Study on the kinetics of iron oxide leaching by oxalic acid

The presence of iron oxides in clay or silica raw materials is detrimental to the manufacturing of high quality ceramics. Although iron has been traditionally removed by physical mineral processing, acid washing has been tested as it is more effective, especially for extremely low iron (of less than 0.1% w/w). However, inorganic acids such as sulphuric or hydrochloric acids easily contaminate the clay products with SO₄²⁻ and Cl⁻, and therefore should be avoided as much as possible. On the other hand, if oxalic acid is used, any acid left behind will be destroyed during the firing of the ceramic products. The characteristics of dissolution of iron oxides were therefore investigated in this study.The dissolution of iron oxides in oxalic acid was found to be very slow at temperatures within the range 25–60 °C, but its rate increases rapidly above 90 °C. The dissolution rate also increases with increasing oxalate concentration at the constant pH values set within the optimum range of pH2.5–3.0. At this optimum pH, the dissolution of fine pure hematite (Fe₂O₃) (105–140 μm) follows a diffusion-controlled shrinking core model. The rate expression expressed as 1 − (2 / 3)x − (1 − x)^2 / 3 where x is a fraction of iron dissolution was found to be proportional to [oxalate]^1.5.The addition of magnetite to the leach liquor at 10% w/w hematite was found to enhance the dissolution rate dramatically. Such addition of magnetite allows coarser hematite in the range 0.5–1.4 mm to be leached at a reasonable rate.     

Geophysical methods applied to fault characterization and earthquake potential assessment in the Lower Tagus Valley, Portugal

The study region is located in the Lower Tagus Valley, central Portugal, and includes a large portion of the densely populated area of Lisbon. It is characterized by a moderate seismicity with a diffuse pattern, with historical earthquakes causing many casualties, serious damage and economic losses. Occurrence of earthquakes in the area indicates the presence of seismogenic structures at depth that are deficiently known due to a thick Cenozoic sedimentary cover. The hidden character of many of the faults in the Lower Tagus Valley requires the use of indirect methodologies for their study. This paper focuses on the application of high-resolution seismic reflection method for the detection of near-surface faulting on two major tectonic structures that are hidden under the recent alluvial cover of the Tagus Valley, and that have been recognized on deep oil-industry seismic reflection profiles and/or inferred from the surface geology. These are a WNW–ESE-trending fault zone located within the Lower Tagus Cenozoic basin, across the Tagus River estuary (Porto Alto fault), and a NNE–SSW-trending reverse fault zone that borders the Cenozoic Basin at the W (Vila Franca de Xira–Lisbon fault). Vertical electrical soundings were also acquired over the seismic profiles and the refraction interpretation of the reflection data was carried out. According to the interpretation of the collected data, a complex fault pattern disrupts the near surface (first 400 m) at Porto Alto, affecting the Upper Neogene and (at least for one fault) the Quaternary, with a normal offset component. The consistency with the previous oil-industry profiles interpretation supports the location and geometry of this fault zone. Concerning the second structure, two major faults were detected north of Vila Franca de Xira, supporting the extension of the Vila Franca de Xira–Lisbon fault zone northwards. One of these faults presents a reverse geometry apparently displacing Holocene alluvium. Vertical offsets of the Holocene sediments detected in the studied geophysical data of Porto Alto and Vila Franca de Xira–Lisbon faults imply minimum slip rates of 0.15–0.30 mm/year, three times larger than previously inferred for active faults in the Lower Tagus Valley and maximum estimates of average return periods of 2000–5000 years for M 6.5–7 co-seismic ruptures.     

CQK-50型车载化钻机的研制

在分析研究小型地质车载钻机的形式、功能与特点的基础上，提出了钻机车载化的新思路。根据地质调查工作现状，结合国内现有小型地质取样钻机，研制了CQK-50型全液压多功能车载取样钻机，并在野外物化探遥感异常验证钻探中取得了良好效果。     

西部大开发促进区域经济协调发展的理论与实践探索

区域经济协调发展是国民经济发展的客观要求,关系到整个国民经济的战略全局。西部大开发是区域经济协调发展的内在要求和具体体现。非均衡区域经济理论是西部大开发与区域经济协调发展这一重大实践问题的核心理论,我国西部地区以其丰富的资源优势及潜在的区位优势已成为中国经济持续、快速、健康发展的新的增长点。     

遥感技术在煤炭地质中的应用现状及前景

介绍了遥感技术在煤炭资源调查和评价、煤矿区地质灾害调查和评估、生态环境及污染调查评价和监测以及煤矿三维可视化仿真规划系统建设方面的应用研究现状及所取得的主要成果，并结合遥感技术的发展方向，展望了其在煤炭地质中的应用前景。     

Comparison of magnetic parameters with vehicular Br levels in urban roadside soils

Chemical methods are generally chosen to monitor soil pollution but magnetic measurements proved to yield additional information at low cost and less time consumption. In this investigation, the novel use of rapid and non-destructive magnetic measurements to characterize Br levels in Xuzhou (China) urban roadside soils was reported. X-ray fluorescence spectrometry (XRF) was used to quantify Br in the soil samples. Data from 21 roadside soil samples confirm Br contamination, with a mean level of 4.36 mg kg⁻¹ and a range of 2.4–8.7 mg kg⁻¹. These values are higher than that of unpolluted soils in Xuzhou that averages 1.1 mg kg⁻¹. Hierarchical clustering analysis shows Br in Xuzhou roadside soils is mainly from road traffic. Clear correlations between Br levels and simple magnetic parameters [mass specific susceptibility (χ _LF), susceptibility of anhysteretic remanent magnetization (χ _ARM), saturation isothermal remanence (SIRM)] are observed. The present study shows that these three magnetic parameters can be used as a proxy for Br levels in Xuzhou urban roadside soils.     

一种实现依比例街区自动合并的算法

针对依比例街区的图形特征，介绍了一种实现街区自动合并的有效算法，即利用数学形态学和模式识别对栅格数据进行追踪，然后提取街区轮廓线，编辑后就得到最终合并的街区。     

青藏高原东缘龙门山晚新生代剥蚀厚度与弹性挠曲模拟

龙门山是青藏高原东缘边界山脉,具有青藏高原地貌、龙门山高山地貌和山前冲积平原三个一级地貌单元。利用数字高程模式图像和裂变径迹年代测定方法研究和计算龙门山晚新生代剥蚀厚度与剥蚀速率,结果表明:3.6 Ma以来龙门山的剥蚀厚度介于1.91-2.16 km之间,剥蚀速率介于0.53-0.60 mm/a之间。在此基础上,开展了该地区岩石圈的弹性挠曲模拟,结果表明龙门山的隆升机制具有以构造缩短隆升和剥蚀卸载隆升相叠合的特点。3.6 Ma之前,龙门山的隆升与逆冲推覆构造负载有关,以构造缩短驱动的构造隆升为特色;3.6 Ma之后,龙门山的隆升与剥蚀卸载驱动的抬升有关,并以剥蚀卸载隆升为特色,进而提出了龙门山晚新生代以来的隆升机制以剥蚀成山作用为主的认识。     

甘肃花岗岩类成矿作用研究与找矿方向

甘肃省花岗岩分布广泛，与其有关的矿产资源也十分丰富。笔者将甘肃省划分为北山、敦煌一阿拉善、祁连山及西秦岭4个构造-花岗岩-矿化区；进一步在北山、祁连山及西秦岭3个区划分出20个构造-花岗岩-矿化带；并就加强花岗岩成矿作用的研究和找矿工作提出了具体的工作思路与建议。     

山西沁水盆地煤层气成藏的微观动力能条件研究

煤层气成藏的微观动力能条件主要包括煤储层的孔隙—裂隙系统、煤储层的生气作用和储气作用两个方面。以山西沁水盆地为例,深入剖析了煤储层的孔隙—裂隙系统及其发育历程、煤储层的生气作用与能量聚散,阐明了煤层气成藏的微观动力能对成藏效应的控制作用。结果表明:构造作用对储层渗透率具有明显的控制作用,成烃增压致使能量聚集,成为盖层突破作用的主要驱动力,而能量放散则主要是通过煤储层孔隙—裂隙系统的产生、发展。根据上述研究成果,沁水盆地煤层气成藏的地质区划结果为:盆地南部的有利区带为阳城和晋城的北部地区,包括潘庄、樊庄、郑庄等地区;盆地中部的有利区带为安泽—沁源地区,位于盆地西斜坡的中南部;盆地北部的可能有利区带为寿阳东南部地区,位于榆次东北部和阳泉西南部之间。