Electron Probe Microanalysis of Bromine in Minerals and Glasses with Correction for Spectral Interference from Aluminium,and Comparison with Microbeam Synchrotron X‐Ray Fluorescence Spectrometry

The strong spectral interference between Br‐ and Al‐induced X‐ray lines hampers the utilisation of electron probe microanalysis (EPMA) for measuring Br mass fractions in Al‐bearing minerals and glasses. Through measuring Br‐free Al‐bearing materials, we established an EPMA method to quantify the overlap from AlKα on BrLβ, which can be expressed as a linear function of the Al₂O₃ content. The count rate of the BrLβ peak signal was enhanced by high beam currents and long measurement times. Application of this EPMA method to Al‐ and Br‐bearing materials, such as sodalite and scapolite, and to five experimental glasses yielded Br mass fractions (in the range of 250–4000 μg g^?1) that are consistent with those measured by microbeam synchrotron X‐ray fluorescence (μ‐SXRF) spectrometry. The EPMA method has an estimated detection limit of ~ 100–300 μg g^?1. We propose that this method is useful for measuring Br mass fractions (hundreds to thousands of μg g^?1) in Al‐bearing minerals and glasses, including those produced in Br‐doped experiments. In addition, the natural marialitic scapolite (ON70) from Mpwapwa (Tanzania) containing homogeneously distributed high mass fractions of Br (2058 ± 56 μg g^?1) and Cl (1.98 ± 0.03% m/m) is an ideal reference material for future in situ analyses.     

Coupling typhoon rainfall forecasting with overland-flow modeling for early warning of inundation

Taiwan suffers from an average of three or four typhoons annually, and the inundation caused by the heavy precipitation that is associated with typhoons frequently occurs in lowlands and floodplains. Potential inundation maps have been widely used as references to set up non-structural strategies for mitigating flood hazards. However, spatiotemporal rainfall distributions must be addressed to improve the accuracy of inundation forecasting for emergency response operations. This study presents a system for 24-h-ahead early warning of inundation, by coupling the forecasting of typhoon rainfall with the modeling of overland flow. A typhoon rainfall climatology model (TRCM) is introduced to forecast dynamically the spatiotemporal rainfall distribution based on typhoon tracks. The systematic scheme for early warning of inundation based on the spatiotemporal downscaling of rainfall and 2D overland-flow modeling yields not only the extent of inundation, but also the time to maximum inundation depth. The scheme is superior to traditional early warning method referring to the maximum extent and depth of inundation determined from conditional uniform rainfall. Analytical results show that coupling TRCM with an overland-flow model yields satisfactory inundation hydrographs for warning of the extent and peak time of inundation. This study also shows that the accuracy of forecasting spatiotemporal rainfall patterns determines the performance of inundation forecasting, which is critical to emergency response operations.     

An exploratory analysis of benthic macroinvertebrates as indicators of the ecological status of the Upper Yellow and Yangtze Rivers

This study presents findings of the first systematic analysis of aquatic biotic assemblages in the source region of the Yellow and Yangtze Rivers. It provides an initial basis with which to select representative organisms as indicators to assess the aquatic ecological status of rivers in this region. Macroinvertebrates are considered to be good indicators of long-term environmental changes due to their restricted range and persistence over time. Field investigations of macroinvertebrates were conducted in August 2009 in the source region of the Yellow River, and in July 2010 in the source region of the Yangtze River. Altogether 68 taxa of macroinvertebrates belonging to 29 families and 59 genera were identified. Among them were 8 annelids, 5 mollusks, 54 arthropods and 1 other animal. In the source region of the Yellow River, taxa number, density and biomass of macroinvertebrates were 50, 329 individuals m2 and 0.3966 g dry weight m2, respectively. Equivalent figures for the source region of the Yangtze River were 29, 59 individuals m2 and 0.0307 g dry weight m-2. The lower benthic animal resources in the source region of the Yangtze River are ascribed to higher altitude, higher sediment concentration and wetland degradation. Preliminary findings of this exploratory study indicate that hydroelectric power stations had a weak impact on benthic dwellers but wetland degradation caused by a series of human activities had a catastrophic impact on survival of macroinvertebrates. Ecological protection measures such as conservative grazing and vegetation management are required to minimize grassland degradation and desertification, and reduce soil erosion rate and river sediment discharge.     

A three-dimensional variational data assimilation system for a size-resolved aerosol model: Implementation and application for particulate matter and gaseous pollutant forecasts across China

A three-dimensional variational(3DVAR) data assimilation(DA) system is presented here based on a size-resolved sectional aerosol model, the Model for Simulating Aerosol Interactions and Chemistry(MOSAIC) within the Weather Research and Forecasting model coupled to Chemistry(WRF-Chem) model. The use of this approach means that both gaseous pollutants such as SO_2, NO_2, CO, and O_3 as well as particulate matter(PM_(2.5), PM_(10)) observational data can be assimilated simultaneously.Two one-month parallel simulation experiments were conducted, one with the assimilation of surface hourly concentration observations of the above six pollutants released by the China National Environmental Monitoring Centre(CNEMC) and one without assimilation in order to verify the impact of assimilation on initial chemical fields and subsequent forecasts. Results show that, in the first place, use of the DA system can provide a more accurate model initial field. The root-mean-square error of PM_(2.5), PM_(10), SO_2, NO_2, CO, and O_3 mass concentrations in analysis field fell by 29.27 μg m~(-3)(53.5%), 34.5 μg m~(-3)(50.9%),30.36 μg m~(-3)(64.2%), 8.91 μg m~(-3)(39.5%), 0.46 mg m~(-3)(47.4%), and 15.11 μg m~(-3)(51.0%), respectively, compared to a background field without assimilation. At the same time, mean fraction error was reduced by 42.6%, 53.1%, 45.2%, 43.1%,69.9%, and 48.8%, respectively, while the correlation coefficient increased by 0.51, 0.55, 0.48, 0.38, 0.47, 0.65, respectively.Secondly, the results of this analysis reveal variable benefits from assimilation on different pollutants. DA significantly improves PM_(2.5), PM_(10), and CO forecasts leading to positive effects that last more than 48 h. The positive effects of DA on SO_2 and O_3 forecasts last up to 8 h but that remains relatively poor for NO_2 forecasts. Thirdly, the influence of assimilation varies in different areas. It is possible that the positive effects of DA on PM_(2.5) and PM_(10) forecasts can last more than 48 h across most regions of China. Indeed, DA significantly improves SO_2 forecasts within 48 h over north China, and much longer CO assimilation benefits(48 h) are found in most regions apart from north and east China and across the Sichuan Basin. DA is able to improve O_3 forecasts within 48 h across China with the exception of southwest and northwest regions and the O_3 DA benefits in southern China are more evident, while from a spatial distribution perspective, NO_2 DA benefits remain relatively poor.     

安徽省震中快速定位查询系统

基于VB6.0软件开发平台,以MapInfo GIS软件为数据支撑平台,建立了安徽省震中快速定位查询系统。系统主要实现了震中快速定位查询显示功能、基于GIS数据的空间分析和定量计算分析功能。为地震应急响应提供辅助决策,为震后资源调度、伤员输送、人员疏散等提供科学信息,提高了应急救援的效率。     

Seasonal and Sub-Seasonal Circulation Anomalies Associated with Persistent Rainy Days in 2018/2019 Winter in Shanghai,China

Shanghai experienced the longest rainy days in 2018/2019 winter since 1988. The physical cause of such an unusual climate condition was investigated through the diagnosis of observational data. From a seasonal perspective, a long persistent rainy winter was often associated with an El Niño condition in the equatorial Pacific. This abnormal oceanic condition induces a remote teleconnection pattern with pronounced low-level southerly anomalies over East China. The wind anomalies transported moisture from tropical oceans and caused persistent rainfall in East Asia. Meanwhile, the local rainfall time series exhibited a strong quasi-biweekly oscillation (QBWO). Three persistent rainy events were identified in the 2018/2019 winter and they all occurred during the active phase of the QBWO. The first two events were associated with a low pressure anomaly west of Shanghai. Southerly anomalies associated with the low pressure system advected high mean moisture into central eastern China, leading to the persistent rainfall there. The third event was associated with a high pressure anomaly in lower troposphere to the east of Shanghai, which induced anomalous southerlies to its west, favoring the occurrence of rainfall in Shanghai. The result suggests the importance of high-frequency variability in affecting seasonal rainfall anomalies.     

长白山天池火山区长白-敦化剖面结晶基底的探测和研究

时间项分析法中，应用广义最小二乘法进行反演，对长白山天池火山区岩浆系统的长白—敦化(L1)剖面的Pg波到时进行了计算处理，得到了Pg波时间项及基底速度值；取上部地壳的介质平均速度为4．5km/s，经反演求得了各点的深度值，给出了长白山天池火山区结晶基底的厚度分布。结晶基底厚度一般在2．0km左右，而在长白山天池下方结晶基底最厚处接近4．0km；在万宝和敦化附近各有一不太明显的凹陷，其原因可能与在这两个位置处有几条断裂穿过有关。     

分潮波模型多资料数值计算方法研究 Ⅱ.有限差分最小二乘方法

对含多资料的分潮波模型的超定问题进行探讨，建立一种有限差分—最小二乘方法，该方法使得岸边资料直接进入了计算方程，并保证岸界法向流速为零条件。通过对渤海的四大分潮的试算，证实本方法可行。     

云南腾冲热泉金的有机地球化学研究——Ⅰ生物标志物浅析

本文主要通过对比分析研究热泉软泥中的金含量与有机质及含硫化合物的相关性。并测定泉水及软泥中含金量和软泥中有机碳含量，以及对抽提物中的饱和烃和芳烃族组分进行色谱—质谱分析，最后得出的结论：有机质的沉积环境为还原—强还原，有机质属于腐泥－腐殖型，接近和达到了成熟阶段。软泥中金含量与有机质的性质无明显相关关系，与有机碳含量也无明显相关关系，而与其成熟度相关密切。样品分析证实软泥中含硫化合物与金含量呈正相关性。对比分析了水及软泥中金含量，认为两者之间也无明显相关关系     

固定模糊度的精密单点定位几何定轨方法及结果分析

传统的基于PPP(precise point positioning)模式的定轨方法采用浮点解,导致其定轨精度及可靠性较双差固定解稍差。为了进一步提高PPP模式事后定轨的精度和可靠性,利用2012年1月2～7日全球IGS跟踪站数据计算出当天所有卫星的宽巷和窄巷FCB产品,实现了GRACE卫星固定PPP整数模糊度的精密定轨。并将定轨结果分别与GFZ事后精密轨道、K波段测距结果进行比较,分析其内外符合精度。实验结果表明:与GFZ提供的事后精密轨道相比,GRACE-A卫星单天轨道固定解的精度为R方向2～3cm,T方向大部分优于2cm,N方向优于2cm,较之浮点解的定轨结果3个方向分别改善了约19%、30%、50%;GRACE-B卫星3个方向精度分别为2～3cm、2cm左右、1～2cm,较之浮点解各方向也有同等程度的改善。与K波段测距结果相比,浮点解的KBR残差STD均值为22.6mm,固定解为16.4mm,比浮点解提高了约28%。可见,PPP模糊度固定解明显改善了低轨卫星的定轨精度,能提供更可靠的轨道服务。