Implications of trace element composition of syntaxial quartz cements for the geochemical conditions during quartz precipitation in sandstones

A petrographic investigation revealed polyphase quartz cementation in the Finefrau Sandstone (Upper Carboniferous, Western Germany) and the Solling Sandstone (Lower Triassic, Central Germany). Three different cements could be distinguished in each sandstone based on their cathodoluminescence and trace element composition. The first quartz generation is suggested to have been formed during eogenesis due to dissolution and replacement of feldspar. The mesogenetic paragenesis comprises two generations of quartz and illite, which are accompanied by albite in the Solling Sandstone. Sharp luminescence zoning in quartz overgrowths points to distinct episodes of cementation in both sandstones. Significant amounts of Al, Li and H and traces of Ge and B have been detected in the quartz overgrowths. The Al‐content of the quartz cements in the Finefrau Sandstones exceeds that in the quartz cements in the Solling Sandstone by a factor of five. It is suggested that this compositional variation reflects the conditions in the pore‐water, such as temperature and pH. The Al‐concentration is generally correlated to the Li‐content with the exception of the latest quartz generation in the Finefrau Sandstones which is also most enriched in trace elements. The ratio of Li/Al varies between 0·11 and 0·25 in the two sandstones. The Li/H‐ratio, which ranges from 0·12 to 0·3, is controlled by the activity ratio of Li and H in the pore fluid. Clay minerals are the most important source for Li and high salinities favour the mobilization of Li during diagenesis. Thus, a relatively low salinity and low pH are responsible for the low Li/H‐ratio in the Finefrau Sandstone, while high salinity and neutral to alkaline pH results in a high Li/H‐ratio for the Solling Sandstone. The Ge‐contents are generally near the average of detrital quartz and indicate that pressure dissolution is a major source for quartz cementation. Different chemical compositions of distinct quartz generations indicate changes in the physico‐chemical conditions and point to mobilization of silica from different sources (for example, pressure solution and clay mineral transformations).     

An empirical model of subcritical bedform migration

The ability to predict bedform migration in rivers is critical for estimating bed material load, yet there is no relation for predicting bedform migration (downstream translation) that covers the full range of conditions under which subcritical bedforms develop. Here, the relation between bedform migration rates and transport stage is explored using a field and several flume data sets. Transport stage is defined as the non‐dimensional Shields stress divided by its value at the threshold for sediment entrainment. Statistically significant positive correlations between both ripple and dune migration rates and transport stage are found. Stratification of the data by the flow depth to grain‐size ratio improved the amount of variability in migration rates that was explained by transport stage to ca 70%. As transport stage increases for a given depth to grain‐size ratio, migration rates increase. For a given transport stage, the migration rate increases as the flow depth to grain‐size ratio gets smaller. In coarser sediment, bedforms move faster than in finer sediment at the same transport stage. Normalization of dune migration rates by the settling velocity of bed sediment partially collapses the data. Given the large amount of variability that arises from combining data sets from different sources, using different equipment, the partial collapse is remarkable and warrants further testing in the laboratory and field.     

Clay mineralogy as a tool for integrated sequence stratigraphic and palaeogeographic reconstructions: Late Oligocene–Early Aquitanian western internal South Iberian Margin,Spain

The different hydrodynamic behaviour of detrital clay minerals in the marine depositional environment allows assessment of relative sea‐level variations in the sedimentary record. Comparison of smectite and kaolinite:illite (S+K:I) changes with the global sea‐level curves and with the third‐order cycles of the eustatic curve for European basins allows assessment of the influence of global eustasy and local tectonics on sequence stratigraphy. In the South Iberian Margin, sedimentation took place both on open‐marine platforms and in deeper water areas. On this margin during the Late Oligocene to Early Aquitanian, the variations in sedimentation were caused not only by global eustasy but also by compressive tectonics. Correlations were made between the S+K:I cycles and the third‐order cycles for European basins, enabling the definition of four third‐order sedimentary sequences (here called C1, C2, C3, and A1) and two lower‐order sequences within C3 and A1 (here called C3a, C3b, A1a, and A1b) related to tectonic movements. High S+K:I values were observed during episodes of maximum flooding in each sequence and lower‐order sequence and in each succession, enabling changes in palaeocoastal morphology to be considered. Copyright © 2012 John Wiley & Sons, Ltd.     

The latest Carboniferous–Early Permian Dorud Group of the eastern Alborz (Iran): biostratigraphy and taxonomy of smaller foraminifers

The latest Carboniferous–Early Permian Dorud Group in the Chaman‐Saver area of eastern Alborz, Iran is more than 222 m thick and includes thick sequences of oncolitic limestone, sandy limestone, sandstones and shales. The Emarat and Ghosnavi formations of this Group are dated here as latest Gzhelian to early Sakmarian Stages. During the Asselian Stage, the sea level fell abruptly and epeirogenic episodes occurred. These events generated a broad, shallow carbonate platform suitable for the growth and diversity of smaller foraminifers in the Chaman‐Saver area which, consequently, displays faunal differences with the rest of the Alborz Mountains. Three foraminiferal biozones are proposed: Nodosinelloides potievskayae–Vervilleina bradyi Zone (latest Gzhelian), Calcitornella heathi–Nodosinelloides sp. Zone (latest Gzhelian–Asselian), and Rectogordius iranicus n. gen. n. sp.–Hemigordius schlumbergeri Zone (early Sakmarian). The new taxa described herein include: Pseudovidalina iranica n. sp., P. damghanica n. sp., Rectogordius iranicus n. gen. n. sp. and Tezaquina sp. 1. Copyright © 2012 John Wiley & Sons, Ltd.     

Lithologic mapping of HED terrains on Vesta using Dawn Framing Camera color data

The surface composition of Vesta, the most massive intact basaltic object in the asteroid belt, is interesting because it provides us with an insight into magmatic differentiation of planetesimals that eventually coalesced to form the terrestrial planets. The distribution of lithologic and compositional units on the surface of Vesta provides important constraints on its petrologic evolution, impact history, and its relationship with vestoids and howardite‐eucrite‐diogenite (HED) meteorites. Using color parameters (band tilt and band curvature) originally developed for analyzing lunar data, we have identified and mapped HED terrains on Vesta in Dawn Framing Camera (FC) color data. The average color spectrum of Vesta is identical to that of howardite regions, suggesting an extensive mixing of surface regolith due to impact gardening over the course of solar system history. Our results confirm the hemispherical dichotomy (east‐west and north‐south) in albedo/color/composition that has been observed by earlier studies. The presence of diogenite‐rich material in the southern hemisphere suggests that it was excavated during the formation of the Rheasilvia and Veneneia basins. Our lithologic mapping of HED regions provides direct evidence for magmatic evolution of Vesta with diogenite units in Rheasilvia forming the lower crust of a differentiated object.     

The origin of eucrites,diogenites, and olivine diogenites: Magma ocean crystallization and shallow magma chamber processes on Vesta

The asteroid 4 Vesta is one of the very few heavenly bodies to have been linked to samples on Earth: the howardite‐eucrite‐diogenite (HED) meteorite suite. This large and diverse suite of meteorites provides a detailed picture of Vesta's igneous and postigneous history. We have used the range of igneous rock types and compositions in the HED suite to test a series of chemical models for solidification processes following peak melting (magma ocean) conditions on Vesta. Fractional crystallization cannot have been a dominant early process in the magma ocean because it leads to excessive Fe‐enrichment in the melt. Models that are dominated by equilibrium crystallization cannot produce orthopyroxene cumulates (diogenites). Our best models invoke 60–70% equilibrium crystallization of a magma ocean followed by continuous extraction of the residual melt into shallow magma chambers. Fractional crystallization in these magma chambers combined with continuous or periodic addition of more melt from the slowly compacting crystal mush (magmatic recharge) can produce all of the igneous HED lithologies (noncumulate and cumulate eucrites, diogenites, dunites, harzburgites, and olivine diogenites). Magmatic recharge can also explain the narrow range in eucrite compositions and the variability of incompatible trace element concentrations in diogenites. We predict an internal structure for Vesta that permits excavation of the HEDs during the formation of the Rheasilvia basin, while remaining consistent with observations from the Dawn mission and most impact models.     

26Al‐26Mg isotope systematics of the first solids in the early solar system

High‐precision bulk aluminum‐magnesium isotope measurements of calcium‐aluminum‐rich inclusions (CAIs) from CV carbonaceous chondrites in several laboratories define a bulk ²⁶Al‐²⁶Mg isochron with an inferred initial ²⁶Al/²⁷Al ratio of approximately 5.25 × 10^?5, named the canonical ratio. Nonigneous CV CAIs yield well‐defined internal ²⁶Al‐²⁶Mg isochrons consistent with the canonical value. These observations indicate that the canonical ²⁶Al/²⁷Al ratio records initial Al/Mg fractionation by evaporation and condensation in the CV CAI‐forming region. The internal isochrons of igneous CV CAIs show a range of inferred initial ²⁶Al/²⁷Al ratios, (4.2–5.2) × 10^?5, indicating that CAI melting continued for at least 0.2 Ma after formation of their precursors. A similar range of initial ²⁶Al/²⁷Al ratios is also obtained from the internal isochrons of many CAIs (igneous and nonigneous) in other groups of carbonaceous chondrites. Some CAIs and refractory grains (corundum and hibonite) from unmetamorphosed or weakly metamorphosed chondrites, including CVs, are significantly depleted in ²⁶Al. At least some of these refractory objects may have formed prior to injection of ²⁶Al into the protosolar molecular cloud and its subsequent homogenization in the protoplanetary disk. Bulk aluminum and magnesium‐isotope measurements of various types of chondrites plot along the bulk CV CAI isochron, suggesting homogeneous distribution of ²⁶Al and magnesium isotopes in the protoplanetary disk after an epoch of CAI formation. The inferred initial ²⁶Al/²⁷Al ratios of chondrules indicate that most chondrules formed 1–3 Ma after CAIs with the canonical ²⁶Al/²⁷Al ratio.     

In situ U/Pb dating of impact‐produced zircons from the Vargeão Dome (Southern Brazil)

The Vargeão impact structure was formed in the Serra Geral basaltic and rhyodacitic to rhyolitic lava flows of southern Brazil, that belong to the Paraná‐Etendeka large igneous province. The Chapecó‐type rhyodacites contain small baddeleyite crystals recently dated at 134.3 (±0.8) Ma, which is regarded as the age of this acid volcanism coeval to the flood basalt eruption. Inside the impact structure, a brecciated rhyodacitic sample displays fine veinlets containing numerous lithic fragments in a former melt. This impact breccia contains newly formed zircons, either in the veins or at the contact between a vein and the volcanic matrix. The zircons are 10–50 μm in length, clear and nearly unzoned. In situ laser‐ablation dating of the zircons provides a concordant Early Aptian age of 123.0 ± 1.4 Ma that is regarded as the age of the impact event. As in situ age determination ensures the best possible selection of the analyzed mineral grains, the methodology employed in this study also represents a promising method for dating other impact structures.     

Geochemical studies of the SUBO 18 (Enkingen) drill core and other impact breccias from the Ries crater,Germany

Suevite and melt breccia compositions in the boreholes Enkingen and Polsingen are compared with compositions of suevites from other Ries boreholes and surface locations and discussed in terms of implications for impact breccia genesis. No significant differences in average chemical compositions for the various drill cores or surface samples are noted. Compositions of suevite and melt breccia from southern and northeastern sectors of the Ries crater do not significantly differ. This is in stark contrast to the published variations between within‐crater and out‐of‐crater suevites from northern and southern sectors of the Bosumtwi impact structure, Ghana. Locally occurring alteration overprint on drill cores—especially strong on the carbonate‐impregnated suevite specimens of the Enkingen borehole—does affect the average compositions. Overall, the composition of the analyzed impact breccias from Ries are characterized by very little macroscopically or microscopically recognized sediment‐clast component; the clast populations of suevite and impact melt breccia are dominated consistently by granitic and intermediate granitoid components. The Polsingen breccia is significantly enriched in a dioritic clast component. Overall, chemical compositions are of intermediate composition as well, with dioritic‐granodioritic silica contents, and relatively small contributions from mafic target components. Selected suevite samples from the Enkingen core have elevated Ni, Co, Cr, and Ir contents compared with previously analyzed suevites from the Ries crater, which suggest a small meteoritic component. Platinum‐group element (PGE) concentrations for some of the enriched samples indicate somewhat elevated concentrations and near‐chondritic ratios of the most immobile PGE, consistent with an extraterrestrial contribution of 0.1–0.2% chondrite‐equivalent.     

Soft‐sediment deformation structures in a Pleistocene glaciolacustrine delta and their implications for the recognition of subenvironments in delta deposits

The development of soft‐sediment deformation structures in clastic sediments is now reasonably well‐understood but their development in various deltaic subenvironments is not. A sedimentological analysis of a Pleistocene (ca 13·1 to 15 ¹⁰Be ka) Gilbert‐type glaciolacustine delta with gravity‐induced slides and slumps in the Mosty‐Danowo tunnel valley (north‐western Poland) provides more insight, because the various soft‐sediment deformation structures in these deposits were considered in the context of their specific deltaic subenvironment. The sediments show three main groups of soft‐sediment deformation structures in layers between undeformed sediments. The first group consists of deformed cross‐bedding (inclined, overturned, recumbent, complex and sheath folds), large‐scale folds (recumbent and sheath folds) and pillows forming plastic deformations. The second group comprises pillar structures (isolated and stress), clastic dykes with sand volcanoes and clastic megadykes as examples of water‐escape structures. The third group consists of faults (normal and reverse) and extensional fissures (small fissures and neptunian dykes). Some of the deformations developed shortly after deposition of the deformed sediment, other structures developed later. This development must be ascribed to hydroplastic movement in a quasi‐solid state, and due to fluidization and liquefaction of the rapidly deposited, water‐saturated deltaic sediments. The various types of deformations were triggered by: (i) a high sedimentation rate; (ii) erosion (by wave action or meltwater currents); and (iii) ice‐sheet loading and seasonal changes in the ablation rate. Analysis of these triggers, in combination with the deformational mechanisms, have resulted – on the basis of the spatial distribution of the various types of soft‐sediment deformation structures in the delta under study – in a model for the development of soft‐sediment deformation structures in the topsets, foresets and bottomsets of deltas. This analysis not only increases the understanding of the deformation processes in both modern and ancient deltaic settings but also helps to distinguish between the various subenvironments in ancient deltaic deposits.