中国大陆科学钻探（CCSD）主孔地区岩石圈热结构

岩石圈热结构是指地球内部热量在壳幔的配分比例、温度以及热导率和生热率等热学参数在岩石圈中的分布特征。岩石圈的热结构直接影响着岩石的物理性质和流变学性质,同时还控制了化学反应的类型和速度,从而制约着岩石圈的发展和演化。本文在前人CCSD主孔岩石主、微量元素研究基础上,利用Rybach生热率公式计算了钻孔岩石的放射性生热率,并结合岩石热导率的测定研究了CCSD主孔100-2000m岩石的热结构和主孔榴辉岩在不同退变质程度下生热率、热导率的变化:钻孔中岩石的平均生热率为0.95μWm-3,平均热导率为2.96mWm-1K-1。,其中片麻岩生热率高迭1.01-1.7μWm-3,热导率为2.76-2.96mWm-1K-1;基性超基性岩石生热率最低(<0.21μWm-3),热导率则高达3.20mWm-1K-1以上;新鲜榴辉岩生热率、热导率居中,分剐为0.16-0.44μWm-3和3.31-3.85mWm-1K-1。钻孔中榴辉岩生热率、热导率变化主要受岩性控制:从新鲜榴辉岩到完全退变榴辉岩,热导率总体上降低,但从强退变榴辉岩到完全退变榴辉岩,岩石热导率升高;而在此过程中岩石生热率总体上升高,仅当从中等退变质榴辉岩退变为强退变质榴辉岩时,岩石生热率出现降低趋势。在综合研究的基础上预测CCSD主孔5000m深度处温度为139℃,温度范围为131-151℃。根据区域深部地球物理探测成果对CCSD主孔地区岩石圈热结构进行了研究:上地壳底部温度为256℃,中地壳底部温度为492℃,Moho面温度为683℃,岩石圈底部温度为1185℃,来自地幔的热流为44.1mWm-2,对地表热流的贡献率为58%。研究结果表明,由岩石物理方法获得的CCSD主孔地区岩石圈地温曲线与石榴石-二辉橄榄岩包体推断的中国东部地温曲线十分吻合,本文从实验岩石物理学角度为CCSD主孔地区岩石圈热结构研究提供了重要约束     

Exploring the impact of diagenesis on (isotope) geochemical and microstructural alteration features in biogenic aragonite

For the Quaternary and Neogene, aragonitic biogenic and abiogenic carbonates are frequently exploited as archives of their environment. Conversely, pre‐Neogene aragonite is often diagenetically altered and calcite archives are studied instead. Nevertheless, the exact sequence of diagenetic processes and products is difficult to disclose from naturally altered material. Here, experiments were performed to understand biogenic aragonite alteration processes and products. Shell subsamples of the bivalve Arctica islandica were exposed to hydrothermal alteration. Thermal boundary conditions were set at 100°C, 175°C and 200°C. These comparably high temperatures were chosen to shorten experimental durations. Subsamples were exposed to different ¹⁸O‐depleted fluids for durations between two and twenty weeks. Alteration was documented using X‐ray diffraction, cathodoluminescence, fluorescence and scanning electron microscopy, as well as conventional and clumped isotope analyses. Experiments performed at 100°C show redistribution and darkening of organic matter, but lack evidence for diagenetic alteration, except in Δ₄₇ which show the effects of annealing processes. At 175°C, valves undergo significant aragonite to calcite transformation and neomorphism. The δ¹⁸O signature supports transformation via dissolution and reprecipitation, but isotopic exchange is limited by fluid migration through the subsamples. Individual growth increments in these subsamples exhibit bright orange luminescence. At 200°C, valves are fully transformed to calcite and exhibit purple‐blue luminescence with orange bands. The δ¹⁸O and Δ₄₇ signatures reveal exchange with the aqueous fluid, whereas δ¹³C remains unaltered in all experiments, indicating a carbonate‐buffered system. Clumped isotope temperatures in high‐temperature experiments show compositions in broad agreement with the measured temperature. Experimentally induced alteration patterns are comparable with individual features present in Pleistocene shells. This study represents a significant step towards sequential analysis of diagenetic features in biogenic aragonites and sheds light on reaction times and threshold limits. The limitations of a study restricted to a single test organism are acknowledged and call for refined follow‐up experiments.     

Quaternary Climate and Environment in the Lop Nur, Xinjiang

Since the middle Early Pleistocene (1.20 Ma B.P.), the desert steppe climate and environment have predominated in the Lop Nur area, Xinjiang, characterized by warm humid epochs interrupted by dry cold intervals. The grain-size and magnetic susceptibility curves record 30 climatic oscillations, each with a ca. 40 ka cycle, in the area since 1.2 Ma B.P., which reflects the controlling effects exerted by the astronomic factor on the environment. The Quaternary sedimentary environment in the Lop Nur gradually changed from a fresh lake through a brackish lake to a saline lake, showing a spiral evolution, and finally it evolved into a playa.     

南天山库米什蛇绿混杂岩带中硅质岩的元素地球化学特征及其形成环境

南天山库米什铜花山地区蛇绿混杂岩带不同岩块中的硅质岩高Al_2O_3和Al_2O_3/TiO_2,Zr、Nb、Hf、Ta和Th与Al_2O_3等陆源元素具较好正相关性,北关页岩标准化稀土模式呈现无Ce负异常(Ce/Ce~*=1．05～1．33)的典型大陆边缘硅质岩平坦稀土谱型,它们的(La/Ce)_SN=0．74～0．98,Ti/V=5．10～122．18,V/Y=0．39～6．03,均与大陆边缘硅质岩值相当,表明这些硅质岩形成在明显受陆源物质影响与大陆边缘密切相关的环境。但不同岩块硅质岩的物源区仍存在一定差异。其中,与泥岩成互层产出的红色硅质岩的Th/Sc=0．56—4．35,具Eu负异常(Eu/Eu~*=0．56～0．71)明显的较陡右倾球粒陨石标准化稀土谱型(La_N/Yb_N=3．92～7．43),与分异岩浆弧源区特征类似,可能形成在相对近陆缘的弧前盆地,其源区物质主要来自分异岩浆弧。而成夹层产出于基性熔岩中的绿色硅质岩呈现为Eu负异常较弱(Eu/Eu~*=0．72～0．93)右倾较缓的稀土谱型(La_n/Yb_n=4．15～6．69),其Th/Sc=0．57～0．87,反映有洋内弧物质加入的影响,因此它们可能形成于相对远离大陆、除有未分异基性程度较高的洋内弧物质输入外,仍受到陆缘物质影响的有限洋盆环境。根据硅质岩晚古生代初的放射虫化石推断,该地区硅质岩在晚古生代初期形成,南天山构造带已进入板块汇聚俯冲消减洋盆萎缩的发展演化阶段。     

海底可视技术在天然气水合物勘查中的应用

海底可视技术是一种可以直观地对海底地形地貌、表层沉积物类型、生物群落等进行实时观察的调查手段。本文介绍了海底摄像、电视抓斗、深拖系统和ROV四种海底可视技术，并对海底可视技术在南海北部陆坡天然气水合物勘查中的应用进行阐述。利用海底可视技术，在南海北部陆坡发现了天然气水合物气体“冷泉”喷溢形成的自生碳酸盐岩和活动于天然气水合物冷喷溢口或渗流口周围的菌席、双壳类、管状蠕虫等化能自养生物群，圈定出该陆坡由天然气水合物气体“冷泉”喷溢形成的巨型碳酸盐岩面积达430km^2。     

山东招远大尹格庄金矿成矿流体特征

大尹格庄金矿位于中国胶北地体西北部招平断裂带下盘的蚀变花岗质碎裂岩 (绢英岩 )带中 ,断裂上盘为胶东群变质岩系。金主要产于黄铁绢英岩和黄铁矿±多金属硫化物 石英±碳酸盐脉 -细网脉中 ,构成细脉 -浸染状矿石。对蚀变围岩和金矿石中流体包裹体的研究表明钾长石化岩 (钾长石 -石英脉 )和绢英岩 (第 I和第 II阶段 )的石英中含有丰富的 CO2 -H2 O包裹体 ,而金 -硫化物矿石和石英 -碳酸盐脉 (第 III和第 IV阶段 )中 CO2 - H2 O包裹体数量逐渐减少。显微测温指示 ,钾长石化岩和绢英岩石英中的 CO2 - H2 O包裹体的均一温度范围为 2 80～ 36 0℃ ;而金 -黄铜矿和金 -方铅矿 -闪锌矿矿石中包裹体的均一温度分别为 2 40～ 2 75℃和 180～ 2 5 0℃。显微测温和激光拉曼探针分析表明 ,第 I和第 II阶段的成矿流体含 10～ 2 5mol% CO2 ;而第 III和第 IV阶段的含 <5～ 10 mol% CO2 ,并含少量至可观数量 CH4,H2 S和 SO2 等。广泛的黄铁矿化、碳酸盐化蚀变以及缺乏较高盐度的水包裹体说明金很可能是以硫络合物和碳络合物形式被搬运。金的沉淀与温度下降、由裂隙的(重复 )开放引起明显的压力降低和原始流体的不混溶作用有关 ,具多阶段成矿特点     

Flow dynamics at the origin of thin clayey sand lacustrine turbidites: Examples from Lake Hazar,Turkey

Turbidity currents and their deposits can be investigated using several methods, i.e. direct monitoring, physical and numerical modelling, sediment cores and outcrops. The present study focused on thin clayey sand turbidites found in Lake Hazar (Turkey) occurring in eleven clusters of closely spaced thin beds. Depositional processes and sources for three of those eleven clusters are studied at three coring sites. Bathymetrical data and seismic reflection profiles are used to understand the specific geomorphology of each site. X‐ray, thin sections and CT scan imagery combined with grain‐size, geochemical and mineralogical measurements on the cores allow characterization of the turbidites. Turbidites included in each cluster were produced by remobilization of surficial slope sediment, a process identified in very few studies worldwide. Three types of turbidites are distinguished and compared with deposits obtained in flume studies published in the literature. Type 1 is made of an ungraded clayey silt layer issued from a cohesive flow. Type 2 is composed of a partially graded clayey sand layer overlain by a mud cap, attributed to a transitional flow. Type 3 corresponds to a graded clayey sand layer overlain by a mud cap issued from a turbulence‐dominated flow. While the published experimental studies show that turbulence is damped by cohesion for low clay content, type 3 deposits of this study show evidence for a turbulence‐dominated mechanism despite their high clay content. This divergence may in part relate to input variables, such as water chemistry and clay mineralogy, that are not routinely considered in experimental studies. Furthermore, the large sedimentological variety observed in the turbidites from one coring site to another is related to the evolution of a sediment flow within a field‐scale basin made of a complex physiography that cannot be tackled by flume experiments.     

Barium Isotopic Compositions in Thirty‐Four Geological Reference Materials Analysed by MC‐ICP‐MS

Measurement of Ba isotope ratios of widely available reference materials is required for interlaboratory comparison of data. Here, we present new Ba isotope data for thirty‐four geological reference materials, including silicates, carbonates, river/marine sediments and soils. These reference materials (RMs) cover a wide range of compositions, with Ba mass fractions ranging from 6.4 to 1900 µg g^?1, SiO₂ from 0.62% to 90.36% m/m and MgO from 0.08% to 41.03% m/m. Accuracy and precision of our data were assessed by the analyses of duplicate samples and USGS rock RMs. Barium isotopic compositions for all RMs were in agreement with each other within uncertainty. The variation of δ^138/134Ba in these RMs was up to 0.7‰. The shale reference sample, affected by a high degree of chemical weathering, had the highest δ^138/134Ba (0.37 ± 0.03‰), while the stream sediment obtained from a tributary draining carbonate rocks was characterised by the lowest δ^138/134Ba (?0.30 ± 0.05‰). Geochemical RMs play a fundamental role in the high‐precision and accurate determination of Ba isotopic compositions for natural samples with similar matrices. Analyses of these RMs could provide universal comparability for Ba isotope data and enable assessment of accuracy for interlaboratory data.     

莺—琼盆地1号断裂带含烃热流体活动初探

１号断裂带是莺－琼盆地油气勘探的重点地区之一,有机包裹体研究有助于追踪油气及热流体活动的痕迹,为油气运聚成藏提供地球化学依据,通过包裹体薄片镜下观察,均一温度和盐度测试,认为工区内发育五种类型的有机包裹体：（１）液态烃包裹体;（２）气流态烃包裹体;（３）气态烃包裹体;（４）含烃ＣＯ２包裹体;（５）烃子矿物包裹体,含烃ＣＯ２包裹体一般与气态烃共生,含烃子矿物包裹体既无液态烃共生又与气态烃共生,包裹体     

气候系统可预报性的全局研究

胞映射方法是对非线性系统进行全局分析的强有力工具。文中基于一个最大简化的地－气耦合模式,引入胞映射全局分析方法,对气候系统的可预报性进行了全局的研究。气候系统存在最大可预报期限,对于超过逐日预报可预报期限后的预报,用胞映射思想证明了平均值的可预报性,并得到了定量的结果。研究表明,耦合机制具有延长可预报期限的作用,观测精度的提高亦可延长可预报期限