuroko quartz‐phyric rhyolites. These observations suggest that the aphyric rhyolite magma was derived from a relatively deep magma chamber with strong fractional crystallization. Almost all of the Kuroko deposits formed in close temporal relation to the aphyric rhyolite indicating a genetic link between the Kuroko deposits and highly differentiated rhyolitic magma.     

Verification of Carbon Sink Assessment: Can We Exclude Natural Sinks?

Any human-induced terrestrial sink is susceptible to the effects of elevated atmospheric CO₂ concentration, nitrogen deposition, climate variability and other natural or indirect human-induced factors. It has been suggested in climate negotiations that the effects of these factors should be excluded from estimates of carbon sequestration used to meet the emission reduction commitments under the Kyoto Protocol. This paper focuses on the methodologies for factoring out the effects of atmospheric and climate variability/change. We estimate the relative magnitude of the non-human induced effects by using two biosphere models and discuss possibilities for narrowing estimate uncertainty.     

Impacts of absorbing aerosols on South Asian rainfall

Anthropogenic aerosols in the lower troposphere increase the absorption and scattering of solar radiation by air and clouds, causing a warmer atmosphere and a cooler surface. It is suspected that these effects contribute to slow down the hydrological cycle. We conducted a series of numerical experiments using a limited area atmospheric model to understand the impacts of aerosol radiative forcing on the rainfall process. Experiments with different radiative conditions under an idealized setting revealed that increasing atmospheric forcing and decreasing surface forcing of radiation causes reductions in rainfall. There was no relationship of top of the atmosphere forcing to the rainfall yield. The model was then used to simulate a domain covering southern part of Sri Lanka, over for the period from November 2002 to July 2003. For a given radiative forcing, instances with lower rainfall yields showed larger fractional reductions in rainfall. The trends in seasonal rainfall observed over the site in past 30 years in a different study confirms this finding. We conclude that the negative impact of increase of anthropogenic aerosols on rainfall would be more severe on regions and seasons with lower rainfall yields. The consequences of this problem on the industries that critically depend on well-distributed rainfall like non-irrigated agriculture and on the general livelihood of societies in low-rain areas can be serious.     

Geochemical and Grain-Sized Implications for Provenance Variations of the Central Yellow Sea Muddy Area Since the Middle Holocene

Based on high-resolution analysis to a 280-cm long sediment core obtained from the muddy area in the central Yellow Sea, we examined the provenance of muddy sediments and discussed the changing marine sedimentary environment since the middle Holocene. The results indicated that fine-grained sediments in the muddy area were mainly derived from the Huanghe(Yellow River) and Changjiang(Yangtze River) with considerable stepwise variations during the past 6.6 kyr. The Yellow Sea Warm Current was initiated at 6 kyr when the sea level was high together with the enhanced East Asian Winter Monsoon. These in combination established the framework of shelf circulation in the Yellow Sea that began to trap the river-derived fine-grained sediments. From 4.9 kyr to 2.8 kyr, both the Kushiro Current and East Asian Monsoon were significantly weakened, reducing the delivery of Changjiang sediments to the muddy area. As a result, the sediments were mainly originated from the Huanghe. From 2.8 kyr to 1.5 kyr the continuously weakened East Asian Winter Monsoon and enhanced Yellow Sea Warm Current entrapped more fine-grain sediments. Whereas the enhanced East Asian Winter Monsoon and the human caused increase in sediment load of the Huanghe since 1.5 kyr, and direct delivery of Huanghe sediments to the Yellow Sea during 1128–1855 AD might dominated the sedimentation in the study area. The stepwise variations of the sediment provenance and composition of the Central Yellow Sea muddy sediments are of importance to understanding the formation of muddy deposit in the central Yellow Sea and the associated variations of marine environment since the middle Holocene.     

Sedimentation rates and heavy metals in a macrotidal salt marsh: Bay of Fundy,Canada

Macrotidal salt marshes play an important role in sedimentary processes in estuaries and can act as a sink for fine sediments and contaminants. This study examines sedimentation rates and the history of heavy metal accumulation in the Allen Creek salt marsh in the Bay of Fundy, Canada. Pb-210 and Cs-137 measurements and accelerated mass spectrometer (AMS) dating indicate a sedimentation rate of about 1.1 cm/year, which is consistent with independent observations. Elevated normalized concentrations of As in the upper section of the deposit may reflect an increase in organic matter content while a consistent decrease in Mn toward the surface of the section may be due to a decrease in natural supply. A peak in metal concentrations in the early to mid twentieth century is attributed to inputs from local foundries.     

Modern sediment characteristics and accumulation rates from the delta front to prodelta of the Yellow River (Huanghe)

Since 1976, the main channel of the Yellow River (Huanghe) has been on the east side of the delta complex, and the river has prograded a broad new delta lobe in Laizhou Bay of the Bohai Sea. In 2012, extensive bathymetric and high-resolution seismic profiles were conducted and sediment cores were collected off the new delta lobe. This study examined delta sedimentation and morphology along a profile across the modern subaqueous Yellow River delta and into Laizhou Bay, by analyzing sediment radionuclides (¹³⁷Cs, ²¹⁰Pb and ⁷Be), sedimentary structure, grain-size composition, organic carbon content, and morphological changes between 1976 and 2012. The change in the bathymetric profile, longitudinal to the river’s course, reveals subaqueous delta progradation during this period. The subbottom boundary between the new delta lobe sediment and the older seafloor sediment (before the 1976 course shift) was identified in terms of lithology and radionuclide distributions, and recognized as a downlap surface in the seismic record. The accumulation rate of the new delta lobe sediment is estimated to be 5–18.6 cm year^–1 on the delta front slope, 2 cm year^–1 at the toe of the slope, and 1–2 cm year^–1 in the shelf areas of Laizhou Bay. Sediment facies also change offshore, from alternations of gray and brown sediment in the proximal area to gray bioturbated fine sediment in the distal area. Based on ⁷Be distribution, the shorter-term deposition rate was at least 20 cm year^–1 in the delta front.     

Abundance and biomass of scyphomedusae, Aurelia aurita and Chrysaora melanaster, and Ctenophora, Bolinopsis mikado, with estimates of their feeding impact on zooplankton in Tokyo Bay, Japan

The abundance of a scyphomedusae, Aurelia aurita and Chrysaora melanaster, and a ctenophore, Bolinopsis mikado, in Tokyo Bay was investigated from 1995 to 1997. Aurelia aurita appeared throughout the year with a peak in abundance occurring from spring to summer. The average abundance and biomass during this period for the three successive years was 4.8, 43.8 and 3.2 ind. m⁻², and 1.02, 10.0 and 0.42 gC m⁻², respectively. The values in 1995 and 1997 were comparable with those previously reported for A. aurita abundance from 1990 to 1992. Values were very high in 1996, but the size composition of the bell diameter did not differ from other years, which suggested the absence of food limitation for A. aurita in 1996. C. melanaster was scarce over the survey period (<1.0 ind. m⁻²) while Bolinopsis mikado was more abundant during September to December, with maximum values of 172 ind. m⁻² and 0.33 gC m⁻² observed in December 1997. The weight-specific clearance rate for A. aurita on zooplankton (mainly copepods and their nauplii) was 0.16 ± 0.05 lgWW⁻¹ h⁻¹ (n = 13). Population clearance rate peaked from spring to summer, with average levels of 14.2%, 162% and 5.0% day⁻¹ obtained from spring to summer for respective years. Population clearance rates for B. mikado, calculated based on minimum carbon requirements, was 7.1% day⁻¹ in December 1997. Consequently, the trophic role of gelatinous zooplankton as predators in Tokyo Bay is important all the year round, considering the high impact of A. aurita from spring to summer and B. mikado from autumn to winter.     

Internal characteristics and numerical analysis of plunging breaker on a slope

Many investigations about the direct measurements of velocities to clarify the internal mechanism of the breaker have been carried out as a result of recent progress in the measuring techniques.This research attempts to clarify the breaking wave transformation system on a slope by an experiment and numerical analysis. In an experiment, the velocities in the surf zone were measured directly using an electromagnetic current meter, and the space distribution characteristic of the vorticity ω = (∂u/∂y − ∂u/∂x) and the skewness γ = (∂u/∂y + ∂u/∂x) were examined. Also, occurrence situations of the vortices at the time of water mass inrush were measured by video tape recorder (VTR) image processing. However, because the breaker is a violent phenomenon that is entrained with plentiful bubbles, the extent to which we can clarify breaker transformation in experiments is limited. Numerical simulations are substituted for experiments as a method to clarify breaker transformation.In numerical analysis, finite amplitude wave analysis based on the potential theory (non-viscous fluid) is possible before wave breaking; however, the analysis must take into account the viscous fluid after breaking. So, we use the Reynolds equations to develop a numerical simulation system of the breaker transformation on a sloping bottom. The numerical energy dissipation model of the breaker was compared to the experimental results, and a modified Simplified Marker and Cell (SMAC) method is presented. The internal characteristics of the breaker transformation are described using application examples.     

Organic geochemistry of the Japan Sea sediments-1: Bulk organic matter and hydrocarbon analyses of Core KH-79-3, C-3 from the Oki Ridge for paleoenvironment assessments

Organic geochemical study of bulk organic matter (OM), hopanoid hydrocarbon and normal hydrocarbon (C₂₃C₃₅) was conducted for a 936-cm-long sediment core sample from the Oki Ridge of the Japan Sea (Core KH-79-3, C-3; 37°03.5 N, 134°42.6E, water depth 935 m). Stable carbon isotopic ratios were also measured for both bulk OM and individual hydrocarbons. The following results were obtained: (1) The weight ratios of total organic carbon to total nitrogen range from 6.2 to 9.4 in the core. The ¹³C values of bulk OM range from –25.1–20.7%.. The ¹³C values of OM in the sections of 140190 cm are lower (–25–24) than those in the other sections (–23–21). This result indicates that OM in the core except for the 140190 cm sections is essentially of marine origin. (2) The ¹³C value of diploptene (a hopanoid hydrocarbon) in the last glacial maximum (LGM), is –66.3 (vs. PDB), which indicates it originating in methanotrophic bacteria. This result provides evidence to support for the previous ideas (Oba et al., 1980, 1984; Masuzawa and Kitano, 1984) that the bottom waters in the Japan Sea were anoxic in LGM. (3) Long chain (C₂₃C₃₅) n-alkanes of higher-plant wax origin were found throughout the core. Their concentration is high in 140190 cm in depth, suggesting that eolian dust load was high in LGM. (4) The n-alkane/TOC ratio increases with decreasing ¹³C values of bulk OM. This result indicates that the load of terrestrial (probably eolian dust-derived) OM to the Japan Sea became higher in colder climates. (5) The CPI values of long-chain n-alkanes are different in different ¹³O stages of paleoclimate, probably reflecting variations in species of terrestrial higher plants as a result of climatological adaptations.