Prediction of the abiotic degradability of organic compounds in the troposphere

A statistically relevant correlation between the reaction rate coefficient, k _OH, for the OH radical reaction with 161 organic compounds in the gas phase at 300 K, and the corresponding vertical ionisation energies E _i,v, reveals two classes of compounds: aromatics where –log(k _OH/cm³s^-1)3/2E _i,v(eV)–2 and aliphatics where –log(k _OH/cm³s^-1)4/5E _i,v(eV)+3. The prediction of the rate coefficient, k _OH, for the reaction of OH with organic molecules from the above equations has a probability of about 90%. Assuming a global diurnal mean of the OH radical concentration of 5×10⁵ cm³, the upper limit of the tropospheric half-life of organic compounds and their persistence can be estimated.     

巴丹吉林沙漠周边地区降水量的时空变化特征

分析了巴丹吉林沙漠周边17个常规气象测站1951—2005年的逐月降水量及沙尘暴频次和东亚夏季风指数。(1)沙漠周边地区降水量的空间分布明显受地形影响:紧靠沙漠的区域地势低、干旱,各季降水量都小;沙漠外围较远处(特别是受祁连山影响的西南边)地势高、湿润,各季降水量都大;地形增高会使降水量增多1个量级以上,但对其季节配额无明显影响。夏季降水量配额最大,平均高达61.6%。(2)依据各站降水量年际变化间的相关系数及测站间的地域关系和地貌相似程度,可将该区域划为4个分区:一为地势较低、紧挨沙漠、极为干旱的沙漠西北缘区,二为气候较湿、受祁连山影响的沙漠西南缘区(或称祁连山影响区),三为位于巴丹吉林沙漠和腾格里沙漠之间的民勤区,四为远离沙漠、但与其周边地区地貌相似的沙漠东侧区。(3)1951—2005年的各个年代,4个分区各季降水量由大到小的顺序均为:祁连山影响区、沙漠东侧区、民勤区和沙漠西北缘区,与其平均海拔由高到低的顺序一致;就各季降水量及其配额的年代际演变位相而言,祁连山影响区可以代表整个区域。(4)1971—2005年各分区年降水量呈增大趋势,春季降水量增加尤为显著(增幅约为0.41mm·a-1),夏季降水量有减小趋势;随海拔增高,春季及年降水量增幅加大,夏季降水量减幅减小;祁连山影响区对全区年降水量增大的贡献最大。(5)各季及年降水量与东亚夏季风的强弱间均呈复相关;其中冬、夏季及年降水量与夏季风间的负相关随海拔升高而加大,说明夏季风对沙漠以南高海拔处的降水影响更为显著。(6)各季沙尘暴与降水量间以负相关为主,各分区冬、春季降水量偏多时,其冬、春季及夏季沙尘暴的发生频次一般偏少。     

Comparison of P‐wave attenuation models of wave‐induced flow

Wave‐induced oscillatory fluid flow in the vicinity of inclusions embedded in porous rocks is one of the main causes for P‐wave dispersion and attenuation at seismic frequencies. Hence, the P‐wave velocity depends on wave frequency, porosity, saturation, and other rock parameters. Several analytical models quantify this wave‐induced flow attenuation and result in characteristic velocity–saturation relations. Here, we compare some of these models by analyzing their low‐ and high‐frequency asymptotic behaviours and by applying them to measured velocity–saturation relations. Specifically, the Biot–Rayleigh model considering spherical inclusions embedded in an isotropic rock matrix is compared with White's and Johnson's models of patchy saturation. The modeling of laboratory data for tight sandstone and limestone indicates that, by selecting appropriate inclusion size, the Biot‐Rayleigh predictions are close to the measured values, particularly for intermediate and high water saturations.     

The response of saltation to wind speed fluctuations

The response time of saltation to spatial or temporal wind speed fluctuations constitutes an important control parameter for aeolian sediment transport and deposition. In this paper, we present direct measurements of the response time obtained from several field experiments. The sand transport was studied using six small microphones arranged in a vertical profile and collocated with a sonic anemometer, a webcam and a cup anemometer tower. The webcam was coupled with the sonic anemometer via a personal computer and provides information on creeping and saltating grains with a sampling rate of 10 Hz. Sediment transport measurements were obtained over four periods. The Wiener filter, a signal processing technique, is used to obtain a discrete transfer function that relates the horizontal wind speed and the non‐intermittent sand transport. The transfer function can be established using an exponential function with a time constant or characteristic response time τ without time shift. The response time fluctuated between zero and 1·5 seconds depending on the turbulence intensity, the saltation activity, the measuring height and sampling rates. The Wiener filter coefficients suggest that the response of saltation to wind speed alterations is determined by more than one process. Copyright © 2012 John Wiley & Sons, Ltd.     

Results of a 36-hour storm surge prediction of the North Sea for 3 January 1976 on the basis of numerical models

Summary To explore the feasibility of forescasting North Sea storm surges by integrating numerically a combined atmospheric-oceanographic physical model, the severe storm and the resulting water levels occurring on 3 January 1976 were simulated as a first step into this direction. For this purpose, the atmospheric model was run with a resolution of 8 levels in the vertical and a horizontal grid spacing of 1.4° in latitude and 2.8° in longitude on the hemisphere. The initial conditions are based upon observations of 2 January 1976, 12 GMT, i.e. about 24 hours before the storm reached its greatest intensity in the southern parts of the North Sea.The surface wind predicted by the atmospheric model was converted into stress values through a bulk formula which then entered the vertically integrated North Sea model, to yield the desired water elevations in a 22 km-grid. Moreover, also the observed wind, stemming from a careful re-analysis of the storm situation, was handled in the same way. The numerically obtained results were compared with gauge measurements at a number of coastal stations.

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Ergebnisse einer 36stündigen Vorhersage der Nordsee-Sturmflut am 3. Januar 1976 aufgrund von numerischen Modellen

Zusammenfassung Zur Untersuchung der Möglichkeiten, Sturmfluten mit physikalischen Modellen der Atmosphäre und der Nordsee vorherzusagen, wurde als erster Schritt in dieser Richtung die schwere Sturmflut an der deutschen Nordseeküste vom 3. Januar 1976 nachgerechnet. Hierzu wurde das im Sonderforschungsbereich 94 entwickelte Atmosphärenmodell auf der Grundlage der hydro- und thermodynamischen Gleichungen mit einer Auflösung von 8 Flächen in der Vertikalen sowie 1,4° in der geographischen Breite und 2,8° in der geographischen Länge auf der gesamten Nordhalbkugel über 36 Stunden numerisch integriert. Als Eingangsdaten dienten die Beobachtungen vom 2. Januar 1976, 12 Uhr. dieser Termin liegt ca. 24 Stunden vor Eintritt des stärksten Sturmes im Bereich der Deutschen Bucht.Die auf diese Weise prognostizierte Windverteilung wurde über der Nordsee in Schubspannungswerte überführt, woraus das Nordseemodell mit den hydrodynamischen Gleichungen die Wasserstandswerte in einem 22-km-Netz berechnete. In entsprechender Weise wurde mit einem aus Beobachtungen während dieses Zeitraums gewonnenen Windfeld verfahren; diesem lag eine besonders sorgfältige, nachträglich angefertigte Analyse des Seewetteramts Hamburg zugrunde. Die so errechneten Wasserstände sind dann mit Pegelmessungen verglichen worden.

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Résultats d'une prédiction d'onde de tempête de 36 heures de la mer du Nord pour le 3 janvier 1976 sur la base de modèles numériques

Résumé Afin d'étudier la possibilité de prévior les ondes de tempête en mer du Nord en intégrant numériquement un modèle physique combiné atmosphère-océan, la forte tempête du 3 janvier 1976 et des niveaux d'eau qui en ont résulté ont été simulés comme premier pas dans cette voie. Dans ce but, on a fait fonctionner le modèle atmosphérique avec une résolution de 8 niveaux dans le plan vertical et un réseau horizontal aux pas de 1,4° en latitude et de 2,8° en longitude sur l'hémisphère. Les conditions initiales sont basées sur les observations du 2 janvier 1976 à 12h GMT, c'est-à-dire environ 24 heures avant que la tempête n'atteignît sa plus forte intensité dans les parties méridionales de la mer du Nord.Le vent en surface prédit par le modèle atmosphérique était converti par l'intermédiaire d'une formule globale en valeurs de tensions qui étaient alors introduites dans le modèle de la mer du Nord intégré verticalement, pour obtenir les hauteurs d'eau désirées, dans un réseau de 22 km de côté. En outre, le vent observé, issu d'une nouvelle analyse soignée de la situation de tempête, était aussi traité de la même manière. Les résultats obtenus numériquement furent comparés aux mesures fournies par les marégraphes en un certain nombre de stations côtières.

     

Effect of cofactors of adjusted and unadjusted quantities on their functions

aamuam uu am a (m u naamuu n) u u (a) uu a uu mu uu. mam (19), (28) naam, m amua am mau u m ¶rt; am amu: a) na ¶rt;um am, n n a uu am u uu a uu; ) ma ¶rt;um am, m aam uu a uu.     

Reconstructions of spring/summer precipitation for the Eastern Mediterranean from tree-ring widths and its connection to large-scale atmospheric circulation

This study represents the first large-scale systematic dendroclimatic sampling focused on developing chronologies from different species in the eastern Mediterranean region. Six reconstructions were developed from chronologies ranging in length from 115 years to 600 years. The first reconstruction (1885–2000) was derived from principal components (PCs) of 36 combined chronologies. The remaining five, 1800–2000, 1700–2000, 1600–2000, 1500–2000 and 1400–2000 were developed from PCs of 32, 18, 14, 9, and 7 chronologies, respectively. Calibration and verification statistics for the period 1931–2000 show good levels of skill for all reconstructions. The longest period of consecutive dry years, defined as those with less than 90% of the mean of the observed May–August precipitation, was 5 years (1591–1595) and occurred only once during the last 600 years. The longest reconstructed wet period was 5 years (1601–1605 and 1751–1755). No long term trends were found in May–August precipitation during the last few centuries. Regression maps are used to identify the influence of large-scale atmospheric circulation on regional precipitation. In general, tree-ring indices are influenced by May–August precipitation, which is driven by anomalous below (above) normal pressure at all atmospheric levels and by convection (subsidence) and small pressure gradients at sea level. These atmospheric conditions also control the anomaly surface air temperature distribution which indicates below (above) normal values in the southern regions and warmer (cooler) conditions north of around 40°N. A compositing technique is used to extract information on large-scale climate signals from extreme wet and dry summers for the second half of the twentieth century and an independent reconstruction over the last 237 years. Similar main modes of atmospheric patterns and surface air temperature distribution related to extreme dry and wet summers were identified both for the most recent 50 years and the last 237 years. Except for the last few decades, running correlation analyses between the major European-scale circulation patterns and eastern Mediteranean spring/summer precipitation over the last 237 years are non-stationary and insignificant, suggesting that local and/or sub-regional geographic factors and processes are important influences on tree-ring variability over the last few centuries.     

Ambiguous Moment Tensors and Radiation Patterns in Anisotropic Media with Applications to the Modeling of Earthquake Mechanisms in W-Bohemia

Anisotropic material properties are usually neglected during inversions for source parameters of earthquakes. In general anisotropic media, however, moment tensors for pure-shear sources can exhibit significant non-double-couple components. Such effects may be erroneously interpreted as an indication for volumetric changes at the source. Here we investigate effects of anisotropy on seismic moment tensors and radiation patterns for pure-shear and tensile-type sources. Anisotropy can significantly influence the interpretation of the source mechanisms. For example, the orientation of the slip within the fault plane may affect the total seismic moment. Also, moment tensors due to pure-shear and tensile faulting can have similar characteristics depending on the orientation of the elastic tensor. Furthermore, the tensile nature of an earthquake can be obscured by near-source anisotropic properties. As an application, we consider effects of inhomogeneous anisotropic properties on the seismic moment tensor and the radiation patterns of a selected type of micro-earthquakes observed in W-Bohemia. The combined effects of near-source and along-path anisotropy cause characteristic amplitude distortions of the P, S1 and S2 waves. However, the modeling suggests that neither homogeneous nor inhomogeneous anisotropic properties alone can explain the observed large non-double-couple components.The results also indicate that a correct analysis of the source mechanism, in principle, is achievable by application of anisotropic moment tensor inversion.