Fractal kinetic characteristics for dissolving and leaching processes of strontium residue

The pore structural characteristics of strontium residue were studied with the N₂ adsorption method (ASAP2010). The kinetic properties concerning dissolving and leaching strontium waste were described by determining the concentrations of Sr²⁺, Ba²⁺ and soluble sulphides in solutions. The results showed that the specific surface area and pore volume increased with decreasing granule diameter, and the micropore surface of the residue was fractal. In the dissolving and leaching processes of strontium residue, soluble ion concentrations increased with decreasing granule diameter of the residue, and the reaction dimension was lower than the fractal dimension of pore surface. Sr²⁺ and soluble sulphide concentrations significantly exceeded the defined standard values, while Ba²⁺ concentrations did not, either in the dissolving or leaching solutions. In addition, dissolving and leaching reactions selectively occurred on the micropore surface of strontium residue.     

我国二氧化碳排放的区域分析

利用我国能源统计数据,对我国及各省区的CO2排放总量、排放强度、人均排放量和排放密度进行了计算.通过分析发现我国CO2排放具有较为明显的东西部差异,总体表现为东部发达省区排放总量大、排放强度低、人均排放多、排放密度高的特点,而中西部尤其是西部地区则表现出相反的特征.在分析我国CO2排放区域特征的基础上,分析出现以上地域差异的主要原因,并针对区域减排行动可能存在的问题进行了探讨,提出以省区为单位,降低排放强度可以取得实际的、可跟踪的减排效果,但需要考虑到全国各省区在功能定位、减排成本、资源环境条件等方面的差别,以及建立基于技术与资金合作的联合减排机制的可行性和障碍等因素.     

安徽铜陵凤凰山夕卡岩型铜矿床中辉钼矿Re-Os同位素年龄及其地质意义

铜陵矿集区是我国长江中下游Cu-Au-Fe-Mo成矿带中最重要的有色金属基地之一,凤凰山矿床是铜陵矿集区的重要组成部分,为一个典型的夕卡岩型铜矿床。本文利用Re-Os同位素定年方法对凤凰山铜矿床进行了成矿时代测定,获得了辉钼矿的Re-Os同位素模式年龄范围为139.1±2.4～142.0±2.2Ma,等时线年龄为141.1±1.4Ma,与矿区内石英二长闪长岩和花岗闪长岩SHRIMP锆石U-Pb年龄(144.2±2.3Ma)相吻合,也与铜陵地区其他矿田的成矿时代基本一致,可能为岩石圈减薄事件的成矿响应。     

Re-Os geochronology of Cu and W-Mo deposits in the Balkhash metallogenic belt,Kazakhstan and its geological significance

<正>The Central Asian metallogenic domain(CAMD) is a multi-core metallogenic system controlled by boundary strike-slip fault systems.The Balkhash metallogenic belt in Kazakhstan,in which occur many large and super-large porphyritic Cu—Mo deposits and some quartz vein- and greisen-type W—Mo deposits,is a well-known porphyritic Cu—Mo metallogenic belt in the CAMD.In this paper 11 molybdenite samples from the western segment of the Balkhash metallogenic belt are selected for Re—Os compositional analyses and Re—Os isotopic dating.Molybdenites from the Borly porphyry Cu deposit and the three quartz vein-greisen W—Mo deposits—East Kounrad.Akshatau and Zhanet—all have relatively high Re contents(2712—2772μg/g for Borly and 2.267—31.50μg/g for the other three W—Mo deposits),and lower common Os contents(0.670—2.696 ng/g for Borly and 0.0051—0.056 ng/g for the other three).The molybdenites from the Borly porphyry Cu—Mo deposit and the East Kounrad,Zhanet,and Akshatau quartz vein- and greisen-type W—Mo deposits give average model Re—Os ages of 315.9 Ma,298.0 Ma,295.0 Ma,and 289.3 Ma respectively.Meanwhile,molybdenites from the East Kounrad,Zhanet,and Akshatau W—Mo deposits give a Re—Os isochron age of 297.9 Ma,with an MSWD value of 0.97.Re-Os dating of the molybdenites indicates that Cu—W—Mo metallogenesis in the western Balkhash metallogenic belt occurred during Late Carboniferous to Early Permian(315.9—289.3 Ma),while the porphyry Cu—Mo deposits formed at—316 Ma,and the quartz vein-greisen W—Mo deposits formed at ~298 Ma.The Re—Os model and isochron ages thus suggest that Late Carboniferous porphyry granitoid and pegmatite magmatism took place during the late Hercynian movement.Compared to the Junggar-East Tianshan porphyry Cu metallogenic belt in northwestern China,the formation of the Cu—Mo metallogenesis in the Balkhash metallogenic belt occurred between that of the Tuwu-Yandong in East Tianshan and the Baogutu porphyry Cu deposits in West Junggar. Collectively,the large-scale Late Carboniferous porphyry Cu—Mo metallogenesis in the Central Asian metallogenic domain is related to Hercynian tectono-magmatic activities.     

Distribution characteristics of delta reservoirs reshaped by bottom currents: A case study from the second member of the Yinggehai Formation in the DF1-1 gas field,Yinggehai Basin,South China Sea

The Dongfang1-1 gas field (DF1-1) in the Yinggehai Basin is currently the largest offshore self-developed gas field in China and is rich in oil and gas resources. The second member of the Pliocene Yinggehai Formation (YGHF) is the main gas-producing formation and is composed of various sedimentary types; however, a clear understanding of the sedimentary types and development patterns is lacking. Here, typical lithofacies, logging facies and seismic facies types and characteristics of the YGHF are identified based on high-precision 3D seismic data combined with drilling, logging, analysis and testing data. Based on 3D seismic interpretation and attribute analysis, the origin of high-amplitude reflections is clarified, and the main types and evolution characteristics of sedimentary facies are identified. Taking gas formation upper II (IIU) as an example, the plane distribution of the delta front and bottom current channel is determined; finally, a comprehensive sedimentary model of the YGHF second member is established. This second member is a shallowly buried “bright spot” gas reservoir with weak compaction. The velocity of sandstone is slightly lower than that of mudstone, and the reflection has medium amplitude when there is no gas. The velocity of sandstone decreases considerably after gas accumulation, resulting in an increase in the wave impedance difference and high-amplitude (bright spot) reflection between sandstone and mudstone; the range of high amplitudes is consistent with that of gas-bearing traps. The distribution of gas reservoirs is obviously controlled by dome-shaped diapir structural traps, and diapir faults are channels through which natural gas from underlying Miocene source rocks can enter traps. The study area is a delta front deposit developed on a shallow sea shelf. The lithologies of the reservoir are mainly composed of very fine sand and coarse silt, and a variety of sedimentary structural types reflect a shallow sea delta environment; upward thickening funnel type, strong toothed bell type and toothed funnel type logging facies are developed. In total, 4 stages of delta front sand bodies (corresponding to progradational reflection seismic facies) derived from the Red River and Blue River in Vietnam have developed in the second member of the YGHF; these sand bodies are dated to 1.5 Ma and correspond to four gas formations. During sedimentation, many bottom current channels (corresponding to channel fill seismic facies) formed, which interacted with the superposed progradational reflections. When the provenance supply was strong in the northwest, the area was dominated by a large set of delta front deposits. In the period of relative sea level rise, surface bottom currents parallel to the coastline were dominant, and undercutting erosion was obvious, forming multistage superimposed erosion troughs. Three large bottom current channels that developed in the late sedimentary period of gas formation IIU are the most typical.     

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ENSO indices from sea surface salinity observed by Aquarius and Argo

Analysis of the first 26 months of data from the Aquarius satellite confirms the existence of a sharp sea surface salinity (SSS) front along the equator in the western equatorial Pacific. Following several earlier studies, we use the longitudinal location of the 34.8-psu isohaline as an index, termed Niño-S34.8, to measure the zonal displacement of the SSS front and consequently the eastern edge of the western Pacific warm pool. The on-going collection of the Array for Real-time Geostrophic Oceanography (ARGO) program data shows high correlations between Niño-S34.8 and the existing indices of El Niño, suggesting its potential important role in ENSO evolution. Further analysis of the ARGO data reveals that SSS variability in the southeastern tropical Pacific is crucial to identify the type of El Niño. A new SSS index, termed the southeastern Pacific SSS index (SEPSI), is defined based on the SSS variability in the region (0°–10°S, 150°–90°W). The SEPSI is highly correlated with the El Niño Modoki index, as well as the Trans-Niño index, introduced by previous studies. It has large positive anomalies during central Pacific El Niño or El Niño Modoki events, as a result of enhanced zonal sea surface temperature gradients between the central and eastern tropical Pacific, and can be used to characterize the type of El Niño. The processes that possibly control these SSS indices are also discussed.     

Geological characteristics and tectonic signifcance of unconformities in Mesoproterozoic successions in the northern margin of the North China Block

Several stratigraphic breaks and unconformities exist in the Mesoproterozoic successions in the northern margin of the North China Block.Geologic characters and spatial distributions of fve of these unconformities,which have resulted from different geological processes,have been studied.The unconformity beneath the Dahongyu Formation is interpreted as a breakup unconformity,representing the time of transition from continental rift to passive continental margin.The unconformities beneath the Gaoyuzhuang and the Yangzhuang formations are considered to be the consequence of regional eustatic fuctuations,leading to the exposure of highlands in passive margins during low sea-level stands and transgressive deposition on coastal regions during high sea-level stands.The unconformity atop the Tieling Formation might be caused by uplift due to contractional deformation in a back-arc setting,whereas the uplift after the deposition of the Xiamaling Formation might be attributed to a continental collision event.It is assumed that the occurrences of these unconformities in the Mesoproterozoic successions in the northern margin of the North China Block had a close bearing on the assemblage and breakup of the Columbia and Rodinia supercontinents.     

Analysis of the microclimate and CO2 flux characteristics in arid desert wetland ecosystem in summer: A case study in Xihu desert wetland,Dunhuang, China

Xihu desert wetland is an important and unusual environment in China or even in the world. However, until now, little research has been focused on the microclimate and CO₂ flux characteristics in this area. This paper reports the characteristics of daily variations of microclimate and CO₂ flux in the Dunhuang Xihu desert wetland, based on data observed in the desert wetland during a period of continuous fine weather in summer 2012. Results indicate that the characteristics of the micrometeorology were significantly affected by the land–lake breeze during the study period, and updrafts were prevalent in this region. The friction wind speed and the vertical velocity were much greater than those in the Maqu grasslands. The energy budget was strongly imbalanced: the latent heat flux was significantly higher than the sensible flux. The daily mean values of total solar radiation and net radiation were larger than those in Maqu grasslands and Jinta oasis. There was a temperature inversion and inverse humidity gradient in the atmospheric surface layer at night. The desert wetland ecosystem was a carbon sink during the whole of the observation period, and the maximum rate of carbon absorption usually occurred at about 11:00 hr each day in this region.     

陆海统筹视域下国土空间多维冲突识别与分区调控——以莱州市为例

充分识别陆海空间冲突并制定科学规划是实现陆海统筹的关键。基于陆海空间利用现状与规划,构建陆海空间冲突的理论分析框架,采用冲突识别矩阵、邻域冲突测度模型和社会网络分析等方法,以山东省莱州市为案例区,1 km格网为研究单元,分别从陆地对海洋、海洋对陆地2个方向定量识别陆海空间的现状冲突和规划冲突,并结合四象限模型对冲突进行分区。主要研究结果如下：① 从冲突范围与强度来看,莱州市陆地利用与规划越过海岸线的范围更大,陆海交互冲突范围将持续增加,陆海统筹应重视空间复合利用与跨系统交互影响。② 从冲突的类型来看,现状冲突中陆地的水域与湿地以及海洋的渔业用海等利用方式对海陆系统产生的影响较大;而在规划冲突中,陆地的一般农地区和其他用地区,海洋的农渔业区和港口航运区4类功能分区跨系统产生的影响较大。③ 现状与规划的耦合分区结果显示,相对独立的陆海空间规划对于控制和缓解空间冲突具有一定效果,然而陆海空间统筹利用与管理迫在眉睫,应结合系统观点根据不同分区特点进行优化。