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841.
贵州大厂锑矿有机质与有机成矿作用 总被引:6,自引:0,他引:6
用有机地球化学方法对矿区与右江盆地有机质的分析研究表明,容矿的大厂层有机碳与锑含量相对较高;有机包裹体主要是气态烃包裹体与沥青包裹体,在气态烃包裹体中含0%~30%的液态烃,发暗黄色荧光;有机气相成分中四种烷烃甲烷、乙烷、丙烷、丁烷均有显示;从主成矿期萤石中的沥青及右江盆地再沉积火山碎屑岩中的干酪根的生物标志物测定结果来看,二者在正烷烃、类异戊二烯烷烃、萜烷与甾烷标志物特征上较为接近,表明右江盆地沉积物中的有机质与锑矿中的有机质有亲缘关系。模拟实验证明原油对锑有较强的萃取迁移能力;而有机质在锑成矿过程中主要起三方面的作用:淋滤、萃取迁移及还原沉淀。 相似文献
842.
843.
844.
珍珠陶石的夹层化合物法鉴定 总被引:1,自引:0,他引:1
应用联氨、使珍珠陶石形成其夹层物,然后再用水洗获是水合珍珠陶石,这种水合珍珠陶石具有十分特征的0.835nmX射线衍射峰,而高岭石族的其它矿物却保持不变,利用这一明显的特征,可以容易地区分出混合在高岭石中的少量珍珠陶石。 相似文献
845.
福清沙浦--平潭马腿推覆型性剪切带位于福建东南沿海褶皱变质带的北段,在“三山、平潭、高山、观音澳”幅1:5万区调工作中,我们首次发现并肯定了该推覆型韧性剪切带的存在,并作了详细的工作。 相似文献
846.
Ultrahigh-pressure metamorphism in the forbidden zone: the Xugou garnet peridotite, Sulu terrane, eastern China 总被引:21,自引:3,他引:21
The Xugou garnet peridotite body of the southern Sulu ultrahigh‐pressure (UHP) terrane is enclosed in felsic gneiss, bounded by faults, and consists of harzburgite and lenses of garnet clinopyroxenite and eclogite. The peridotite is composed of variable amounts of olivine (Fo91), enstatite (En92?93), garnet (Alm20?23Prp53?58Knr6?9Grs12?18), diopside and rare chromite. The ultramafic protolith has a depleted residual mantle composition, indicated by a high‐Mg number, very low CaO, Al2O3 and total REE contents compared to primary mantle and other Sulu peridotites. Most garnet (Prp44?58) clinopyroxenites are foliated. Except for rare kyanite‐bearing eclogitic bands, most eclogites contain a simple assemblage of garnet (Alm29?34Prp32?50Grs15?39) + omphacite (Jd24?36) + minor rutile. Clinopyroxenite and eclogite exhibit LREE‐depleted and LREE‐enriched patterns, respectively, but both have flat HREE patterns. Normalized La, Sm and Yb contents indicate that both eclogite and garnet clinopyroxenite formed by high‐pressure crystal accumulation (+ variable trapped melt) from melts resulting from two‐stage partial melting of a mantle source. Recrystallized textures and P–T estimates of 780–870 °C, 5–7 GPa and a metamorphic age of 231 ± 11 Ma indicate that both mafic and ultramafic protoliths experienced Triassic UHP metamorphism in the P–T forbidden zone with an extremely low thermal gradient (< 5 °C km?1), and multistage retrograde recrystallization during exhumation. Develop of prehnite veins in clinopyroxenite, eclogite, felsic blocks and country rock gneiss, and replacements of eclogitic minerals by prehnite, albite, white mica, and K‐feldspar indicate low‐temperature metasomatism. 相似文献
847.
Spatial and seasonal distributions of soil phosphorus in a typical seasonal flooding wetland of the Yellow River Delta,China 总被引:2,自引:0,他引:2
Xiaofei Ye Junhong Bai Qiongqiong Lu Qingqing Zhao Junjing Wang 《Environmental Earth Sciences》2014,71(11):4811-4820
Soil samples from 0 to 100 cm depth were collected in four sampling sites (Sites A, B, C and D) along a 250-m length of sampling zone from the Yellow River channel to a tidal creek in a seasonal flooding wetland of the Yellow River Delta of China in fall of 2007 and spring of 2008 to investigate spatial and seasonal distribution patterns of total phosphorous (TP) and available phosphorus (AP) and their influencing factors. Our results showed that TP contents in spring and AP contents in both seasons in surface soils increased with increasing distances away from the Yellow River channel. TP contents in surface soils (0–10 cm) followed the order Site A (698.6 mg/kg) > Site B (688.0 mg/kg) > Site C (638.8 mg/kg) > Site D (599.2 mg/kg) in fall, while Site C (699.6 mg/kg) > Site D (651.7 mg/kg) > Site B (593.6 mg/kg) > Site A (577.5 mg/kg) in spring. Generally, lower TP content (630.6 mg/kg) and higher AP level (6.2 mg/kg) in surface soils were observed in spring compared to fall (656.2 mg/kg for TP and 5.2 mg/kg for AP). Both TP and AP exhibited similar profile distribution patterns and decreased with depth along soil profiles with one or two accumulation peaks at the depth of 40–80 cm. Although the mean TP content in soil profiles was slightly higher in spring (635.7 mg/kg) than that in fall (628.0 mg/kg), the mean TP stock was obviously lower in spring (959.9 g/m2) with an obvious accumulation at the 60–80 cm soil depth compared to fall (1124.6 g/m2). Topsoil concentration factors also indicated that TP and AP had shallower distribution in soil profiles. Correlation analysis showed that AP had significant and positive correlation with these soil properties such as soil organic matter, salinity, total nitrogen and Al (p < 0.01), but TP was just significantly correlated with TN and Al (p < 0.05). 相似文献
848.
山西义兴寨金矿床地球化学研究 总被引:12,自引:1,他引:12
晋东北地区以唐河大断裂为核心的一组早燕山期 NW向张剪性断裂与区域 NE向复向斜复合部位 ,控制着区内燕山期中酸性浅成侵入体及其与之有关的铁、金、铜矿化 ,义兴寨金矿是该地区具代表性的典型矿床。金矿床为热液型脉状金 -多金属矿床 ,矿体受岩体和断裂构造控制。金矿床分 4个成矿期 ,8个亚期。对金矿床的矿床地质特征、成矿流体成分、性质、成矿物理化学条件及成矿时代的研究表明 ,成矿溶液的 p H值为 6 .1 6~ 6 .5 3:Eh值为 -0 .2 81~-0 .2 80 ;lgf O2 =-3.6~ -2 9,lgf CO2 =4 .3~ 5 .2 ;成矿温度为 1 90~ 349℃ ;成矿压力为 2 0 .0~ 76 .0 MPa;矿床主成矿期石英的 40 Ar— 3 9Ar坪年龄为 ( 1 31 .4± 3.1 ) Ma。 相似文献
849.
850.
The sphalerite oxidative kinetics under hypergene condition was simulated and studied by means of a mixed flow reactor over a pH range of 1.0 7.8,and at dissolution temperatures from 20 to 55℃,ferric ion concentrations from 1.0×10-5 to 1.0×10-2 mol/L,O 2 flux of 0.5 L/min,and oxidants of ferric ion and O 2.It is indicated that with ferric ion as oxidant,the oxidation rate of sphalerite increases with increasing ferric ion concentration,temperature and decreasing pH value,and under the studied conditions,the dissolution rates of Zn and Cd are approximately identical,with the values of activation energy being 41.75 and 42.51 kJ·mol-1,respectively,suggesting that the oxidation rate of sphalerite is controlled by chemical reactions on mineral surface.However,with O 2 as oxidant,the oxidation mechanism of sphalerite varies with pH value.Oxidation rate decreases with increasing pH value when pH is lower than 5.95,whereas the increase of pH value results in an increase in oxidation rate when pH value is higher than 7.The oxidation rate of sphalerite can be expressed as:R Zn =10 1.1663 [Fe3+] 0 0.154 ·[H+] 0.2659 ·e-41.75/RT or R Cd =10 1.7292 [Fe3+] 0 0.170 ·[H+] 0.2637 ·e-42.51/RT 相似文献